Effect of long range forces on the interfacial profiles in thin binary polymer films

We study the effect of surface fields on the interfacial properties of a binary polymer melt confined between two parallel walls. Each wall attracts a different component of the blend by a non-retarded van der Waals potential. An interface which runs parallel to the surfaces is stabilized in the center of the film. Using extensive Monte Carlo simulations we study the interfacial properties as a function of the film thickness, the strength of the surface forces and the lateral size over which the profiles across the film are averaged. We find evidence for capillary wave broadening of the apparent interfacial profiles. However, the apparent interfacial width cannot be described quantitatively by a simple logarithmic dependence on the film thickness. The Monte Carlo simulations reveal that the surface fields give rise to an additional reduction of the intrinsic interfacial width and an increase of the effective interfacial tension upon decreasing the film thickness. These modifications of the intrinsic interfacial properties are confirmed by self-consistent field calculations. Taking account of the thickness dependence of the intrinsic interfacial properties and the capillary wave broadening, we can describe our simulation results quantitatively.Comment: to appear in J.Chem.Phy

Inferring physical conditions in interstellar clouds of H_2

We have developed a code that models the formation, destruction, radiative transfer, and vibrational/rotational excitation of H_2 in a detailed fashion. We discuss how such codes, together with FUSE observations of H_2 in diffuse and translucent lines of sight, may be used to infer various physical parameters. We illustrate the effects of changes in the major physical parameters (UV radiation field, gas density, metallicity), and we point out the extent to which changes in one parameter may be mirrored by changes in another. We provide an analytic formula for the molecular fraction, f_H2, as a function of cloud column density, radiation field, and grain formation rate of H_2. Some diffuse and translucent lines of sight may be concatenations of multiple distinct clouds viewed together. Such situations can give rise to observables that agree with the data, complicating the problem of uniquely identifying one set of physical parameters with a line of sight. Finally, we illustrate the application of our code to an ensemble of data, such as the FUSE survey of H_2 in the Large and Small Magellanic Clouds (LMC/SMC), in order to constrain the elevated UV radiation field intensity and reduced grain formation rate of H_2 in those low- metallicity environments.Comment: 33 pages (aastex, manuscript), 9 figures (3 color). accepted to Ap

Diblock copolymers at a homopolymer-homopolymer-interface: a Monte Carlo simulation

The properties of diluted symmetric A-B diblock copolymers at the interface between A and B homopolymer phases are studied by means of Monte Carlo (MC) simulations of the bond fluctuation model. We calculate segment density profiles as well as orientational properties of segments, of A and B blocks, and of the whole chain. Our data support the picture of oriented ``dumbbells'', which consist of mildly perturbed A and B Gaussian coils. The results are compared to a self consistent field theory (SCFT) for single copolymer chains at a homopolymer interface. We also discuss the number of interaction contacts between monomers, which provide a measure for the ``active surface'' of copolymers or homopolymers close to the interface

A polarized neutron-scattering study of the Cooper-pair moment in Sr2RuO4

We report a study of the magnetization density in the mixed state of the unconventional superconductor S2RuO4. On entering the superconducting state we find no change in the magnitude or distribution of the induced moment for a magnetic field of 1 Tesla applied within the RuO2 planes. Our results are consistent with a spin-triplet Cooper pairing with spins lying in the basal plane. This is in contrast with similar experiments performed on conventional and high-Tc superconductors.Comment: Submitted to Physical Review Letter

The Escape of Ionizing Photons from OB Associations in Disk Galaxies: Radiation Transfer Through Superbubbles

