229 research outputs found
Rotation-Induced Breakdown of Torsional Quantum Control
Control of the torsional angles of nonrigid molecules is key for the development of emerging areas like molecular electronics and nanotechnology. Based on a rigorous calculation of the rotation-torsion-Stark energy levels of nonrigid biphenyl-like molecules, we show that, unlike previously believed, instantaneous rotation-torsion-Stark eigenstates of such molecules, interacting with a strong laser field, present a large degree of delocalization in the torsional coordinate even for the lowest energy states. This is due to a strong coupling between overall rotation and torsion leading to a breakdown of the torsional alignment. Thus, adiabatic control of changes on the planarity of this kind of molecule is essentially impossible unless the temperature is on the order of a few Kelvin
Optimal design of nanoplasmonic materials using genetic algorithms as a multi-parameter optimization tool
An optimal control approach based on multiple parameter genetic algorithms is
applied to the design of plasmonic nanoconstructs with pre-determined optical
properties and functionalities. We first develop nanoscale metallic lenses that
focus an incident plane wave onto a pre-specified, spatially confined spot. Our
results illustrate the role of symmetry breaking and unravel the principles
that favor dimeric constructs for optimal light localization. Next we design a
periodic array of silver particles to modify the polarization of an incident,
linearly-polarized plane wave in a desired fashion while localizing the light
in space. The results provide insight into the structural features that
determine the birefringence properties of metal nanoparticles and their arrays.
Of the variety of potential applications that may be envisioned, we note the
design of nanoscale light sources with controllable coherence and polarization
properties that could serve for coherent control of molecular or electronic
dynamics in the nanoscale.Comment: 13 pages, 6 figures. submitted to J. Chem. Phy
Laser Induced Selective Alignment of Water Spin Isomers
We consider laser alignment of ortho and para spin isomers of water molecules
by using strong and short off-resonance laser pulses. A single pulse is found
to create a distinct transient alignment and antialignment of the isomeric
species. We suggest selective alignment of one isomeric species (leaving the
other species randomly aligned) by a pair of two laser pulses.Comment: 6 pages, 4 figures, 3 table
Utilization Of Goose Muscle In The Preparation Of Meat Rolls
South Dakota produces more domestic geese than any other state in the United States. Marketing of geese is decreasing due to importation of Canadian geese and a decreasing consumer demand. Research is needed to increase goose meat consumption. A large percentage of turkey meat is sold as retail convenience products such as rolls, yet there are virtually no comparable products on the market from goose meat. This study was undertaken to develop and evaluate an acceptable goose roll
Coherently Controlled Nanoscale Molecular Deposition
Quantum interference effects are shown to provide a means of controlling and
enhancing the focusing a collimated neutral molecular beam onto a surface. The
nature of the aperiodic pattern formed can be altered by varying laser field
characteristics and the system geometry.Comment: 13 pages (inculding 4 figures), LaTeX (Phys. Rev. Lett., 2000, in
Press
Controlling the sense of molecular rotation
We introduce a new scheme for controlling the sense of molecular rotation. By
varying the polarization and the delay between two ultrashort laser pulses, we
induce unidirectional molecular rotation, thereby forcing the molecules to
rotate clockwise/counterclockwise under field-free conditions. We show that
unidirectionally rotating molecules are confined to the plane defined by the
two polarization vectors of the pulses, which leads to a permanent anisotropy
in the molecular angular distribution. The latter may be useful for controlling
collisional cross-sections and optical and kinetic processes in molecular
gases. We discuss the application of this control scheme to individual
components within a molecular mixture in a selective manner.Comment: 21 pages, 10 figures, Submitted to the New Journal of Physics for the
"coherent control" special issu
Tunneling Ionization Rates from Arbitrary Potential Wells
We present a practical numerical technique for calculating tunneling
ionization rates from arbitrary 1-D potential wells in the presence of a linear
external potential by determining the widths of the resonances in the spectral
density, rho(E), adiabatically connected to the field-free bound states. While
this technique applies to more general external potentials, we focus on the
ionization of electrons from atoms and molecules by DC electric fields, as this
has an important and immediate impact on the understanding of the multiphoton
ionization of molecules in strong laser fields.Comment: 13 pages, 7 figures, LaTe
Application of Absorbing Boundary Condition to Nuclear Breakup Reactions
Absorbing boundary condition approach to nuclear breakup reactions is
investigated. A key ingredient of the method is an absorbing potential outside
the physical area, which simulates the outgoing boundary condition for
scattered waves. After discretizing the radial variables, the problem results
in a linear algebraic equation with a sparse coefficient matrix, to which
efficient iterative methods can be applicable. No virtual state such as
discretized continuum channel needs to be introduced in the method. Basic
aspects of the method are discussed by considering a nuclear two-body
scattering problem described with an optical potential. We then apply the
method to the breakup reactions of deuterons described in a three-body direct
reaction model. Results employing the absorbing boundary condition are found to
accurately coincide with those of the existing method which utilizes
discretized continuum channels.Comment: 21 pages, 5 figures, RevTeX
Correlation dynamics between electrons and ions in the fragmentation of D molecules by short laser pulses
We studied the recollision dynamics between the electrons and D ions
following the tunneling ionization of D molecules in an intense short pulse
laser field. The returning electron collisionally excites the D ion to
excited electronic states from there D can dissociate or be further
ionized by the laser field, resulting in D + D or D + D,
respectively. We modeled the fragmentation dynamics and calculated the
resulting kinetic energy spectrum of D to compare with recent experiments.
Since the recollision time is locked to the tunneling ionization time which
occurs only within fraction of an optical cycle, the peaks in the D kinetic
energy spectra provides a measure of the time when the recollision occurs. This
collision dynamics forms the basis of the molecular clock where the clock can
be read with attosecond precision, as first proposed by Corkum and coworkers.
By analyzing each of the elementary processes leading to the fragmentation
quantitatively, we identified how the molecular clock is to be read from the
measured kinetic energy spectra of D and what laser parameters be used in
order to measure the clock more accurately.Comment: 13 pages with 14 figure
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