Vortex core transitions in superfluid 3He in globally anisotropic aerogels

Core structures of a single vortex in A-like and B-like phases of superfluid 3He in uniaxially compressed and stretched aerogels are studied by numerically solving Ginzburg-Landau equations derived microscopically. It is found that, although any uniaxial deformation leads to a wider A-like phase with the axial pairing in the pressure-temperature phase diagram, the vortex core states in the two phases in aerogel depend highly on the type of deformation. In a compressed aerogel, the first-order vortex core transition (VCT) previously seen in the bulk B phase appears at any pressure in the B-like phase while no strange vortex core is expected in the corresponding A-like phase. By contrast, in a stretched aerogel, the VCT in the B-like phase is lost while another VCT is expected to occur between a nonunitary core and a polar one in the A-like phase. Experimental search for these results is hoped to understand correlation between superfluid 3He and aerogel structure.Comment: 7 pages, 6 figures Text was changed. Resubmitted versio

Mass coupling and Q−1ofimpurity−limitednormalQ^{-1} of impurity-limited normal ^3$He in a torsion pendulum

We present results of the $Q^{-1}$ and period shift, $\Delta P$, for $^3$He confined in a 98% nominal open aerogel on a torsion pendulum. The aerogel is compressed uniaxially by 10% along a direction aligned to the torsion pendulum axis and was grown within a 400 $\mu$m tall pancake (after compression) similar to an Andronikashvili geometry. The result is a high $Q$ pendulum able to resolve $Q^{-1}$ and mass coupling of the impurity-limited $^3$He over the whole temperature range. After measuring the empty cell background, we filled the cell above the critical point and observe a temperature dependent period shift, $\Delta P$, between 100 mK and 3 mK that is 2.9$$ of the period shift (after filling) at 100 mK. The $Q^{-1}$ due to the $^3$He decreases by an order of magnitude between 100 mK and 3 mK at a pressure of $0.14\pm0.03$ bar. We compare the observable quantities to the corresponding calculated $Q^{-1}$ and period shift for bulk $^3$He.Comment: 8 pages, 3 figure

New Chiral Phases of Superfluid 3He Stabilized by Anisotropic Silica Aerogel

A rich variety of Fermi systems condense by forming bound pairs, including high temperature [1] and heavy fermion [2] superconductors, Sr2RuO4 [3], cold atomic gases [4], and superfluid 3He [5]. Some of these form exotic quantum states having non-zero orbital angular momentum. We have discovered, in the case of 3He, that anisotropic disorder, engineered from highly porous silica aerogel, stabilizes a chiral superfluid state that otherwise would not exist. Additionally, we find that the chiral axis of this state can be uniquely oriented with the application of a magnetic field perpendicular to the aerogel anisotropy axis. At suffciently low temperature we observe a sharp transition from a uniformly oriented chiral state to a disordered structure consistent with locally ordered domains, contrary to expectations for a superfluid glass phase [6].Comment: 6 pages, 4 figure, and Supplementary Informatio

Electrospray Ionization with High-Resolution Mass Spectrometry as a Tool for Lignomics: Lignin Mass Spectrum Deconvolution

Capability to characterize lignin, lignocellulose, and their degradation products is essential for development of new renewable feedstocks. Electrospray ionization high-resolution time-offlight mass spectrometry (ESI HR TOF MS) method was developed expanding the lignomics toolkit while targeting the simultaneous detection of low and high molecular weight (MW) lignin species. The effect of a broad range of electrolytes and various ionization conditions on ion formation and ionization effectiveness was studied using a suite of mono-, di- and triarene lignin model compounds as well as intact lignin. Contrary to the previous studies, the positive ionization mode was found to be more effective for methoxy-substituted arenes and polyphenols, i.e., species of a broadly varied MW structurally similar to the native lignin. For the first time, we report an effective formation of multiply charged species of lignin with the subsequent mass spectrum deconvolution in the presence of 100 mmol·L-1 formic acid in the positive ESI mode. The developed method enabled the detection of lignin species with an MW between 150 and 9,000 Da or higher, depending on the mass analyzer. The obtained Mn and Mw values of 1,500 and 2,500 Da, respectively, were in good agreement with those determined by gel permeation chromatography. Furthermore, the deconvoluted ESI mass spectrum was similar to that obtained with matrixassisted laser desorption/ionization (MALDI) TOF MS, yet featuring a higher signal-to-noise ratio. The formation of multiply charged species was confirmed with ESI ion mobility HR Q-TOF MS

Self-assembly of a lamellar abc triblock terpolymer thin film. Effect of substrates

We study the self-assembly in thin films of a lamella-forming polystyrene-block-poly(2-vinylpyridine) -block-poly(tert-butyl methacrylate) triblock terpolymer thin film on a polyimide substrate and compare it with the self-assembly of the same system on a native oxide silicon (SiOx) substrate. In addition to scanning force microscopy, we performed cross-sectional transmission electron microscopy. Both polyimide and SiOx substrates attract the polar P2VP middle block. However, significant differences between the two substrates were revealed: (i) the difference in the interaction strength between the substrate and the polymers caused a different configuration of P2VP chains adsorbed to the substrate and hence a different structure of the first layer, and (ii) the structure of the first layer influenced the self-assembly of the lamellae throughout the entire film. In contrast to SiOx substrates, on polyimide substrates the lamellae with the equilibrium thickness were formed in one step through a new intermediate structure

Standing wave diffraction with a beam of slow atoms

10.1080/09500349708231852JOURNAL OF MODERN OPTICS44101863-188