811 research outputs found
Gaps and excitations in fullerides with partially filled bands : NMR study of Na2C60 and K4C60
We present an NMR study of Na2C60 and K4C60, two compounds that are related
by electron-hole symmetry in the C60 triply degenerate conduction band. In both
systems, it is known that NMR spin-lattice relaxation rate (1/T1) measurements
detect a gap in the electronic structure, most likely related to
singlet-triplet excitations of the Jahn-Teller distorted (JTD) C60^{2-} or
C60^{4-}. However, the extended temperature range of the measurements presented
here (10 K to 700 K) allows to reveal deviations with respect to this general
trend, both at high and low temperatures. Above room temperature, 1/T1 deviates
from the activated law that one would expect from the presence of the gap and
saturates. In the same temperature range, a lowering of symmetry is detected in
Na2C60 by the appearance of quadrupole effects on the 23Na spectra. In K4C60,
modifications of the 13C spectra lineshapes also indicate a structural
modification. We discuss this high temperature deviation in terms of a coupling
between JTD and local symmetry. At low temperatures, 1/TT tends to a
constant value for Na2C60, both for 13C and 23Na NMR. This indicates a residual
metallic character, which emphasizes the proximity of metallic and insulting
behaviors in alkali fullerides.Comment: 12 pages, 13 figure
Swift and Suzaku Observations of the X-Ray Afterglow from the GRB 060105
Results are presented of early X-ray afterglow observations of GRB 060105 by
Swift and Suzaku. The bright, long gamma-ray burst GRB 060105 triggered the
Swift Burst Alert Telescope (BAT) at 06:49:28 on 5 January 2006. The Suzaku
team commenced a pre-planned target of opportunity observation at 19 ks (5.3
hr) after the Swift trigger. Following the prompt emission and successive very
steep decay, a shallow decay was observed from T_0+187 s to T_0+1287 s. After
an observation gap during T_0 +(1.5-3) ks, an extremely early steep decay was
observed in T_0+(4-30) ks. The lightcurve flattened again at T_0+30 ks, and
another steep decay followed from T_0+50 ks to the end of observations. Both
steep decays exhibited decay indices of 2.3 - 2.4. This very early break, if it
is a jet break, is the earliest case among X-ray afterglow observations,
suggesting a very narrow jet whose opening angle is well below 1 degree. The
unique Suzaku/XIS data allow us to set very tight upper limits on line emission
or absorption in this GRB. For the reported pseudo-redshift of z=4.0+/-1.3 the
upper limit on the iron line equivalent width is 50 eV.Comment: 8 pages, 5 figures, Accepted for publication in PASJ Suzaku Special
Issue (vol. 58
Effect of Non-Magnetic Impurities (Zn,Li) in a Hole Doped Spin-Fermion Model for Cuprates
The effect of adding non-magnetic impurities (NMI), such as Zn or Li, to
high-Tc cuprates is studied applying Monte Carlo techniques to a spin-fermion
model. It is observed that adding Li is qualitatively similar to doping with
equal percentages of Sr and Zn. The mobile holes (MH) are trapped by the NMI
and the system remains insulating and commensurate with antiferromagnetic (AF)
correlations. This behavior persists in the region %NMI > %MH. On the other
hand, when %NMI < %MH magnetic and charge incommensurabilities are observed.
The vertical or horizontal hole-rich stripes, present when % NMI=0 upon hole
doping, are pinned by the NMI and tend to become diagonal, surrounding finite
AF domains. The %MH-%NMI plane is investigated. Good agreement with
experimental results is found in the small portion of this diagram where
experimental data are available. Predictions about the expected behavior in the
remaining regions are made.Comment: Four pages with four figures embedded in tex
Nonbonding oxygen holes and spinless scenario of magnetic response in doped cuprates
Both theoretical considerations and experimental data point to a more
complicated nature of the valence hole states in doped cuprates than it is
predicted by Zhang-Rice model. Actually, we deal with a competition of
conventional hybrid Cu 3d-O 2p state and purely
oxygen nonbonding state with symmetry. The latter
reveals a non-quenched Ising-like orbital moment that gives rise to a novel
spinless purely oxygen scenario of the magnetic response in doped cuprates with
the oxygen localized orbital magnetic moments of the order of tenths of Bohr
magneton. We consider the mechanism of Cu-O 2p transferred orbital
hyperfine interactions due to the mixing of the oxygen O 2p orbitals with Cu 3p
semicore orbitals. Quantitative estimates point to a large magnitude of the
respective contributions both to local field and electric field gradient, and
their correlated character.Comment: 7 pages, 1 figur
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