Synthesis and characterization of LNMO cathode materials for lithium-ion batteries

Abstract Synthesis of LiNi0.5Mn1.5O4 (LNMO), a promising cathode material for next generation lithium-ion batteries, was performed via Liquid Phase Self-propagating High-temperature Synthesis (LPSHS) and Aerosol Spray Pyrolysis (ASP) techniques. In the case of the LPSHS technique, the effect of the "fuel" quantity of the precursor solution on the structure, morphology and electrochemical performance of the materials was studied, while in the case of the ASP technique the effect of eight different calcination profiles on the structure, morphology, crystalline phase and electrochemical performance of the material. Structural characterization was performed through XRD, SEM, TEM, BET and Raman spectroscopy, while the electrochemical activity was evaluated via charge/discharge galvanostatic characterization. The results showed that the optimal LPSHS material was obtained for a molar ratio of metal ions/fuel = 3:1 exhibiting stable specific capacity over the cycles even by increasing the C-rate. Τhe optimal ASP material was identified in the case of calcination at 850°C. Both materials had the disordered Fd-3m structure of the LNMO spine

Study of Oxidation and Combustion Characteristics of Iron Nanoparticles under Idealized and Enginelike Conditions

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Energy Fuels, copyright © American Chemical Society after peer review and technical editing by the publisher.[EN] The present work includes findings from proof-of-principle feasibility studies on iron nanopowder combustion under idealized, enginelike, and real engine conditions. The study was conducted under the scope of recent interest in metallic nanoparticles as alternative fuels for internal combustion engines. More specifically, Fe nanoparticles with different morphologies and average primary particle sizes ranging from 25 to 85 nm were studied with respect to their oxidation characteristics via thermogravimetric analysis as well as in customized shock tube, constant-volume vessel, and compression-ignition (CI) engine configurations. Combusted powder samples were in all cases examined via in situ and ex situ techniques for the identification of combustion products and their morphologies. The findings facilitated the determination of the main phenomena involved during oxidation. The results verified that combustion of Fe nanoparticles in a slightly modified CI engine is feasible, albeit with various technological challenges related to ignition and scavenging that inhibit combustion quality.The authors thank the European Commission for partial funding of this work through the Project “COMETNANO” (FP7-NMP4-SL-2009-229063).Mandilas, C.; Karagiannakis, G.; Konstandopoulos, AG.; Beatrice, C.; Lazzaro, M.; Di Blasio, G.; Molina, S.... (2016). Study of Oxidation and Combustion Characteristics of Iron Nanoparticles under Idealized and Enginelike Conditions. Energy and Fuels. 30(5):4318-4330. https://doi.org/10.1021/acs.energyfuels.6b00121S4318433030

An Alternative Yukawa Unified SUSY Scenario

Supersymmetric SO(10) Grand Unified Theories with Yukawa unification represent an appealing possibility for physics beyond the Standard Model. However Yukawa unification is made difficult by large threshold corrections to the bottom mass. Generally one is led to consider models where the sfermion masses are large in order to suppress these corrections. Here we present another possibility, in which the top and bottom GUT scale Yukawa couplings are equal to a component of the charged lepton Yukawa matrix at the GUT scale in a basis where this matrix is not diagonal. Physically, this weak eigenstate Yukawa unification scenario corresponds to the case where the charged leptons that are in the 16 of SO(10) containing the top and bottom quarks mix with their counterparts in another SO(10) multiplet. Diagonalizing the resulting Yukawa matrix introduces mixings in the neutrino sector. Specifically we find that for a large region of parameter space with relatively light sparticles, and which has not been ruled out by current LHC or other data, the mixing induced in the neutrino sector is such that $sin^2 2\Theta_{23} \approx 1$, in agreement with data. The phenomenological implications are analyzed in some detail.Comment: 32 pages, 22 Figure

The impact of XENON100 and the LHC on Supersymmetric Dark Matter

The effect of 2010 and 2011 LHC data are discussed in connection to the potential for the direct detection of supersymmetric dark matter. The impact of the recent XENON100 results are contrasted to these predictions.Comment: 14 pages, 23 figures, To be published in the Proceedings of the 7th DSU Conference, Beijing Chin

Responsive Operations for Key Services (ROKS): A Modular, Low SWaP Quantum Communications Payload

Quantum key distribution (QKD) is a theoretically proven future-proof secure encryption method that inherits its security from fundamental physical principles. With a proof-of-concept QKD payload having flown on the Micius satellite since 2016, efforts have intensified globally. Craft Prospect, working with a number of UK organisations, has been focused on miniaturising the technologies that enable QKD so that they may be used in smaller platforms including nanosatellites. The significant reduction of size, and therefore the cost of launching quantum communication technologies either on a dedicated platform or hosted as part of a larger optical communications will improve potential access to quantum encryption on a relatively quick timescale. The Responsive Operations for Key Services (ROKS) mission seeks to be among the first to send a QKD payload on a CubeSat into low Earth orbit, demonstrating the capabilities of newly developed modular quantum technologies. The ROKS payload comprises a quantum source module that supplies photons randomly in any of four linear polarisation states fed from a quantum random number generator; an acquisition, pointing, and tracking system to fine-tune alignment of the quantum source beam with an optical ground station; an imager that will detect cloud cover autonomously; and an onboard computer that controls and monitors the other modules, which manages the payload and assures the overall performance and security of the system. Each of these modules have been developed with low Size, Weight and Power (SWaP) for CubeSats, but with interoperability in mind for other satellite form factors. We present each of the listed components, together with the initial test results from our test bench and the performance of our protoflight models prior to initial integration with the 6U CubeSat platform systems. The completed ROKS payload will be ready for flight at the end of 2022, with various modular components already being baselined for flight and integrated into third party communication missions

Dark Matter and Higgs Mass in the CMSSM with Yukawa Quasi-Unification

We present an updated analysis of the constrained minimal supersymmetric standard model with mu>0 supplemented by an `asymptotic' Yukawa coupling quasi-unification condition, which allows an acceptable b-quark mass. Imposing constraints from the cold dark matter abundance in the universe, B physics, the muon anomalous magnetic moment, and the mass m_h of the lightest neutral CP-even Higgs boson, we find that the lightest neutralino cannot act as a cold dark matter candidate. This is mainly because the upper bound on the lightest neutralino relic abundance from cold dark matter considerations, despite the fact that this abundance is drastically reduced by neutralino-stau coannihilations, is incompatible with the recent data on the branching ratio of B_s --> mu^+ mu^-. Allowing for a different particle, such as the axino or the gravitino, to be the lightest supersymmetric particle and, thus, constitute the cold dark matter in the universe, we find that the predicted m_h's in our model favor the range (119-126) GeV.Comment: 13 pages including 4 figures and 1 table, talk given by G. Lazarides at the 7th International Workshop on the Dark Side of the Universe, KITPC, Beijing, China, September 26-30, 2011 (to appear in the proceedings

125 GeV Higgs Boson from t-b-tau Yukawa Unification

We identify a class of supersymmetric SU(4)_c x SU(2)_L x SU(2)_R models in which imposing essentially perfect t-b-tau Yukawa coupling unification at M_GUT yields a mass close to 122-126 GeV for the lightest CP-even (SM-like) Higgs boson. The squark and gluino masses in these models exceed 3 TeV, but the stau and charginos in some cases can be considerably lighter. We display some benchmark points corresponding to neutralino-stau and bino-wino coannihilations as well as A-resonance. The well-known MSSM parameter tan beta is around 46-52.Comment: 16 pages, 4 figure