Tetrahedratic mesophases, chiral order, and helical domains induced by quadrupolar and octupolar interactions

We present an exhaustive account of phases and phase transitions that can be stabilized in the recently introduced generalized Lebwohl-Lasher model with quadrupolar and octupolar microscopic interactions [ L. Longa, G. Pająk and T. Wydro Phys. Rev. E 79 040701 (2009)]. A complete mean-field analysis of the model, along with Monte Carlo simulations allows us to identify four distinct classes of the phase diagrams with a number of multicritical points where, in addition to the standard uniaxial and biaxial nematic phases, the other nematic like phases are stabilized. These involve, among the others, tetrahedratic (T), nematic tetrahedratic (NT), and chiral nematic tetrahedratic (NT*) phases of global Td, D2d, and D2 symmetry, respectively. Molecular order parameters and correlation functions in these phases are determined. We conclude with generalizations of the model that give a simple molecular interpretation of macroscopic regions with opposite optical activity (ambidextrous chirality), observed, e.g., in bent-core systems. An estimate of the helical pitch in the NT* phase is also given

Intrinsic optical dichroism in the chiral superconducting state of Sr2_{2}RuO4_{4}

We present an analysis of the Hall conductivity $\sigma_{xy}(\omega, T)$ in time reversal symmetry breaking states of exotic superconductors. We find that the dichroic signal is non-zero in systems with inter-band order parameters. This new intrinsic mechanism may explain the Kerr effect observed in strontium ruthenate and possibly other superconductors. We predict coherence factor effects in the temperature dependence of the imaginary part of the ac Hall conductivity $Im\sigma_{xy}(\omega, T)$, which can be tested experimentally.Comment: 4+ pages, 4 figures, published versio

Electron gun for diffraction experiments off controlled molecules

A dc electron gun, generating picosecond pulses with up to $8\times10^{6}$ electrons per pulse, was developed. Its applicability for future time-resolved-diffraction experiments on state- and conformer-selected laser-aligned or oriented gaseous samples was characterized. The focusing electrodes were arranged in a velocity-map imaging spectrometer configuration. This allowed to directly measure the spatial and velocity distributions of the electron pulses emitted from the cathode. The coherence length and pulse duration of the electron beam were characterized by these measurements combined with electron trajectory simulations. Electron diffraction data off a thin aluminum foil illustrated the coherence and resolution of the electron-gun setup

The Kerr rotation in the unconventional superconductor Sr2_2RuO4_4

The interpretation of Kerr rotation measurements in the superconducting phase of Sr$_2$RuO$_4$ is a controversial topic. Both intrinsic and extrinsic mechanisms have been proposed, and it has been argued that the intrinsic response vanishes by symmetry. We focus on the intrinsic contribution and clarify several conflicting results in the literature. On the basis of symmetry considerations and detailed calculations we show that the intrinsic Kerr signal is not forbidden in a general multi- band system but has a rich structure in the near infrared regime. We distinguish different optical transitions determined by the superconducting gap (far infrared) and the inter orbital coupling of the normal state (near infrared). We argue that the low frequency transitions do not contribute to the Hall conductivity while only the inter-orbital transitions in the near infrared regime contribute. Finally, we discuss the difficulties to connect the calculations for the optical Hall conductivity to the experimental measurement of the Kerr angle. We will compare different approximations which might lead to conflicting results.Comment: 9 pages, 8 figures, 1 tabl

Subnormalized states and trace-nonincreasing maps

We investigate the set of completely positive, trace-nonincreasing linear maps acting on the set M_N of mixed quantum states of size N. Extremal point of this set of maps are characterized and its volume with respect to the Hilbert-Schmidt (Euclidean) measure is computed explicitly for an arbitrary N. The spectra of partially reduced rescaled dynamical matrices associated with trace-nonincreasing completely positive maps belong to the N-cube inscribed in the set of subnormalized states of size N. As a by-product we derive the measure in M_N induced by partial trace of mixed quantum states distributed uniformly with respect to HS-measure in $M_{N^2}$.Comment: LaTeX, 21 pages, 4 Encapsuled PostScript figures, 1 tabl

Spin-nematic order in the frustrated pyrochlore-lattice quantum rotor model

As an example of ordering due to quantum fluctuations, we examine the nearest-neighbor antiferromagnetic quantum O(n) rotor model on the pyrochlore lattice. Classically, this system remains disordered even at zero temperature; we find that adding quantum fluctuations induces an ordered phase that survives to positive temperature, and we determine how its phase diagram scales with the coupling constant and the number of spin components. We demonstrate, using quantum Monte Carlo simulations, that this phase has long-range spin-nematic order, and that the phase transition into it appears to be first order.Comment: 10 pages, 8 figure