Is it really organic? Authenticity testing of organic plant products using elemental and isotopic fingerprinting

The commercial market for high-value plant products is steadily increasing. Consumers are willingly paying premium prices for plants that originate from specific geographical regions or are produced according to certain agricultural management practices. This has significantly enhanced the market shares of organically grown plant products but has simultaneously increased the risk of food adulteration and fraudulent activities. Consequently, sophisticated analytical principles are currently being developed to enable discrimination of organic and conventional plants and ensure compliance with the regulations of organic agriculture. Some of the most promising principles for organic authentication are based on atomic spectroscopy which encompasses several analytical techniques suitable for analysis of the elemental and isotopic composition of plants (1). Analytical discrimination of organic and conventional plant products relies on an expectation of systematic differences in agricultural management practices. Thus, it has been hypothesized that the prohibition of pesticides and synthetically produced fertilizers in organic agriculture is reflected in the chemical composition of plants. This hypothesis was recently tested in a Danish research project called OrgTrace, in which analytical methods for elemental and isotopic fingerprinting were developed and combined with multivariate statistics for authenticity testing of organic crops (2-4). The unique experimental design of OrgTrace included numerous plant species grown either organically or conventionally at several geographical locations differing in soil type, climate etc. Furthermore, year-to-year variation was assessed by inclusion of two growth years. Results from the OrgTrace project will be presented at the seminar. Recently, the international research project AuthenticFood was initiated. In AuthenticFood novel analytical procedures will be tested and combined to enable authentication of selected organic plant products before and after processing of these. The main research hypotheses and methodologies of AuthenticFood will be presented

HOW DO WE DETERMINE PLANT QUALITY OF ORGANIC CROPS?

Plants are photoautotrophic organisms being able to synthesize all metabolites and macro-molecules on the basis of light, CO2, H2O and 14 inorganic elements taken up from the soil. As plants are confined to the environment in which they germinate, this means that the plant ionome, metabolome and proteome are heavily influenced by soil mineralogy, climate and not least agricultural management. Organic plant products within the European Union are produced according to a specific set of regulations, which e.g. implicate that organic plants are cultivated without pesticides and synthetically produced nitrogen (N) fertilizers. In addition, N fertilizers are often used in lower amounts relative to conventional agriculture. Over more than a decade it has been intensively studied whether these marked agronomical differences lead to systematic differences in the chemical composition of plant tissue and whether this has an impact on selected plant quality attributes. From a theoretical point of view the marked differences in fertilization strategies between organic and conventional agriculture will cause systematic differences in the chemical composition of plants. The differences are expected to be very large when comparing plants representing the extremes of organic and conventional agriculture. Thus, if synthetic fertilizers are used exclusively for conventional plant production and in high amounts relative to organic production based on animal manure, green manures, compost etc., the conventional plants are likely to differ from the organic ones. However, in most cases plants are not produced with such extreme fertilization strategies and differences are often masked by natural variation caused by e.g. geographical locations and growth season and thereby little difference in plant quality is usually observed. Despite the fact that systematic differences in chemical composition between organic and conventional plants are usually overridden by natural variation it was recently found that the type of N fertilizers is reflected in the isotope ratios of plants and that the isotopic fingerprints are unbiased by geographical locations and growth season. However, the fundamental differences in isotope ratios are supposedly irrelevant regarding plant quality, but have shown to be a strong signature for authentication of organic plants products. In this lecture we will further explain how the fertilization strategy can affect the underlying biochemical mechanisms controlling the chemical composition of plants and discuss how these are related to organic plant quality. Special attention will be given to N fertilizer forms and quantity, as fertilization generally appears to be the single-most parameter with the strongest impact on metabolism when comparing plants from organic and conventional agricultural systems

Sensorless multi-loop control of phase-controlled series-parallel resonant converter

This paper proposes a multi-loop controller for the phase-controlled series-parallel resonant converter. Output voltage is solely measured for control and inner loop is used to enhance closed loop stability and dynamic performance compared to single-loop control. No additional sensors are used for inner loop variables. These are estimated using a Kalman filter, based on a linearized converter model. The advantage of this sensorless scheme is not only reducing the number of sensors but more significantly providing an alternative to sensing high frequency resonant tank variables which require high microcontroller resolution in real time. First, the converter non-linear large signal behavior is linearized using a state feedback based scheme. Consequently, the converter preserves its large signal characteristics while modeled as a linear system. Comparison is made between the most suitable state variables for feedback, according to a stability study. Finally, simulation and experimental results are demonstrated to validate the improved system performance in contrast with single-loop control

