Short- and long-term modulation of the lutein epoxide and violaxanthin cycles in two species of the Lauraceae: sweet bay laurel (Laurus nobilis L.) and avocado (Persea americana Mill.)

Short- and long-term responses of the violaxanthin (V) and lutein epoxide (Lx) cycles were studied in two species of Lauraceae: sweet bay laurel (Laurus nobilis L.) and avocado (Persea americana L.). The Lx content exceeded the V content in shade leaves of both species. Both Lx and V were de-epoxidised on illumination, but only V was fully restored by epoxidation in low light. Violaxanthin was preferentially de-epoxidised in low light in L. nobilis. This suggests that Lx accumulates with leaf ageing, partly because its conversion to lutein is limited in shade. After exposure to strong light, shade leaves of avocado readjusted the total pools of α- and β-xanthophyll cycles by de novo synthesis of antheraxanthin, zeaxanthin and lutein. This occurred in parallel with a sustained depression of Fv/Fm. In Persea indica, a closely related but low Lx species, Fv/Fm recovered faster after a similar light treatment, suggesting the involvement of the Lx cycle in sustained energy dissipation. Furthermore, the seasonal correlation between non-reversible Lx and V photoconversions and pre-dawn Fv/Fm in sun leaves of sweet bay supported the conclusion that the Lx cycle is involved in a slowly reversible downregulation of photosynthesis analogous to the V cycle

Short- and long-term modulation of the lutein epoxide and violaxanthin cycles in two species of the Lauraceae: sweet bay laurel (Laurus nobilis L.) and avocado (Persea americana Mill)

Short- and long-term responses of the violaxanthin (V) and lutein epoxide (Lx) cycles were studied in two species of Lauraceae: sweet bay laurel (Laurus nobilis L.) and avocado (Persea americana L.). The Lx content exceeded the V content in shade leaves of both species. Both Lx and V were de-epoxidised on illumination, but only V was fully restored by epoxidation in low light. Violaxanthin was preferentially de-epoxidised in low light in L. nobilis. This suggests that Lx accumulates with leaf ageing, partly because its conversion to lutein is limited in shade. After exposure to strong light, shade leaves of avocado readjusted the total pools of α- and β-xanthophyll cycles by de novo synthesis of antheraxanthin, zeaxanthin and lutein. This occurred in parallel with a sustained depression of Fv/Fm. In Persea indica, a closely related but low Lx species, Fv/Fm recovered faster after a similar light treatment, suggesting the involvement of the Lx cycle in sustained energy dissipation. Furthermore, the seasonal correlation between non-reversible Lx and V photoconversions and pre-dawn F v/Fm in sun leaves of sweet bay supported the conclusion that the Lx cycle is involved in a slowly reversible downregulation of photosynthesis analogous to the V cycle

Mechanical characterization and modelling of Inconel 718 material behavior for machining process assessment

Nickel based alloys are extensively used in the aerospace industry due to the excellent corrosion resistance and high mechanical properties that are maintained up to elevated temperatures (600–800 °C). However, these superalloys are classified as difficult-to-cut and therefore modelling and simulation of the machining processes has become a key in the machinability assessment of nickel based alloys. The reliability of Finite Element Models (FEM) largely depends on the quality of input parameters, one of the most relevant being the constitutive material model representing work material behavior under high strain, strain rate and temperatures. In order to develop a reliable material model, the present work deals with a complete characterization of Inconel 718. Uniaxial compression tests at testing temperatures close to those found in machining (21–1050 °C) and high strain rates (10°−10 2 s −1 ) were performed on the Gleeble 3500 testing machine. Moreover, the microstructural analysis and microhardness measurements of the testing samples were performed, in order to correlate the microstructural state with the mechanical properties of the Inconel 718. Based on this experimental work, a new coupled empirical model is proposed to describe the particular behaviour of nickel based alloys at elevated temperatures and high strain rates. This material behaviour model introduces softening phenomena as well as the coupling between the temperature and the strain rate known to occur experimentally, for machining FEM simulations with Inconel 718 superalloy