On the overabundance of light rare earth elements in terrestrial zircons and its implication for Earth's earliest magmatic differentiation

We present whole-rock and zircon rare earth element (REE) data from two early Archaean gneisses (3.81 Ga and 3.64 Ga) from the Itsaq gneiss complex, south-west Greenland. Both gneisses represent extremely rare examples of unaltered, fresh and relatively undeformed igneous rocks of such antiquity. Cathodoluminescence imaging of their zircons indicates a single crystallisation episode with no evidence for either later metamorphic and/or anatectic reworking or inheritance of earlier grains. Uniform, single-population U/Pb age data confirm the structural simplicity of these zircons. One sample, a 3.64 Ga granodioritic gneiss from the Gothabsfjord, yields a chondrite-normalised REE pattern with a positive slope from La to Lu as well as substantial positive Ce and slight negative Eu anomalies, features generally considered to be typical of igneous zircon. In contrast, the second sample, a 3.81 Ga tonalite from south of the Isua Greenstone Belt, has variable but generally much higher light REE abundances, with similar middle to heavy REE. Calculation of zircon/melt distribution coefficients (D-REE(zircon/melt)) from each sample yields markedly different values for the trivalent REE (i.e. Ce and Eu omitted) and simple application of one set of D-REE(zircon/melt) to model the melt composition for the other sample yields concentrations that are in error by up to two orders of magnitude for the light REE (La-Nd). The observed light REE overabundance in the 3.81 Ga tonalite is a commonly observed feature in terrestrial zircons for which a number of explanations ranging from lattice strain to disequilibrium crystallisation have been proposed and are further investigated herein. Regardless of the cause of light REE overabundance, our study shows that simple application of zircon/melt distribution coefficients is not an unambiguous method for ascertaining original melt composition. In this context, recent studies that use REE data to claim that > 4.3 Ga Hadean detrital zircons originally crystallised from an evolved magma, in turn suggesting the operation of geological processes in the early Earth analogous to those of the present day (e.g. subduction and melting of hydrated oceanic crust), must be regarded with caution. Indeed, comparison of terrestrial Hadean and > 3.9 Ga lunar highland zircons shows remarkable similarities in the light REE, even though subduction processes that have been used to explain the terrestrial zircons have never operated on the Moon. (C) 2002 Elsevier Science B.V. All rights reserved

The evolution of high T- low P granulites in the Northern Marginal Zone sensu stricto, Limpopo Belt, Zimbabwe - the case for petrography

The Limpopo Belt of southern Africa is generally believed to represent the root of a late Archaean continental collision zone, and has been used to demonstrate the validity of the uniformitarian concept in tectonics Large scale tectonic models have been applied in spite of the fact that large portions of the belt yet await the most basic investigations. Here we report the first detailed field and petrographic study of the northernmost part of the Limpopo Belt, the Northern Marginal Zone sensu stricto (NMZ s.s) and conclude, on the basis of relative age relation, nature of PT evolution and deformation, that none of the current models can correctly explain the evolution of the study area. The evolution of NMZ s.s, is complex and includes four metamorphic stages, two major plutonic episodes and at least three deformation events. The oldest rocks, mafic granulites, record all four stages of metamorphic mineral growth. The first two stages predate deposition of sediments and the intrusion of voluminous enderbite and charnockite between 2.72 and 2.62 Ga. The bulk of our observations relate to the late Archaean (stage 3) granulite facies event. Abundant reaction textures are preserved in mafic granulite, metasediments, metamorphosed charnockite and enderbite and allow us to qualitatively reconstruct the PT evolution. Prograde heating occurred in the sillimanite stability held. During peak temperature conditions vapour-absent melting is observed in most felsic lithologies,Temperatures between 800 and 850 degrees C at pressures as low as 0.4-0.5 GPa are indicated by various mineral assemblages. The thermal peak was followed by an increase in pressure. Typical reactions of anti-clockwise PT evolution, like breakdown of cordierite + spinel to sapphirine and orthopyroxene + plagioclase to garnet + quartz, are frequently found. Maximum pressure is constraint to ca. 0.85 GPa by the complete absence of garnet in mafic granulites. Initial cooling was rapid, and is indicated by the back reaction of melt + orthopyroxene to biotite + quartz symplectites preserved in migmatites. This metamorphic event was accompanied by intrusion of porphyritic charnockite and granite, and by coeval compressional deformation. The observed evolution, especially the combination of an anti-clockwise PT loop and compressional tectonics, requires a strong, transient heat-source affecting the base of the crust. Neither the thermal evolution nor the relative timing is correctly predicted by existing collision models. The NMZ s.s. granulites were finally exhumed in a separate event along upper greenschist-facies thrusts, in response to a transpressive orogeny affecting the units further south at 2.0 Ga. In spite of potential ambiguities inherent to a qualitative approach, our observations show that petrography and field work, if used in conjunction with dating of a few key age relations and structural interpretation, are a pre-requisite to the erection of realistic tectonic models. The example of the NMZ s.s. may encourage geoscientists with limited access to analytical facilities to reassess the geological evolution of terrains which lack basic description

Scavenging of atmospheric trace metal pollutants by mineral dusts: Inter-regional transport of Australian trace metal pollution to New Zealand.