By solving the time-dependent radiation transfer problem of stellar radiation through evolving superbubbles within a smoothly varying HI distribution, we estimate the fraction of ionizing photons emitted by OB associations that escapes the HI disk of our Galaxy into the halo and intergalactic medium (IGM). We consider both coeval star-formation and a Gaussian star-formation history with a time spread sigma_t = 2 Myr. We consider both a uniform H I distribution and a two-phase (cloud/intercloud) model, with a negligible filling factor of hot gas. We find that the shells of the expanding superbubbles quickly trap or attenuate the ionizing flux, so that most of the escaping radiation escapes shortly after the formation of the superbubble. For the coeval star-formation history, the total fraction of Lyman Continuum photons that escape both sides of the disk in the solar vicinity is f_esc approx 0.15 +/- 0.05. For the Gaussian star formation history, f_esc approx 0.06 +/- 0.03, a value roughly a factor of two lower than the results of Dove & Shull (1994), where superbubbles were not considered. For a local production rate of ionizing photons Psi_LyC = 4.95 X 10^7 cm^{-2} s^{-1}, the flux escaping the disk is Phi_LyC approx (1.5-3.0) X 10^6 cm^{-2} s^{-1} for coeval and Gaussian star formation, comparable to the flux required to sustain the Reynolds layer.Comment: Revised version (expanded), accepted for publication by ApJ, 38 pages, 8 figures, aasms4.sty and aabib.sty files include

The Emergence of the Modern Universe: Tracing the Cosmic Web

This is the report of the Ultraviolet-Optical Working Group (UVOWG) commissioned by NASA to study the scientific rationale for new missions in ultraviolet/optical space astronomy approximately ten years from now, when the Hubble Space Telescope (HST) is de-orbited. The UVOWG focused on a scientific theme, The Emergence of the Modern Universe, the period from redshifts z = 3 to 0, occupying over 80% of cosmic time and beginning after the first galaxies, quasars, and stars emerged into their present form. We considered high-throughput UV spectroscopy (10-50x throughput of HST/COS) and wide-field optical imaging (at least 10 arcmin square). The exciting science to be addressed in the post-HST era includes studies of dark matter and baryons, the origin and evolution of the elements, and the major construction phase of galaxies and quasars. Key unanswered questions include: Where is the rest of the unseen universe? What is the interplay of the dark and luminous universe? How did the IGM collapse to form the galaxies and clusters? When were galaxies, clusters, and stellar populations assembled into their current form? What is the history of star formation and chemical evolution? Are massive black holes a natural part of most galaxies? A large-aperture UV/O telescope in space (ST-2010) will provide a major facility in the 21st century for solving these scientific problems. The UVOWG recommends that the first mission be a 4m aperture, SIRTF-class mission that focuses on UV spectroscopy and wide-field imaging. In the coming decade, NASA should investigate the feasibility of an 8m telescope, by 2010, with deployable optics similar to NGST. No high-throughput UV/Optical mission will be possible without significant NASA investments in technology, including UV detectors, gratings, mirrors, and imagers.Comment: Report of UV/O Working Group to NASA, 72 pages, 13 figures, Full document with postscript figures available at http://casa.colorado.edu/~uvconf/UVOWG.htm

Levitation of superconducting composites

The inverse levitation of a high temperature superconductor polymer composite consisting of powdered quench melt growth Ba2YCu3O(7-delta) and cyanoacrylate is reported. Magnetic hysteresis loop measurements for the composite are compared to those measured for the bulk material prior to powdering. Differences in the flux pining capability between the two material forms are small but significant

Nuclear Inelastic X-Ray Scattering of FeO to 48 GPa

The partial density of vibrational states has been measured for Fe in compressed FeO (w\"ustite) using nuclear resonant inelastic x-ray scattering. Substantial changes have been observed in the overall shape of the density of states close to the magnetic transiton around 20 GPa from the paramagnetic (low pressure) to the antiferromagnetic (high pressure) state. Our data indicate a substantial softening of the aggregate sound velocities far below the transition, starting between 5 and 10 GPa. This is consistent with recent radial x-ray diffraction measurements of the elastic constants in FeO. The results indicate that strong magnetoelastic coupling in FeO is the driving force behind the changes in the phonon spectrum of FeO.Comment: 4 pages, 4 figure