75 research outputs found
Realistic description of electron-energy loss spectroscopy for One-Dimensional SrCuO
We investigate the electron-energy loss spectrum of one-dimensional undoped
CuO chains within an extended multi-band Hubbard model and an extended
one-band Hubbard model, using the standard Lanczos algorithm. Short-range
intersite Coulomb interactions are explicitly included in these models, and
long-range interactions are treated in random-phase approximation. The results
for the multi-band model with standard parameter values agree very well with
experimental spectra of SrCuO. In particular, the width of the main
structure is correctly reproduced for all values of momentum transfer. It is
shown for both models that intersite Coulomb interactions mainly lead to an
energy shift of the spectra. We find no evidence for enhanced intersite
interactions in SrCuO.Comment: 4 pages, 4 figure
Sr2V3O9 and Ba2V3O9: quasi one-dimensional spin-systems with an anomalous low temperature susceptibility
The magnetic behaviour of the low-dimensional Vanadium-oxides Sr2V3O9 and
Ba2V3O9 was investigated by means of magnetic susceptibility and specific heat
measurements. In both compounds, the results can be very well described by an
S=1/2 Heisenberg antiferromagnetic chain with an intrachain exchange of J = 82
K and J = 94 K in Sr2V3O9 and Ba2V3O9, respectively. In Sr2V3O9,
antiferromagnetic ordering at T_N = 5.3 K indicate a weak interchain exchange
of the order of J_perp ~ 2 K. In contrast, no evidence for magnetic order was
found in Ba2V3O9 down to 0.5 K, pointing to an even smaller interchain
coupling. In both compounds, we observe a pronounced Curie-like increase of the
susceptibility below 30 K, which we tentatively attribute to a staggered field
effect induced by the applied magnetic field. Results of LDA calculations
support the quasi one-dimensional character and indicate that in Sr2V3O9, the
magnetic chain is perpendicular to the structural one with the magnetic
exchange being transferred through VO4 tetrahedra.Comment: Submitted to Phy. Rev.
Separation of the magnetic phases at the N\'{e}el point in the diluted spin-Peierls magnet CuGeO3
The impurity induced antiferromagnetic ordering of the doped spin-Peierls
magnet Cu(1-x)Mg(x)GeO(3) was studied by ESR technique. Crystals with the Mg
concentration x<4% demonstrate a coexistence of paramagnetic and
antiferromagnetic ESR modes. This coexistence indicates the separation of a
macroscopically uniform sample in the paramagnetic and antiferromagnetic
phases. In the presence of the long-range spin-Peierls order (in a sample with
x=1.71%) the volume of the antiferromagnetic phase immediately below the
N\'{e}el point T_N is much smaller than the volume of the paramagnetic phase.
In the presence of the short-range spin-Peierls order (in samples with x=2.88%,
x= 3.2%) there are comparable volumes of paramagnetic and antiferromagnetic
phases at T=T_N. The fraction of the antiferromagnetic phase increases with
lowering temperature. In the absence of the spin-Peierls dimerization (at
x=4.57%)the whole sample exhibits the transition into the antiferromagnetic
state and there is no phase separation. The phase separation is explained by
the consideration of clusters of staggered magnetization located near impurity
atoms. In this model the areas occupied by coherently correlated spins expand
with decreasing temperature and the percolation of the ordered area through a
macroscopic distance occurs.Comment: 7pages, 10 figure
Hidden magnetic transitions in thermoelectric layered cobaltite, [CaCoO][CoO]
A positive muon spin rotation and relaxation (SR) experiment on
[CaCoO][CoO], ({\sl i.e.}, CaCoO, a layered
thermoelectric cobaltite) indicates the existence of two magnetic transitions
at 100 K and 400 - 600 K; the former is a transition from a paramagnetic
state to an incommensurate ({\sf IC}) spin density wave ({\sf SDW}) state. The
anisotropic behavior of zero-field SR spectra at 5 K suggests that the
{\sf IC-SDW} propagates in the - plane, with oscillating moments directed
along the c-axis; also the {\sf IC-SDW} is found to exist not in the
[CaCoO] subsystem but in the [CoO] subsystem. In addition, it is
found that the long-range {\sf IC-SDW} order completes below 30 K,
whereas the short-range order appears below 100 K. The latter transition is
interpreted as a gradual change in the spin state of Co ions %% at temperatures
above 400 K. These two magnetic transitions detected by SR are found to
correlate closely with the transport properties of
[CaCoO][CoO].Comment: 7 pages, 8 figures. to be appeared in Phys. Rev.
Cu Nuclear Quadrupole Resonance Study of the Spin-Peierls Compound Cu1-xMgxGeO3: A Possibility of Precursory Dimerization
We report on a zero-field 63Cu nuclear quadrupole resonance (NQR) study of
nonmagnetic Mg impurity substituted Cu1-xMgxGeO3 (single crystals; the
spin-Peierls transition temperature Tsp~14, 13.5, and 11 K for x=0, 0.0043, and
0.020) in a temperature range from 4.2 K to 250 K. We found that below T*~77 K,
Cu NQR spectra are broadened and nonexponential Cu nuclear spin-lattice
relaxation increases for undoped and more remarkably for Mg-doped samples. The
results indicate that random lattice distortion and impurity-induced spins
appear below T*, which we associate with a precursor of the spin-Peierls
transition. Conventional magnetic critical slowing down does not appear down to
4.2 K below Tsp.Comment: 4 pages, 4 figure
Prunella vulgaris: A comprehensive review of chemical constituents, pharmacological effects and clinical applications.
Prunella vulgaris (PV) is a perennial herb belonging to the Labiate family and is widely distributed in northeastern Asian countries such as Korea, Japan, and China. It is reported to display diverse biological activities including anti-microbial, anti-cancer, and anti-inflammation as determined by in vitro or in vivo studies. So far, about 200 compounds have been isolated from PV plant and majority of these have been characterized mainly as triterpenoids, sterols and flavonoids, followed by coumarins, phenylpropanoids, polysaccharides and volatile oils. This review summarizes and analyzes the current knowledge on the chemical constituents, pharmacological activities, mechanisms of action and clinical applications of the PV plant including its potential as a future medicinal plant. Although some of the chemical constituents of the PV plant and their mechanism of action have been investigated the biological activities of many of these remain unknown and further clinical trials are required to further enhance its reputation as a medicinal plant
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