Modified half-bridge modular multilevel converter for HVDC systems with DC fault ride-through capability

One of the main challenges of voltage source converter based HVDC systems is DC faults. In this paper, two different modified half-bridge modular multilevel converter topologies are proposed. The proposed converters offer a fault tolerant against the most severe pole-to-pole DC faults. The converter comprises three switches or two switches and 4 diodes in each cell, which can result in less cost and losses compared to the full-bridge modular multilevel converter. Converter structure and controls are presented including the converter modulation and capacitors balancing. MATLAB/SIMULINK simulations are carried out to verify converter operation in normal and faulty conditions

A Walsh-Fourier approach to the circulant Hadamard conjecture

We describe an approach to the circulant Hadamard conjecture based on Walsh-Fourier analysis. We show that the existence of a circulant Hadamard matrix of order $n$ is equivalent to the existence of a non-trivial solution of a certain homogenous linear system of equations. Based on this system, a possible way of proving the conjecture is proposed.Comment: 8 page

PID control system analysis and design

With its three-term functionality offering treatment of both transient and steady-state responses, proportional-integral-derivative (PID) control provides a generic and efficient solution to realworld control problems. The wide application of PID control has stimulated and sustained research and development to "get the best out of PID", and "the search is on to find the next key technology or methodology for PID tuning". This article presents remedies for problems involving the integral and derivative terms. PID design objectives, methods, and future directions are discussed. Subsequently, a computerized, simulation-based approach is presented, together with illustrative design results for first-order, higher order, and nonlinear plants. Finally, we discuss differences between academic research and industrial practice, so as to motivate new research directions in PID control

PID control system analysis, design, and technology

Designing and tuning a proportional-integral-derivative (PID) controller appears to be conceptually intuitive, but can be hard in practice, if multiple (and often conflicting) objectives such as short transient and high stability are to be achieved. Usually, initial designs obtained by all means need to be adjusted repeatedly through computer simulations until the closed-loop system performs or compromises as desired. This stimulates the development of "intelligent" tools that can assist engineers to achieve the best overall PID control for the entire operating envelope. This development has further led to the incorporation of some advanced tuning algorithms into PID hardware modules. Corresponding to these developments, this paper presents a modern overview of functionalities and tuning methods in patents, software packages and commercial hardware modules. It is seen that many PID variants have been developed in order to improve transient performance, but standardising and modularising PID control are desired, although challenging. The inclusion of system identification and "intelligent" techniques in software based PID systems helps automate the entire design and tuning process to a useful degree. This should also assist future development of "plug-and-play" PID controllers that are widely applicable and can be set up easily and operate optimally for enhanced productivity, improved quality and reduced maintenance requirements

Quark Gluon Plasma - Recent Advances

While heavy ion collisions at the SPS have produced excited strongly interacting matter near the conditions for quark deconfinement, the RHIC may be the first machine capable of creating quark-antiquark plasmas sufficiently long-lived to allow deep penetration into the new phase. A comprehensive experimental program addressing this exciting physics has been put into place. Presented here are preliminary results from Au+Au at $\sqrt{S}$ = 130 GeV obtained during the first RHIC run and some CERN SPS results from Pb+Pb at $\sqrt{S}$ = 17 GeV (particularly relevant to QGP search).Comment: 15 pages, 19 figure

The Lie algebra of infinitesimal symmetries of nonlinear diffusion equations

By using developed software for solving overdetermined systems of partial differential equations, the authors establish the complete Lie algebra of infinitesimal symmetries of nonlinear diffusion equations

Analysis and hardware testing of cell capacitor discharge currents during DC faults in half-bridge modular multilevel converters

This paper focuses on the behaviour of the cell capacitor discharge currents during DC faults in half-bridge modular multilevel converters. Active switches, not designed for fault conditions, are tripped to minimize discharge currents effect on the semiconductor switches. Two levels of device protection are commonly in place; driver level protection monitoring collector-emitter voltage and overcurrent protection with feedback measurement and control. However, unavoidable tripping delay times, arising from factors such as sensor lags, controller sampling delays and hardware propagation delays, impact transient current shape and hence affect the selection of semiconductor device ratings as well as arm inductance. Analytical expressions are obtained for current slew rate, peak transient current and resultant I2t for the cell capacitor discharge current taking into account such delays. The study is backed by experimental testing on discharge of a 900V MMC capacitor