X-ray and infrared studies of several ruthenium-sulfur dioxide complexes

X-ray and infrared data on crystal and molecular structure of ruthenium-sulfur dioxide complexe

The crystal and molecular structure of ruthenium-sulfur dioxide coordination compounds. i- chlorotetraammine/sulfur dioxide/-ruthenium/ii/ chloride

Crystal and molecular structure of ruthenium- ammonia coordination compound

Three-dimensional calculation of shuttle charging in polar orbit

The charged particles environment in polar orbit can be of sufficient intensity to cause spacecraft charging. In order to gain a quantitative understanding of such effects, the Air Force is developing POLAR, a computer code which simulates in three dimensions the electrical interaction of large space vehicles with the polar ionospheric plasma. It models the physical processes of wake generation, ambient ion collection, precipitating auroral electron fluxes, and surface interactions, including secondary electron generation and backscattering, which lead to vehicle charging. These processes may be followed dynamically on a subsecond timescale so that the rapid passage through intense auroral arcs can be simulated. POLAR models the ambient plasma as isotropic Maxwellian electrons and ions (0+, H+), and allows for simultaneous precipitation of power-law, energetic Maxwellian, and accelerated Gaussian distributions of electrons. Magnetic field effects will be modeled in POLAR but are currently ignored

Growth, Characterization, and Electrochemical Properties of Doped n-Type KTaO_3 Photoanodes

The effects of compositionally induced changes on the semiconducting properties, optical response, chemical stability, and overall performance of KTaO_3 photoanodes in photoelectrochemical (PEC) cells have been investigated. Single crystals of n-type Ca- and Ba-doped KTaO_3 with carrier concentrations ranging from 0.45 to 11.5×10^(19) cm^(−3) were grown and characterized as photoanodes in basic aqueous electrolyte PEC cells. The PEC properties of the crystals, including the photocurrent, photovoltage, and flatband potential in contact with 8.5 M NaOH(aq) were relatively independent of whether Ca or Ba was used to produce the semiconducting form of KTaO_3. All of the Ca- or Ba-doped KTaO_3 single-crystal photoanodes were chemically stable in the electrolyte and, based on the open-circuit potential and the band-edge positions, were capable of unassisted photochemical H_2 and O_2 evolution from H_2O. The minority-carrier diffusion lengths values were small and comparable to the depletion region width. Photoanodic currents were only observed for photoanode illumination with light above the bandgap (i.e., λ<340 nm). The maximum external quantum yield occurred at λ=255 nm (4.85 eV), and the depletion width plus the minority-carrier diffusion length ranged from 20 to 65 nm for the various KTaO_3-based photoanode materials

Quasilocal Energy for a Kerr black hole

The quasilocal energy associated with a constant stationary time slice of the Kerr spacetime is presented. The calculations are based on a recent proposal \cite{by} in which quasilocal energy is derived from the Hamiltonian of spatially bounded gravitational systems. Three different classes of boundary surfaces for the Kerr slice are considered (constant radius surfaces, round spheres, and the ergosurface). Their embeddings in both the Kerr slice and flat three-dimensional space (required as a normalization of the energy) are analyzed. The energy contained within each surface is explicitly calculated in the slow rotation regime and its properties discussed in detail. The energy is a positive, monotonically decreasing function of the boundary surface radius. It approaches the Arnowitt-Deser-Misner (ADM) mass at spatial infinity and reduces to (twice) the irreducible mass at the horizon of the Kerr black hole. The expressions possess the correct static limit and include negative contributions due to gravitational binding. The energy at the ergosurface is compared with the energies at other surfaces. Finally, the difficulties involved in an estimation of the energy in the fast rotation regime are discussed.Comment: 22 pages, Revtex, Alberta-Thy-18-94. (the approximations in Section IV have been improved. To appear in Phys. Rev. D