2,066 research outputs found
Single-particle and collective slow dynamics of colloids in porous confinement
Using molecular dynamics simulations we study the slow dynamics of a hard
sphere fluid confined in a disordered porous matrix. The presence of both
discontinuous and continuous glass transitions as well as the complex interplay
between single-particle and collective dynamics are well captured by a recent
extension of mode-coupling theory for fluids in porous media. The degree of
universality of the mode-coupling theory predictions for related models of
colloids is studied by introducing size-disparity between fluid and matrix
particles, as well as softness in the interactions.Comment: 4 pages, 5 figures, minor revision
Computer Assembly of Cluster-Forming Amphiphilic Dendrimers
Recent theoretical studies have predicted a new clustering mechanism for soft
matter particles that interact via a certain kind of purely repulsive, bounded
potentials. At sufficiently high densities, clusters of overlapping particles
are formed in the fluid, which upon further compression crystallize into cubic
lattices with density-independent lattice constants. In this work we show that
amphiphilic dendrimers are suitable colloids for the experimental realization
of this phenomenon. Thereby, we pave the way for the synthesis of such
macromolecules, which form the basis for a novel class of materials with
unusual properties.Comment: 4 pages, 4 figures, 1 tabl
Thermodynamically self-consistent liquid state theories for systems with bounded potentials
The mean spherical approximation (MSA) can be solved semi-analytically for
the Gaussian core model (GCM) and yields - rather surprisingly - exactly the
same expressions for the energy and the virial equations. Taking advantage of
this semi-analytical framework, we apply the concept of the self-consistent
Ornstein-Zernike approximation (SCOZA) to the GCM: a state-dependent function K
is introduced in the MSA closure relation which is determined to enforce
thermodynamic consistency between the compressibility route and either the
virial or energy route. Utilizing standard thermodynamic relations this leads
to two different differential equations for the function K that have to be
solved numerically. Generalizing our concept we propose an
integro-differential-equation based formulation of the SCOZA which, although
requiring a fully numerical solution, has the advantage that it is no longer
restricted to the availability of an analytic solution for a particular system.
Rather it can be used for an arbitrary potential and even in combination with
other closure relations, such as a modification of the hypernetted chain
approximation.Comment: 11 pages, 11 figures, submitted to J. Chem. Phy
ShapeFit and ShapeKick for Robust, Scalable Structure from Motion
We introduce a new method for location recovery from pair-wise directions
that leverages an efficient convex program that comes with exact recovery
guarantees, even in the presence of adversarial outliers. When pairwise
directions represent scaled relative positions between pairs of views
(estimated for instance with epipolar geometry) our method can be used for
location recovery, that is the determination of relative pose up to a single
unknown scale. For this task, our method yields performance comparable to the
state-of-the-art with an order of magnitude speed-up. Our proposed numerical
framework is flexible in that it accommodates other approaches to location
recovery and can be used to speed up other methods. These properties are
demonstrated by extensively testing against state-of-the-art methods for
location recovery on 13 large, irregular collections of images of real scenes
in addition to simulated data with ground truth
Phase behaviour of a symmetrical binary fluid mixture
We have investigated the phase behaviour of a symmetrical binary fluid
mixture for the situation where the chemical potentials and of
the two species differ. Attention is focused on the set of interparticle
interaction strengths for which, when , the phase diagram exhibits
both a liquid-vapor critical point and a tricritical point. The corresponding
phase behaviour for the case is investigated via
integral-equation theory calculations within the mean spherical approximation
(MSA), and grand canonical Monte Carlo (GCMC) simulations. We find that two
possible subtypes of phase behaviour can occur, these being distinguished by
the relationship between the critical lines in the full phase diagram in the
space of temperature, density, and concentration. We present the detailed form
of the phase diagram for both subtypes and compare with the results from GCMC
simulations, finding good overall agreement. The scenario via which one subtype
evolves into the other, is also studied, revealing interesting features.Comment: 22 pages, 13 figure
Assessment of processing technologies which may improve the nutritional composition of dairy products – Overview of progress
Among consumers there is a growing demand for food products with a natural nutritional-physiological advantage over comparable conventional products. As part of an EU funded project, ALP is examining the possible impact of processing on nutritionally valuable milk components, using the example of conjugated linoleic acids (CLA). The extent to which processing influences the CLA content of the end product was determined by literature research and own investigations of organic and conventional butter. Furthermore, new chemical, sensory-based and bio crystallization methods were evaluated by ALP and the University of Kassel to determine the oxidation stability of butter. In a further step the storage stability of CLA enriched and conventional butter was examined and the different methods will be compared. As a third objective a process for low-input CLA enrichment of milk fat (with a focus on alpine butter) has been developed. Since the process selected for the work is a physical enrichment process, it is accepted by international organic farming and food groups. Among the many benefits ascribed to CLA, it is believed to be an effective agent against cancer. The demand for foods with properties that promote human health is growing. The dairy industry has the opportunity to meet this demand by developing new dairy products with a nutritional-physiological function for the functional food market
Sine-Gordon on a wormhole
In an attempt to understand the soliton resolution conjecture, we consider
the Sine-Gordon equation on a spherically symmetric wormhole spacetime. We show
that within each topological sector (indexed by a positive integer degree )
there exists a unique linearly stable soliton, which we call the -kink. We
give numerical evidence that the -kink is a global attractor in the
evolution of any smooth, finite energy solutions of degree . When the radius
of the wormhole throat is large enough, the convergence to the -kink is
shown to be governed by internal modes that slowly decay due to the resonant
transfer of energy to radiation. We compute the exact asymptotics of this
relaxation process for the -kink using the Soffer-Weinstein weakly nonlinear
perturbation theory
Why do ultrasoft repulsive particles cluster and crystallize? Analytical results from density functional theory
We demonstrate the accuracy of the hypernetted chain closure and of the
mean-field approximation for the calculation of the fluid-state properties of
systems interacting by means of bounded and positive-definite pair potentials
with oscillating Fourier transforms. Subsequently, we prove the validity of a
bilinear, random-phase density functional for arbitrary inhomogeneous phases of
the same systems. On the basis of this functional, we calculate analytically
the freezing parameters of the latter. We demonstrate explicitly that the
stable crystals feature a lattice constant that is independent of density and
whose value is dictated by the position of the negative minimum of the Fourier
transform of the pair potential. This property is equivalent with the existence
of clusters, whose population scales proportionally to the density. We
establish that regardless of the form of the interaction potential and of the
location on the freezing line, all cluster crystals have a universal Lindemann
ratio L = 0.189 at freezing. We further make an explicit link between the
aforementioned density functional and the harmonic theory of crystals. This
allows us to establish an equivalence between the emergence of clusters and the
existence of negative Fourier components of the interaction potential. Finally,
we make a connection between the class of models at hand and the system of
infinite-dimensional hard spheres, when the limits of interaction steepness and
space dimension are both taken to infinity in a particularly described fashion.Comment: 19 pages, 5 figures, submitted to J. Chem. Phys; new version: minor
changes in structure of pape
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