Revisiting Mt. Kilimanjaro : Do n-alkane biomarkers in soils reflect the δ2H isotopic composition of precipitation?

Abstract. During the last decade compound-specific deuterium (δ2H) analysis of plant leaf wax-derived n-alkanes has become a promising and popular tool in paleoclimate research. This is based on the widely accepted assumption that n-alkanes in soils and sediments generally reflect δ2H of precipitation (δ2Hprec). Recently, several authors suggested that δ2H of n-alkanes (δ2H,sub&gt;n-alkanes) can also be used as proxy in paleoaltimetry studies. Here we present results from a δ2H transect study (~1500 to 4000 m a.s.l.) carried out on precipitation and soil samples taken from the humid southern slopes of Mt. Kilimanjaro. Contrary to earlier suggestions, a distinct altitude effect in δ2Hprec is present above ~2000 m a.s.l., i.e. δ2Hprec values become more negative with increasing altitude. The compound-specific δ2H values of nC27 and nC29 do not confirm this altitudinal trend, but rather become more positive both in the O-layers (organic layers) and the Ah-horizons (mineral topsoils). Although our δ2Hn-alkane results are in agreement with previously published results from the southern slopes of Mt. Kilimanjaro (Peterse et al., 2009, BG, 6, 2799–2807), a major re-interpretation is required given that the δ2Hn-alkane results do not reflect the δ2Hprec results. The theoretical framework for this re-interpretation is based on the evaporative isotopic enrichment of leaf water associated with transpiration process. Modelling results show that relative humidity, decreasing considerably along the southern slopes of Mt. Kilimanjaro (from 78% at ~ 2000 m a.s.l. to 51% at 4000 m a.s.l.), strongly controls δ2Hleaf water. The modelled δ2H leaf water enrichment along the altitudinal transect matches well the measured 2H leaf water enrichment as assessed by using the δ2Hprec and δ2Hn-alkane results and biosynthetic fractionation during n-alkane biosynthesis in leaves. Given that our results clearly demonstrate that n-alkanes in soils do not simply reflect δ2Hprec but rather δ2Hleaf water, we conclude that care has to be taken not to over-interpret δ2Hn-alkane records from soils and sediments when reconstructing δ2H of paleoprecipitation. Both in paleoaltimetry and in paleoclimate studies changes in relative humidity and consequently in δ2Hn-alkane values can completely mask altitudinally or climatically-controlled changes in δ2Hprec. </jats:p

Analysis of White Dwarfs with Strange-Matter Cores

We summarize masses and radii for a number of white dwarfs as deduced from a combination of proper motion studies, Hipparcos parallax distances, effective temperatures, and binary or spectroscopic masses. A puzzling feature of these data is that some stars appear to have radii which are significantly smaller than that expected for a standard electron-degenerate white-dwarf equations of state. We construct a projection of white-dwarf radii for fixed effective mass and conclude that there is at least marginal evidence for bimodality in the radius distribution forwhite dwarfs. We argue that if such compact white dwarfs exist it is unlikely that they contain an iron core. We propose an alternative of strange-quark matter within the white-dwarf core. We also discuss the impact of the so-called color-flavor locked (CFL) state in strange-matter core associated with color superconductivity. We show that the data exhibit several features consistent with the expected mass-radius relation of strange dwarfs. We identify eight nearby white dwarfs which are possible candidates for strange matter cores and suggest observational tests of this hypothesis.Comment: 11 pages, 6 figures, accepted for publication in J. Phys. G: Nucl. Part. Phy

Water and nutrient fluxes as indicators for the sustainability of different land-use systems on the terra firme near Manaus - a project overview.

