29 research outputs found
Poly(ε-caprolactone)-Banded Spherulites and Interaction with MC3T3-E1 Cells
We report that protein adsorption, cell attachment, and
cell proliferation
were enhanced on spherulites-roughened polymer surfaces. Banded spherulites
with concentric alternating succession of ridges and valleys were
observed on spin-coated thin films of poly(ε-caprolactone) (PCL)
and two series of PCL binary homoblends composed of high- and low-molecular-weight
components when they were isothermally crystallized at 25–52
°C. Their thermal properties, crystallization kinetics, and surface
morphology were examined. The melting temperature (<i>T</i><sub>m</sub>), crystallinity (χ<sub>c</sub>), crystallization
rate, and spherulitic patterns showed strong dependence on the crystallization
temperature (<i>T</i><sub>c</sub>) and the blend composition.
The surface roughness of the spherulites was higher when <i>T</i><sub>c</sub> was higher; thus, the larger surface area formed in
banded spherulites could adsorb more serum proteins from cell culture
media. In vitro mouse preosteoblastic MC3T3-E1 cell attachment, proliferation,
and nuclear localization were assessed on the hot-compressed flat
disks and spherulites-roughened films of the high-molecular-weight
PCL and one of its homoblends. The number of attached MC3T3-E1 cells
and the proliferation rate were greater on the rougher surfaces than
those on the flat ones. It is interesting to note that cell nuclei
were preferentially, though not absolutely, located in or close to
the valleys of the banded spherulites. The percentage of cell nuclei
in the valleys was higher than 78% when the ridge height and adjacent
ridge distance were ∼350 and ∼35 nm, respectively. This
preference was weaker when the ridge height was lower or at a higher
cell density. These results suggest that isothermal crystallization
of semicrystalline polymers can be an effective thermal treatment
method to achieve controllable surface roughness and pattern for regulating
cell behaviors in tissue-engineering applications
Funnel plot and sensitivity analysis for prognosis of patients with OSCC (A: Funnel plot; B: sensitivity analysis).
<p>Funnel plot and sensitivity analysis for prognosis of patients with OSCC (A: Funnel plot; B: sensitivity analysis).</p
Facile synthesis and wide-band electromagnetic wave absorption properties of carbon-coated ZnO nanorods
<p>In this work, a facile and scalable acetylene decomposition method was employed to synthesize carbon-coated ZnO (ZnO@C) nanorods. The characterization of morphology and structure analysis demonstrate that ZnO nanorod was well coated by an amorphous carbon shell with a thickness of about 20 nm. Comparted with ZnO, ZnO@C exhibit significantly enhanced microwave absorption properties. The effective absorption bandwidth with RL values exceeding –10 dB can reach 5.3 GHz for ZnO@C with a matching thickness of 2.5 mm. The excellent microwave absorption arose from enhanced dielectric loss caused by interfacial polarization, dipole polarization and the formation of conductive network.</p
Flow diagram of the literature search process.
<p>Flow diagram of the literature search process.</p
Sensitivity analysis for clinicopathological features (A: lymph node involvement; B: clinical stage; C: cell differentiation; D: depth of invasion; E: gender; F: age).
<p>Sensitivity analysis for clinicopathological features (A: lymph node involvement; B: clinical stage; C: cell differentiation; D: depth of invasion; E: gender; F: age).</p
Additional file 1: of The Preparation of Au@TiO2 Yolk–Shell Nanostructure and its Applications for Degradation and Detection of Methylene Blue
Supporting information. Figure S1. SEM images of CNCs. Figure S2. TEM images and the size distribution analysis of Au nanoparticles of (a1 and a2) Au-30@TiO2; (b1 and b2) Au-50@TiO2; (c1 and c2) Au-80@TiO2; (d1 and d2) Au-120@TiO2. Figure S3. TEM image of the Au-80@TiO2 after photocatalytic reaction. (DOC 11017 kb
Clinicopathological and methodological features of eligible studies.
<p>Clinicopathological and methodological features of eligible studies.</p
Distribution of ncRNAs on four replicons.
<p>Distribution of ncRNAs on four replicons.</p
From the ZnO Hollow Cage Clusters to ZnO Nanoporous Phases: A First-Principles Bottom-Up Prediction
A family
of Zn<sub><i>k</i></sub>O<sub><i>k</i></sub> (<i>k</i> = 12, 16) cluster-assembled solid phases
with novel structures and properties has been characterized utilizing
a bottom-up approach with density functional calculations. Geometries,
stabilities, equation of states, phase transitions, and electronic
properties of these ZnO polymorphs have been systematically investigated.
First-principles molecular dynamics (FPMD) study of the two selected
building blocks, Zn<sub>12</sub>O<sub>12</sub> and Zn<sub>16</sub>O<sub>16</sub>, with hollow cage structure and large HOMO–LUMO
gap shows that both of them are thermodynamically stable enough to
survive up to at least 500 K. Via the coalescence of building blocks,
we find that the Zn<sub>12</sub>O<sub>12</sub> cages are able to form
eight stable phases by four types of Zn<sub>12</sub>O<sub>12</sub>–Zn<sub>12</sub>O<sub>12</sub> interactions, and the Zn<sub>16</sub>O<sub>16</sub> cages can bind into three phases by the Zn<sub>16</sub>O<sub>16</sub>–Zn<sub>16</sub>O<sub>16</sub> links
of H′, C′, and S′. Among these phases, six ones
are reported for the first time. This has greatly extended the family
of ZnO nanoporous phases. Notably, some of these phases are even more
stable than the synthesized metastable rocksalt ZnO polymorph. The
hollow cage structure of the corresponding building block Zn<sub><i>k</i></sub>O<sub><i>k</i></sub> is well preserved
in all of them, which leads to their low-density nanoporous and high
flexibility features. In addition the electronic integrity (wide-energy
gap) of the individual Zn<sub><i>k</i></sub>O<sub><i>k</i></sub> is also retained. Our calculation reveals that they
are all semiconductor with a large direct or indirect band gap. The
insights obtained in this work are likely to be general in II–VI
semiconductor compounds and will be helpful for extending the range
of properties and applications of ZnO materials