Dust samples collected from the surface of glaciers and in dust traps on the remote West Coast of New Zealand's South Island can reliably be identified as being of both Australian and New Zealand origin. Most are, however, found to be enriched in Cu, Zn, Cd, Sb, Sn, Pb, Ni and Cr, when compared with their source-area sediments. The degree of metal enrichment in the dust samples is proportionally related to the percentage of Australian dust implying that the pollutants were transported with dust from eastern Australia. Pollution enrichment factors for these metals in dusts were calculated with a high degree of certainty, because the specific source regions of the dust could be identified. Rates of trace metal pollution transport were then calculated using a record of Australian dust transport over New Zealand. Results show that significant concentrations of trace metal pollutants are transported to New Zealand at levels that are between 1.5 and 100 times background conditions. Results also show that Sb, Pb and Cr are highly particle reactive and their transport in this region is almost exclusively associated with dust scavenging (up-take of pollutants by dust). By comparison, Cu, Zn, Cd, Sn and Ni may also be transported independently of dust. While the rates of pollution metal transport reported here are lower than in more industrialised regions of the globe, the majority of these metals are being deposited in a region internationally recognised for its environmental and conservation values

Differentiated impact melt sheets may be a potential source of Hadean detrital zircon: Reply

Open access on publisher website

The tectono-metamorphic event at 2 Ga in the Limpopo Belt and the resetting behaviour of chronometers at high temperature

Structural observations with garnet and monazite dates from the Messina area, Central Zone of the Limpopo Belt, are presented, as well as Rb-Sr and zircon ages from the Transition Zone between the Triangle shear zone and the Northern Marginal zone. It is shown that the 2.57 Ga Bulai pluton NW of Messina is deformed by a later high grade event involving minor local remelting. Within samples, monazite concordia ages broadly concur with garnet-feldspar Pb-Pb results. In some samples they document full resetting of both chronometers at 2.0 Ga, but in some they display mixed ages indicating pre-existing parageneses of at least 2.6 Ga. An overview in histogram form of available age results from the Limpopo Belt shows peaks at 2.6-2.7 Ga in the Northern and Southern Marginal Zones but not in the Central Zone, and a peak at 2.0 in all three zones, indicating that the 2.0 Ga event is the first episode common to the three zones of the Limpopo Belt.</p

A new compositional estimate for refractory lower continental crust with implications for the first terrestrial Pb-isotope paradox

The lower continental crust, representing up to 50% of the continental mass, is largely inaccessible, making its composition difficult to constrain. Previous composite models based on geophysical evidence and geochemical data of granulite terrains and xenoliths have proposed varying results, from a mafic, relatively refractory lower crust to an intermediate-felsic, more enriched composition. Here, we investigated the mineralogy and geochemistry of predominantly mafic granulite xenoliths from eastern Australia and the Kola Peninsula, Russia, using an in situ analytical approach that minimises host magma contamination. The resulting xenolith compositions are variably and often strongly depleted in most highly incompatible trace elements, including the heat-producing elements. These xenoliths represent an extremely refractory component of the lower continental crust, likely formed after high degrees of partial melting or crystallisation from a depleted source. A lower crust composed solely of this refractory endmember would be too exhausted in heat-producing elements to satisfy heat-flow constraints. However, a volumetrically significant component of the lower crust is this mafic and refractory material, combined with undifferentiated material and a felsic or metapelitic portion. Using geophysical constraints on proportions of refractory (55%), undepleted (38%) and enriched (7%) components, a new estimate for average lower continental crust that satisfies heat flow limits was calculated, including for elements such as Be, B, Cs, W and Tl, where previous estimates relied on very few data. Finally, we show that because much of the lower continental crust is so refractory and depleted in incompatible elements, it is unlikely to be a reservoir that can balance radiogenic isotope (unradiogenic Pb) and trace element ratios (e.g. Rb/Cs, Nb/Ta) for which bulk silicate Earth departs from chondritic ratios