330 research outputs found
Three-dimensional Binary Superlattices of Oppositely-charged Colloids
We report the equilibrium self-assembly of binary crystals of
oppositely-charged colloidal microspheres at high density. By varying the
magnitude of the charge on near equal-sized spheres we show that the structure
of the binary crystal may be switched between face-centered cubic, cesium
chloride and sodium chloride. We interpret these transformations in terms of a
competition between entropic and Coulombic forces
Modelling colloids with Baxter's adhesive hard sphere model
The structure of the Baxter adhesive hard sphere fluid is examined using
computer simulation. The radial distribution function (which exhibits unusual
discontinuities due to the particle adhesion) and static structure factor are
calculated with high accuracy over a range of conditions and compared with the
predictions of Percus--Yevick theory. We comment on rigidity in percolating
clusters and discuss the role of the model in the context of experiments on
colloidal systems with short-range attractive forces.Comment: 14 pages, 7 figures. (For proceedings of "Structural arrest in
colloidal systems with short-range attractive forces", Messina, December
2003
Equilibrium phase behavior of polydisperse hard spheres
We calculate the phase behavior of hard spheres with size polydispersity,
using accurate free energy expressions for the fluid and solid phases. Cloud
and shadow curves, which determine the onset of phase coexistence, are found
exactly by the moment free energy method, but we also compute the complete
phase diagram, taking full account of fractionation effects. In contrast to
earlier, simplified treatments we find no point of equal concentration between
fluid and solid or re-entrant melting at higher densities. Rather, the fluid
cloud curve continues to the largest polydispersity that we study (14%); from
the equilibrium phase behavior a terminal polydispersity can thus only be
defined for the solid, where we find it to be around 7%. At sufficiently large
polydispersity, fractionation into several solid phases can occur, consistent
with previous approximate calculations; we find in addition that coexistence of
several solids with a fluid phase is also possible
On chemiluminescent emission from an infiltrated chiral sculptured thin film
The theory describing the far-field emission from a dipole source embedded
inside a chiral sculptured thin film (CSTF), based on a spectral Green function
formalism, was further developed to allow for infiltration of the void regions
of the CSTF by a fluid. In doing so, the extended Bruggeman homogenization
formalism--which accommodates constituent particles that are small compared to
wavelength but not vanishingly small--was used to estimate the relative
permittivity parameters of the infiltrated CSTF. For a numerical example, we
found that left circularly polarized (LCP) light was preferentially emitted
through one face of the CSTF while right circularly polarized (RCP) light was
preferentially emitted through the opposite face, at wavelengths within the
Bragg regime. The centre wavelength for the preferential emission of LCP/RCP
light was red shifted as the refractive index of the infiltrating fluid
increased from unity, and this red shift was accentuated when the size of the
constituent particles in our homogenization model was increased. Also, the
bandwidth of the preferential LCP/RCP emission regime decreased as the
refractive index of the infiltrating fluid increased from unity
Spontaneous Magnetization of the O(3) Ferromagnet at Low Temperatures
We investigate the low-temperature behavior of ferromagnets with a
spontaneously broken symmetry O(3) O(2). The analysis is performed within
the perspective of nonrelativistic effective Lagrangians, where the dynamics of
the system is formulated in terms of Goldstone bosons. Unlike in a
Lorentz-invariant framework (chiral perturbation theory), where loop graphs are
suppressed by two powers of momentum, loops involving ferromagnetic spin waves
are suppressed by three momentum powers. The leading coefficients of the
low-temperature expansion for the partition function are calculated up to order
. In agreement with Dyson's pioneering microscopic analysis of the
cubic ferromagnet, we find that, in the spontaneous magnetization, the
magnon-magnon interaction starts manifesting itself only at order . The
striking difference with respect to the low-temperature properties of the O(3)
antiferromagnet is discussed from a unified point of view, relying on the
effective Lagrangian technique.Comment: 23 pages, 4 figure
Weighted-density approximation for general nonuniform fluid mixtures
In order to construct a general density-functional theory for nonuniform
fluid mixtures, we propose an extension to multicomponent systems of the
weighted-density approximation (WDA) of Curtin and Ashcroft [Phys. Rev. A 32,
2909 (1985)]. This extension corrects a deficiency in a similar extension
proposed earlier by Denton and Ashcroft [Phys. Rev. A 42, 7312 (1990)], in that
that functional cannot be applied to the multi-component nonuniform fluid
systems with spatially varying composition, such as solid-fluid interfaces. As
a test of the accuracy of our new functional, we apply it to the calculation of
the freezing phase diagram of a binary hard-sphere fluid, and compare the
results to simulation and the Denton-Ashcroft extension.Comment: 4 pages, 4 figures, to appear in Phys. Rev. E as Brief Repor
Ювілей Михайла Миколайовича Тарана
18 жовтня 2008 р. виповнилося 60 років відомому українському вченому-мінералогу, знаному в світі фахівцю в галузі фізики мінералів, доктору геолого-мінералогічних наук Михайлові Миколайовичу Тарану
High Magnetic Field NMR Studies of LiVGeO, a quasi 1-D Spin System
We report Li pulsed NMR measurements in polycrystalline and single
crystal samples of the quasi one-dimensional S=1 antiferromagnet
LiVGeO, whose AF transition temperature is K.
The field () and temperature () ranges covered were 9-44.5 T and
1.7-300 K respectively. The measurements included NMR spectra, the spin-lattice
relaxation rate (), and the spin-phase relaxation rate (),
often as a function of the orientation of the field relative to the crystal
axes. The spectra indicate an AF magnetic structure consistent with that
obtained from neutron diffraction measurements, but with the moments aligned
parallel to the c-axis. The spectra also provide the -dependence of the AF
order parameter and show that the transition is either second order or weakly
first order. Both the spectra and the data show that has at
most a small effect on the alignment of the AF moment. There is no spin-flop
transition up to 44.5 T. These features indicate a very large magnetic
anisotropy energy in LiVGeO with orbital degrees of freedom playing an
important role. Below 8 K, varies substantially with the orientation
of in the plane perpendicular to the c-axis, suggesting a small energy
gap for magnetic fluctuations that is very anisotropic.Comment: submitted to Phys. Rev.
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