422 research outputs found
Replicating Nanostructures on Silicon by Low Energy Ion Beams
We report on a nanoscale patterning method on Si substrates using
self-assembled metal islands and low-energy ion-beam irradiation. The Si
nanostructures produced on the Si substrate have a one-to-one correspondence
with the self-assembled metal (Ag, Au, Pt) nanoislands initially grown on the
substrate. The surface morphology and the structure of the irradiated surface
were studied by high-resolution transmission electron microscopy (HRTEM). TEM
images of ion-beam irradiated samples show the formation of sawtooth-like
structures on Si. Removing metal islands and the ion-beam induced amorphous Si
by etching, we obtain a crystalline nanostructure of Si. The smallest
structures emit red light when exposed to a UV light. The size of the
nanostructures on Si is governed by the size of the self-assembled metal
nanoparticles grown on the substrate for this replica nanopatterning. The
method can easily be extended for tuning the size of the Si nanostructures by
the proper choice of the metal nanoparticles and the ion energy in
ion-irradiation. It is suggested that off-normal irradiation can also be used
for tuning the size of the nanostructures.Comment: 12 pages, 7 figures, regular paper submitted to Nanotechnolog
The composition and technology of polychrome enamels on Chinese ruby‐backed plates identified through nondestructive micro‐X‐ray fluorescence
This research presents non‐destructive analyses of Chinese enamelled copper and porcelain decorated with polychrome enamels. This study utilises two key, high‐value art works with complex enamelling in the collection of the Victoria and Albert Museum (London, UK) to elucidate the composition and technology of objects with ruby‐backed decoration. These plates date from early Qing dynasty and are associated with the Yongzheng (1723–1735) and early Qianlong (1735–1796) periods. The goal of this research is to investigate the hypothesis that ruby‐backed plates in these two mediums are decorated with the same enamels and possibly manufactured in mutual enamelling workshops, which is a current topic of debate among scholars. Ten different enamel colours and the gilding on each plate were analysed and evaluated with micro‐X‐ray fluorescence to study the opacifiers and pigments. The results show that the enamels on these two works utilise the same opacifier and the consistent pigments in the white, ruby, pink, green, yellow, turquoise green, and blue enamels. Compositional differences were identified in the underdrawings, purple enamels, and gilding. The results demonstrate that Chinese painted enamels and overglazes on porcelain share mutual technology in most, but not all, of the polychrome decoration, which impacts upon our knowledge of technological organisation in the manufacture of these objects. Micro‐X‐ray fluorescence has been shown to be an effective and robust technique for the nondestructive study of decorative surfaces in these two material types
Transformation of Quartz to Tridymite in the Presence of Binary Silicate Liquids
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/66429/1/j.1151-2916.1967.tb15146.x.pd
Synthesis of Glass Nanofibers Using Femtosecond Laser Radiation Under Ambient Condition
We report the unique growth of nanofibers in silica and borosilicate glass using femtosecond laser radiation at 8 MHz repetition rate and a pulse width of 214 fs in air at atmospheric pressure. The nanofibers are grown perpendicular to the substrate surface from the molten material in laser-drilled microvias where they intertwine and bundle up above the surface. The fibers are few tens of nanometers in thickness and up to several millimeters in length. Further, it is found that at some places nanoparticles are attached to the fiber surface along its length. Nanofiber growth is explained by the process of nanojets formed in the molten liquid due to pressure gradient induced from the laser pulses and subsequently drawn into fibers by the intense plasma pressure. The attachment of nanoparticles is due to the condensation of vapor in the plasma
Relative energetics and structural properties of zirconia using a self-consistent tight-binding model
We describe an empirical, self-consistent, orthogonal tight-binding model for
zirconia, which allows for the polarizability of the anions at dipole and
quadrupole levels and for crystal field splitting of the cation d orbitals.
This is achieved by mixing the orbitals of different symmetry on a site with
coupling coefficients driven by the Coulomb potentials up to octapole level.
