Magnetic ordering, electronic structure and magnetic anisotropy energy in the high-spin Mn10_{10} single molecule magnet

We report the electronic structure and magnetic ordering of the single molecule magnet [Mn$_{10}$O$_{4}$(2,2'-biphenoxide)$_{4}$Br$_{12}$]$^{4-}$ based on first-principles all-electron density-functional calculations. We find that two of the ten core Mn atoms are coupled antiferromagnetically to the remaining eight, resulting in a ferrimagnetic ground state with total spin S=13. The calculated magnetic anisotropy barrier is found to be 9 K in good agreement with experiment. The presence of the Br anions impact the electronic structure and therefore the magnetic properties of the 10 Mn atoms. However, the electric field due to the negative charges has no significant effect on the magnetic anisotropy.Comment: 4 pages, submitted to PR

Magnetic Field Induced Spin Polarization of AlAs Two-dimensional Electrons

Two-dimensional (2D) electrons in an in-plane magnetic field become fully spin polarized above a field B_P, which we can determine from the in-plane magnetoresistance. We perform such measurements in modulation-doped AlAs electron systems, and find that the field B_P increases approximately linearly with 2D electron density. These results imply that the product |g*|m*, where g* is the effective g-factor and m* the effective mass, is a constant essentially independent of density. While the deduced |g*|m* is enhanced relative to its band value by a factor of ~ 4, we see no indication of its divergence as 2D density approaches zero. These observations are at odds with results obtained in Si-MOSFETs, but qualitatively confirm spin polarization studies of 2D GaAs carriers.Comment: 4 pages, 5 figure

Quantum-classical transition of the escape rate of uniaxial antiferromagnetic particles in an arbitrarily directed field

Quantum-classical escape rate transition has been studied for uniaxial antiferromagnetic particles with an arbitrarily directed magnetic field. In the case that the transverse and longitudinal fileds coexist, we calculate the phase boundary line between first- and second-order transitions, from which phase diagrams can be obtained. It is shown that the effects of the applied longitudinal magnetic field on quantum-classical transition vary greatly for different relative magnitudes of the non-compensation.Comment: to be appeared in Phys. Rev.

Tunneling with dissipation and decoherence for a large spin

We present rigorous solution of problems of tunneling with dissipation and decoherence for a spin of an atom or a molecule in an isotropic solid matrix. Our approach is based upon switching to a rotating coordinate system coupled to the local crystal field. We show that the spin of a molecule can be used in a qubit only if the molecule is strongly coupled with its atomic environment. This condition is a consequence of the conservation of the total angular momentum (spin + matrix), that has been largely ignored in previous studies of spin tunneling.Comment: 4 page

Semiconductive and Photoconductive Properties of the Single Molecule Magnets Mn12_{12}-Acetate and Fe8_8Br8_8

Resistivity measurements are reported for single crystals of Mn$_{12}$-Acetate and Fe$_8$Br$_8$. Both materials exhibit a semiconductor-like, thermally activated behavior over the 200-300 K range. The activation energy, $E_a$, obtained for Mn$_{12}$-Acetate was 0.37 $\pm$ 0.05 eV, which is to be contrasted with the value of 0.55 eV deduced from the earlier reported absorption edge measurements and the range of 0.3-1 eV from intramolecular density of states calculations, assuming $2E_a$= $E_g$, the optical band gap. For Fe$_8$Br$_8$, $E_a$ was measured as 0.73 $\pm$ 0.1 eV, and is discussed in light of the available approximate band structure calculations. Some plausible pathways are indicated based on the crystal structures of both lattices. For Mn$_{12}$-Acetate, we also measured photoconductivity in the visible range; the conductivity increased by a factor of about eight on increasing the photon energy from 632.8 nm (red) to 488 nm (blue). X-ray irradiation increased the resistivity, but $E_a$ was insensitive to exposure.Comment: 7 pages, 8 figure

Nonequilibrium dynamics and superfluid ring excitations in binary Bose-Einstein condensates

We revisit a classic study of interpenetrating Bose-Einstein condensates in the hyperfine states |F=1,mf=-1 |1 and |F=2,mf=+1 |2 of Rb87 and observe striking new nonequilibrium component separation dynamics in the form of oscillating ringlike structures. The process of component separation is not significantly damped, a finding that also contrasts sharply with earlier experimental work, allowing a clean first look at a collective excitation of a binary superfluid. We further demonstrate extraordinary quantitative agreement between theoretical and experimental results using a multicomponent mean-field model with key additional features: the inclusion of atomic losses and the careful characterization of trap potentials (at the level of a fraction of a percent). © 2007 The American Physical Society