Comparision of the water and nutrient fluxes in different perennial land-se systems, either monocultures or mixed cropping systems, in order to determine the resource efficiency of perennial land-se systems. They were comparision of the monocultue systems with Theobroma grandiflorum (cupuacu) or Bactris gasipaes (pupunha), polyculture systems with cupuacu, pupunh, Bixa orellana (urucum) and Bertholletia excelsa (castanha-do-Para) and primary and secondary forest sites. In the first experimental year, the equipment was installed to measure raianfall, throughfall, stemflow and soil water fluxes. These data combined with measurements of nutrient concentrations inform about the element fluxes. for this purpose, laboratory facilities were implemented to analyze anions and cations in the different land-se systems. Additionally, the nutrient and organic matter content of the soils were studied. Firt results showed that the investigated tree species differ in their effect on the water distribution and nutrient accumulation within the different cropping systems

Oxygen-isotope effect on the in-plane penetration depth in underdoped Y_{1-x}Pr_xBa_2Cu_3O_{7-delta} as revealed by muon-spin rotation

The oxygen-isotope (^16O/^18O) effect (OIE) on the in-plane penetration depth $\lambda_{ab} (0)$ in underdoped Y_{1-x}Pr_xBa_2Cu_3O_{7-delta} was studied by muon-spin rotation. A pronounced OIE on $\lambda_{ab}^{-2}(0)$ was observed with a relative isotope shift of $\Delta\lambda^{-2}_{ab}/\lambda^{-2}_{ab}$=-5(2)% for x =0.3 and -9(2)% for x=0.4. It arises mainly from the oxygen-mass dependence of the in-plane effective mass $m_{ab}^{\ast}$. The OIE exponents of T_{c} and of $\lambda_{ab}^{-2}(0)$ exhibit a relation that appears to be generic for cuprate superconductors.Comment: 4 pages, 4 eps figures, RevTex

Investigation of A1g phonons in YBa2Cu3O7 by means of LAPW atomic-force calculations

We report first-principles frozen-phonon calculations for the determination of the force-free geometry and the dynamical matrix of the five Raman-active A1g modes in YBa2Cu3O7. To establish the shape of the phonon potentials atomic forces are calculated within the LAPW method. Two different schemes - the local density approximation (LDA) and a generalized gradient approximation (GGA) - are employed for the treatment of electronic exchange and correlation effects. We find that in the case of LDA the resulting phonon frequencies show a deviation from experimental values of approximately -10%. Invoking GGA the frequency values are significantly improved and also the eigenvectors are in very good agreement with experimental findings.Comment: 15 page

Confounding variables can degrade generalization performance of radiological deep learning models

Early results in using convolutional neural networks (CNNs) on x-rays to diagnose disease have been promising, but it has not yet been shown that models trained on x-rays from one hospital or one group of hospitals will work equally well at different hospitals. Before these tools are used for computer-aided diagnosis in real-world clinical settings, we must verify their ability to generalize across a variety of hospital systems. A cross-sectional design was used to train and evaluate pneumonia screening CNNs on 158,323 chest x-rays from NIH (n=112,120 from 30,805 patients), Mount Sinai (42,396 from 12,904 patients), and Indiana (n=3,807 from 3,683 patients). In 3 / 5 natural comparisons, performance on chest x-rays from outside hospitals was significantly lower than on held-out x-rays from the original hospital systems. CNNs were able to detect where an x-ray was acquired (hospital system, hospital department) with extremely high accuracy and calibrate predictions accordingly. The performance of CNNs in diagnosing diseases on x-rays may reflect not only their ability to identify disease-specific imaging findings on x-rays, but also their ability to exploit confounding information. Estimates of CNN performance based on test data from hospital systems used for model training may overstate their likely real-world performance

Observation of the Ankle and Evidence for a High-Energy Break in the Cosmic Ray Spectrum

We have measured the cosmic ray spectrum at energies above $10^{17}$ eV using the two air fluorescence detectors of the High Resolution Fly's Eye experiment operating in monocular mode. We describe the detector, PMT and atmospheric calibrations, and the analysis techniques for the two detectors. We fit the spectrum to models describing galactic and extragalactic sources. Our measured spectrum gives an observation of a feature known as the ``ankle'' near $3\times 10^{18}$ eV, and strong evidence for a suppression near $6\times 10^{19}$ eV.Comment: 14 pages, 9 figures. To appear in Physics Letters B. Accepted versio