The additional forces on atoms due to the self-consistency and polarizabilities
are exactly obtained by straightforward electrostatics, by analogy with the
Hellmann-Feynman theorem as applied in first-principles calculations. The model
correctly orders the zero temperature energies of all zirconia polymorphs. The
Zr-O matrix elements of the Hamiltonian, which measure covalency, make a
greater contribution than the polarizability to the energy differences between
phases. Results for elastic constants of the cubic and tetragonal phases and
phonon frequencies of the cubic phase are also presented and compared with some
experimental data and first-principles calculations. We suggest that the model
will be useful for studying finite temperature effects by means of molecular
dynamics.Comment: to be published in Physical Review B (1 march 2000
Observations from Preliminary Experiments on Spatial and Temporal Pressure Measurements from Near-Field Free Air Explosions
It is self-evident that a crucial step in analysing the performance of protective structures is to be able to accurately quantify the blast load arising from a high explosive detonation. For structures located near to the source of a high explosive detonation, the resulting pressure is extremely high in magnitude and highly non-uniform over the face of the target. There exists very little direct measurement of blast parameters in the nearfield, mainly attributed to the lack of instrumentation sufficiently robust to survive extreme loading events yet sensitive enough to capture salient features of the blast. Instead literature guidance is informed largely by early numerical analyses and parametric studies. Furthermore, the lack of an accurate, reliable data set has prevented subsequent numerical analyses from being validated against experimental trials. This paper presents an experimental methodology that has been developed in part to enable such experimental data to be gathered. The experimental apparatus comprises an array of Hopkinson pressure bars, fitted through holes in a target, with the loaded faces of the bars flush with the target face. Thus, the bars are exposed to the normally or obliquely reflected shocks from the impingement of the blast wave with the target. Pressure-time recordings are presented along with associated Arbitary-Langrangian-Eulerian modelling using the LS-DYNA explicit numerical code. Experimental results are corrected for the effects of dispersion of the propagating waves in the pressure bars, enabling accurate characterisation of the peak pressures and impulses from these loadings. The combined results are used to make comments on the mechanism of the pressure load for very near-field blast events
High-performance shape-engineerable thermoelectric painting
Output power of thermoelectric generators depends on device engineering minimizing heat loss as well as inherent material properties. However, the device engineering has been largely neglected due to the limited flat or angular shape of devices. Considering that the surface of most heat sources where these planar devices are attached is curved, a considerable amount of heat loss is inevitable. To address this issue, here, we present the shape-engineerable thermoelectric painting, geometrically compatible to surfaces of any shape. We prepared Bi2Te3-based inorganic paints using the molecular Sb2Te3 chalcogenidometalate as a sintering aid for thermoelectric particles, with ZT values of 0.67 for n-type and 1.21 for p-type painted materials that compete the bulk values. Devices directly brush-painted onto curved surfaces produced the high output power of 4.0 mW cm(-2). This approach paves the way to designing materials and devices that can be easily transferred to other applications.ope
Supporting the education and wellbeing of children looked-after: what is the role of the virtual school?
The Children and Families Act (2014) placed a statutory responsibility on local authorities in the United Kingdom to establish a Virtual School Headteacher with the role of championing the education of all children looked-after within that authority. The current research was designed to illuminate how Virtual Schools are currently supporting educational outcomes for children looked-after, not only through educational interventions, but also through supporting broader psychological factors that might impact on attainment such as attachment, relationships and mental health. Virtual School Head Teachers from 29 local authorities completed an online survey about the services they provided to three target groups – children looked-after, foster carers and schools – with a particular focus on the transition years from primary to secondary school, which have been identified as being a difficult time for children looked-after. Using inductive thematic analysis four overarching themes to service provision were identified: Enhanced learning opportunities; Specific Transition Support; Wellbeing and Relationships, and Raising Awareness. Direct work, interprofessional working and the development of supportive environments, particularly guided by attachment theory, were identified as important areas of practice. Practice is discussed in relation to resilience and ecological systems theory and suggestions for future research are identified
The big problem of small particles : a comparison of methods for determination of particle size in nanocrystalline anatase powders
We compare different methods for particle size determination in nanocrystalline anatase (TiO2) powders: transmission electron microscopy (TEM), nitrogen adsorption measurements, mercury porosimetry, and X-ray diffraction(XRD). The main source of errors in TEM is the sampling of the powder population, whereas in XRD the deconvolution of peak broadening due to instrument, microstrains, and crystalline domain size is delicate and can lead to unreliable results. Different approaches including Scherrer and Williamson-Hall equations are discussed. The presence of mesopores due to agglomerate formation is clearly revealed in adsorption measurements and porosimetry
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