6 research outputs found
The Weakness of the Internet Mail System and a Proposal of N ew Mail Transfer Agent
This paper presents a framework of implementing Mail Transfer Agent(MTA) for Small office/Home office and aims at the improvement of the security of e-mail server. We simplify the setting file of our MTA to reduce setting errors, because difficult settings cause setting errors and occur security holes. This MTA has limits relaying function of mails in order to prohibit SPAM mail relay. And we limit a size of received mail for the counter measures of mail bomb. Experimental results indicate that, this MTA has high security. And the MTA was evaluated that the settings of the MTA are very easy, and that this MTA is convenient in spite of the minimum functions
Direct Observation of Active Nickel Oxide Cluster in Nickel–Borate Electrocatalyst for Water Oxidation by In Situ O K‑Edge X‑ray Absorption Spectroscopy
In situ O K-edge X-ray absorption
fine structure (XAFS) spectroscopy
was applied to investigate the electronic and structural change in
the nickel–borate (Ni–B<sub>i</sub>) electrocatalyst
during the oxygen evolution reaction (OER). An absorption peak was
observed around 528.7 eV at 1.0 V versus Ag/AgCl in a potassium borate
aqueous solution, which relates with the formation of nanoscale order
domains of edge-sharing NiO<sub>6</sub> octahedra in the Ni–B<sub>i</sub> electrocatalyst. XAFS spectra were measured with variation
of the electrode potential from 0.3 up to 1.0 V. The measured absorption
peaks suggest that the quantity of NiO<sub>6</sub> octahedra increased
in correlation with the OER current; however, when the potential was
changed downward, the XAFS absorption peak assigned to NiO<sub>6</sub> octahedra remained constant, even at the electrode potential for
no OER current. This difference implies that the water oxidation catalysis
proceeds at the domain edge of NiO<sub>6</sub> octahedra. The XAFS
technique provides the first successful direct probing of the active
species in the Ni–B<sub>i</sub> electrocatalyst during electrochemical
reaction