180 research outputs found
Three-dimensional femtosecond laser nanolithography of crystals
Nanostructuring hard optical crystals has so far been exclusively feasible at
their surface, as stress induced crack formation and propagation has rendered
high precision volume processes ineffective. We show that the inner chemical
etching reactivity of a crystal can be enhanced at the nanoscale by more than
five orders of magnitude by means of direct laser writing. The process allows
to produce cm-scale arbitrary three-dimensional nanostructures with 100 nm
feature sizes inside large crystals in absence of brittle fracture. To showcase
the unique potential of the technique, we fabricate photonic structures such as
sub-wavelength diffraction gratings and nanostructured optical waveguides
capable of sustaining sub-wavelength propagating modes inside yttrium aluminum
garnet crystals. This technique could enable the transfer of concepts from
nanophotonics to the fields of solid state lasers and crystal optics.Comment: Submitted Manuscript and Supplementary Informatio
Laser-induced Microexplosion Confined in the Bulk of a Sapphire Crystal: Evidence of Multimegabar Pressures
Extremely high pressures (∼10TPa) and temperatures (5×105K) have been produced using a single laser pulse (100nJ, 800 nm, 200 fs) focused inside a sapphire crystal. The laser pulse creates an intensity over 1014W/cm2 converting material within the abs
Femtosecond laser-induced hard X-ray generation in air from a solution flow of Au nano-sphere suspension using an automatic positioning system
Femtosecond laser-induced hard X-ray generation in air from a 100-μm-thick solution film of distilled water or Au nano-sphere suspension was carried out by using a newly-developed automatic positioning system with 1-μm precision. By positioning the solution film for the highest X-ray intensity, the optimum position shifted upstream as the laser power increased due to breakdown. Optimized positioning allowed us to control X-ray intensity with high fidelity. X-ray generation from Au nano-sphere suspension and distilled water showed different power scaling. Linear and nonlinear absorption mechanism are analyzed together with numerical modeling of light delivery
Mechanical properties and tuning of three-dimensional polymeric photonic crystals
Applied Physics LettersMechanical properties of photopolymerized photonic crystal PhC structures having woodpile and
spiral three-dimensional architectures were examined using flat-punch indentation. The structures
were found to exhibit a foamlike response with a bend-dominated elastic deformation regime
observed at strain levels up to 10%. Numerical simulations of optical properties of these PhC
structures demonstrate the possibility of achieving a substantial and reversible spectral tuning of the
photonic stop gap wavelength by applying a mechanical load to the PhC
Synthesis of Glass Nanofibers Using Femtosecond Laser Radiation Under Ambient Condition
We report the unique growth of nanofibers in silica and borosilicate glass using femtosecond laser radiation at 8 MHz repetition rate and a pulse width of 214 fs in air at atmospheric pressure. The nanofibers are grown perpendicular to the substrate surface from the molten material in laser-drilled microvias where they intertwine and bundle up above the surface. The fibers are few tens of nanometers in thickness and up to several millimeters in length. Further, it is found that at some places nanoparticles are attached to the fiber surface along its length. Nanofiber growth is explained by the process of nanojets formed in the molten liquid due to pressure gradient induced from the laser pulses and subsequently drawn into fibers by the intense plasma pressure. The attachment of nanoparticles is due to the condensation of vapor in the plasma
Coupling of Rotational Motion with Shape Fluctuations of Core-shell Microgels Having Tunable Softness
The influence of shape fluctuations on deformable thermosensitive microgels
in aqueous solution is investigated by dynamic light scattering (DLS) and
depolarized dynamic light scattering (DDLS). The systems under study consist of
a solid core of polystyrene and a thermosensitive shell of cross-linked
poly(N-isopropylacrylamide) (PNIPA) without and with embedded palladium
nanoparticles. PNIPA is soluble in water, but has a lower critical solution
temperature at 32 C (LCST). Below the LCST the PNIPA shell is swollen. Here we
find that besides translational and rotational diffusion, the particles exhibit
additional dynamics resulting from shape fluctuations. This leads to a
pronounced apparent increase of the rotational diffusion coefficient. Above the
transition temperature the shell collapses and provides a rather tight envelope
of the core. In this state the dynamics of the shell is frozen and the
core-shell particles behave like hard spheres. A simple physical model is
presented to capture and explain the essentials of the coupling of rotational
motion and shape fluctuations.Comment: 9 pages, 7 figure
Ultrafast laser micro-nano structuring of transparent materials with high aspect ratio
Ultrafast lasers are ideal tools to process transparent materials because
they spatially confine the deposition of laser energy within the material's
bulk via nonlinear photoionization processes. Nonlinear propagation and
filamentation were initially regarded as deleterious effects. But in the last
decade, they turned out to be benefits to control energy deposition over long
distances. These effects create very high aspect ratio structures which have
found a number of important applications, particularly for glass separation
with non-ablative techniques. This chapter reviews the developments of
in-volume ultrafast laser processing of transparent materials. We discuss the
basic physics of the processes, characterization means, filamentation of
Gaussian and Bessel beams and provide an overview of present applications
3D-Printed Stationary Phases with Ordered Morphology: State of the Art and Future Development in Liquid Chromatography Chromatographia
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