Role of Nucleophiles in Schiff Base Interaction with Nickel Ions

855-85

Preparation & Characterization of Dimethylformamidyl Substituted Titanium( IV) Compounds

456-45

Constraints on Metastable Helium in the Atmospheres of WASP-69b and WASP-52b with Ultra-Narrowband Photometry

Infrared observations of metastable 2$^3$S helium absorption with ground- and space-based spectroscopy are rapidly maturing, as this species is a unique probe of exoplanet atmospheres. Specifically, the transit depth in the triplet feature (with vacuum wavelengths near 1083.3 nm) can be used to constrain the temperature and mass loss rate of an exoplanet's upper atmosphere. Here, we present a new photometric technique to measure metastable 2$^3$S helium absorption using an ultra-narrowband filter (full-width at half-maximum of 0.635 nm) coupled to a beam-shaping diffuser installed in the Wide-field Infrared Camera (WIRC) on the 200-inch Hale Telescope at Palomar Observatory. We use telluric OH lines and a helium arc lamp to characterize refractive effects through the filter and to confirm our understanding of the filter transmission profile. We benchmark our new technique by observing a transit of WASP-69b and detect an excess absorption of $0.498\pm0.045$% (11.1$\sigma$), consistent with previous measurements after considering our bandpass. Then, we use this method to study the inflated gas giant WASP-52b and place a 95th-percentile upper limit on excess absorption in our helium bandpass of 0.47%. Using an atmospheric escape model, we constrain the mass loss rate for WASP-69b to be $5.25^{+0.65}_{-0.46}\times10^{-4}~M_\mathrm{J}/\mathrm{Gyr}$ ($3.32^{+0.67}_{-0.56}\times10^{-3}~M_\mathrm{J}/\mathrm{Gyr}$) at 7,000 K (12,000 K). Additionally, we set an upper limit on the mass loss rate of WASP-52b at these temperatures of $2.1\times10^{-4}~M_\mathrm{J}/\mathrm{Gyr}$ ($2.1\times10^{-3}~M_\mathrm{J}/\mathrm{Gyr}$). These results show that ultra-narrowband photometry can reliably quantify absorption in the metastable helium feature.Comment: 17 pages, 8 figures (figures 1 and 2 are rasterized for arXiv file size compliance), accepted to A

A Giant Glitch in the Energetic 69 ms X-ray Pulsar AXS J161730-505505

We present new results on the recently discovered 69 ms X-ray pulsar AXS J161730-505505, the sixth youngest sample of all known pulsars. We have undertaken a comprehensive X-ray observing campaign of AXS J161730-505505 with the ASCA, SAX, and XTE observatories and follow its long term spin-down history between 1989 and 1999, using these, archival GINGA and ASCA data sets, and the radio ephemeris. The spin-down is not simply described by a linear function as originally thought, but instead we find evidence of a giant glitch (|Delta P/P| > 10E-6) between 1993 August and 1997 September, perhaps the largest yet observed from a young pulsar. The glitch is well described by steps in the period and its first derivative accompanied by a persistent second derivative similar to those in the Vela pulsar. The pulse profile of AXS J161730-505505 presents a single asymmetric peak which is maintained over all observation epochs. The energy spectrum is also steady over time, characterized by a highly absorbed power-law with a photon index 1.4 +/- 0.2, consistent with that found for other young rotation powered pulsars.Comment: 6 pages with 2 figures, LaTex, emulateapj.sty. To appear in the Astrophysical Journal Letter

Optical and Infrared Observations of SGR 1806-20

The soft gamma-ray repeater (SGR) 1806$-$20 is associated with the center-brightened non-thermal nebula G~10.0$-$0.3, thought to be a plerion. As in other plerions, a steady \Xray\ source, AX~1805.7$-$2025, has been detected coincident with the peak of the nebular radio emission. Vasisht et al.\ have shown that the radio peak has a core-jet appearance, and argue that the core marks the true position of the SGR. At optical wavelengths, we detect three objects in the vicinity of the radio core. Only for the star closest to the core, barely visible in the optical but bright in the infrared ($K=8.4\,$mag.), the reddening is consistent with the high extinction ($A_V\simeq30\,$mag.) that has been inferred for AX~1805.7$-$2025. From the absence of CO band absorption, we infer that the spectral type of this star is earlier than late~G/early~K. The large extinction probably arises in a molecular cloud located at a distance of 6$\,$kpc, which means that the star, just like AX~1805.7$-$2025, is in or behind this cloud. This implies that the star is a supergiant. Since supergiants are rare, a chance coincidence with the compact radio core is very unlikely. To our knowledge, there are only three other examples of luminous stars embedded in non-thermal radio nebulae, SS~433, \mbox{Cir X-1} and G~70.7+1.2. Given this and the low coincidence probability, we suggest that the bright star is physically associated with SGR~1806$-$20, making it the first stellar identification of a high-energy transient.Comment: 7 pages, AASTeX (needs LaTeX style files aaspptwo.sty and epsf.sty, plus PostScript figure). In case of problems, contact [email protected]

Observing Exoplanets with High-Dispersion Coronagraphy. II. Demonstration of an Active Single-Mode Fiber Injection Unit

High-dispersion coronagraphy (HDC) optimally combines high contrast imaging techniques such as adaptive optics/wavefront control plus coronagraphy to high spectral resolution spectroscopy. HDC is a critical pathway towards fully characterizing exoplanet atmospheres across a broad range of masses from giant gaseous planets down to Earth-like planets. In addition to determining the molecular composition of exoplanet atmospheres, HDC also enables Doppler mapping of atmosphere inhomogeneities (temperature, clouds, wind), as well as precise measurements of exoplanet rotational velocities. Here, we demonstrate an innovative concept for injecting the directly-imaged planet light into a single-mode fiber, linking a high-contrast adaptively-corrected coronagraph to a high-resolution spectrograph (diffraction-limited or not). Our laboratory demonstration includes three key milestones: close-to-theoretical injection efficiency, accurate pointing and tracking, on-fiber coherent modulation and speckle nulling of spurious starlight signal coupling into the fiber. Using the extreme modal selectivity of single-mode fibers, we also demonstrated speckle suppression gains that outperform conventional image-based speckle nulling by at least two orders of magnitude.Comment: 10 pages, 7 figures, accepted by Ap