635 research outputs found
Application of the Shifting Method as a Technique to Correct for the Background in Quantitative Analysis by Open-Path FTIR
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/91921/1/awmapub.pd
NuclearâElectron Correlation Effects and Their Photoelectron Imprint in Molecular XUV Ionisation
The ionisation of molecules by attosecond XUV pulses is accompanied by complex correlated dynamics, such as the creation of coherent electron wave packets in the parent ion, their interplay with nuclear wave packets, and a correlated photoelectron moving in a multi-centred potential. Additionally, these processes are influenced by the dynamics prior to and during the ionisation. To fully understand and subsequently control the ionisation process on different time scales, a profound understanding of electron and nuclear correlation is needed. Here, we investigate the effect of nuclearâelectron correlation in a correlated two-electron and one-nucleus quantum model system. Solving the time-dependent Schrödinger equation allows to monitor the correlation impact pre, during, and post-XUV ionisation. We show how an initial nuclear wave packet displaced from equilibrium influences the post-ionisation dynamics by means of momentum conservation between the target and parent ion, whilst the attosecond electron population remains largely unaffected. We calculate time-resolved photoelectron spectra and their asymmetries and demonstrate how the coupled electronânuclear dynamics are imprinted on top of electronâelectron correlation on the photoelectron properties. Finally, our findings give guidelines towards when correlation resulting effects have to be incorporated and in which instances the exact correlation treatment can be neglected
Analysis of death in major trauma: value of prompt post mortem computed tomography (pmCT) in comparison to office hour autopsy
Background: To analyze diagnostic accuracy of prompt post mortem Computed Tomography (pmCT) in determining causes of death in patients who died during trauma room management and to compare the results to gold standard autopsy during office hours. Methods: Multiple injured patients who died during trauma room care were enrolled. PmCT was performed immediately followed by autopsy during office hours. PmCT and autopsy were analyzed primarily regarding pmCT ability to find causes of death and secondarily to define exact causes of death including accurate anatomic localizations. For the secondary analysis data was divided in group-I with equal results of pmCT and autopsy, group-II with autopsy providing superior results and group-III with pmCT providing superior information contributing to but not majorly causing death. Results: Seventeen multiple trauma patients were enrolled. Since multiple trauma patients were enrolled more injuries than patients are provided. Eight patients sustained deadly head injuries (47.1 %), 11 chest (64.7 %), 4 skeletal system (23.5 %) injuries and one patient drowned (5.8 %). Primary analysis revealed in 16/17 patients (94.1 %) causes of death in accordance with autopsy. Secondary analysis revealed in 9/17 cases (group-I) good agreement of autopsy and pmCT. In seven cases autopsy provided superior results (group-II) whereas in 1 case pmCT found more information (group-III). Discussion: The presented work studied the diagnostic value of pmCT in defining causes of death in comparison to standard autopsy. Primary analysis revealed that in 94.1% of cases pmCT was able to define causes of death even if only indirect signs were present. Secondary analysis showed that pmCT and autopsy showed equal results regarding causes of death in 52.9%. Conclusions: PmCT is useful in traumatic death allowing for an immediate identification of causes of death and providing detailed information on bony lesions, brain injuries and gas formations. It is advisable to conduct pmCT especially in cases without consent to autopsy to gain information about possible causes of death and to rule out possible clinical errors
Absolute Calibration and Characterization of the Multiband Imaging Photometer for Spitzer. II. 70 micron Imaging
The absolute calibration and characterization of the Multiband Imaging
Photometer for Spitzer (MIPS) 70 micron coarse- and fine-scale imaging modes
are presented based on over 2.5 years of observations. Accurate photometry
(especially for faint sources) requires two simple processing steps beyond the
standard data reduction to remove long-term detector transients. Point spread
function (PSF) fitting photometry is found to give more accurate flux densities
than aperture photometry. Based on the PSF fitting photometry, the calibration
factor shows no strong trend with flux density, background, spectral type,
exposure time, or time since anneals. The coarse-scale calibration sample
includes observations of stars with flux densities from 22 mJy to 17 Jy, on
backgrounds from 4 to 26 MJy sr^-1, and with spectral types from B to M. The
coarse-scale calibration is 702 +/- 35 MJy sr^-1 MIPS70^-1 (5% uncertainty) and
is based on measurements of 66 stars. The instrumental units of the MIPS 70
micron coarse- and fine-scale imaging modes are called MIPS70 and MIPS70F,
respectively. The photometric repeatability is calculated to be 4.5% from two
stars measured during every MIPS campaign and includes variations on all time
scales probed. The preliminary fine-scale calibration factor is 2894 +/- 294
MJy sr^-1 MIPS70F^-1 (10% uncertainty) based on 10 stars. The uncertainty in
the coarse- and fine-scale calibration factors are dominated by the 4.5%
photometric repeatability and the small sample size, respectively. The 5-sigma,
500 s sensitivity of the coarse-scale observations is 6-8 mJy. This work shows
that the MIPS 70 micron array produces accurate, well calibrated photometry and
validates the MIPS 70 micron operating strategy, especially the use of frequent
stimulator flashes to track the changing responsivities of the Ge:Ga detectors.Comment: 19 pages, PASP, in pres
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