2,210 research outputs found
When is a State a State? The Case for Recognition of Somaliland
It has been well over a decade since the world attempted to save Somalia from the dustbin of āfailed states.ā During that decade, one re-gion of Somalia has pulled away from its post-colonial union with Somalia, established its own government, kept the peace, and managed to flourish in a kind of stability that is only a faint memory to most Somalians outside the region. Somaliland, once a British colony, argues it should be recognized as an independent state. This Note explores the legal conception of statehood, from the Montevideo Convention to the more recent emphasis on self-determination, and then turns to the case of Somaliland, arguing that Somaliland should be recognized as a state by the international community
A Bulk Water-Dependent Desolvation Energy Model for Analyzing the Effects of Secondary Solutes on Biological Equilibria
A new phenomenological model for interpreting the effects of solutes on biological equilibria is presented. The model attributes changes in equilibria to differences in the desolvation energy of the reacting species that, in turn, reflect changes in the free energy of the bulk water upon addition of secondary solutes. The desolvation approach differs notably from that of other solute models by treating the free energy of bulk water as a variable and by not ascribing the observed shifts in reaction equilibria to accumulation or depletion of solutes next to the surfaces of the reacting species. On the contrary, the partitioning of solutes is viewed as a manifestation of the different subpopulations of water that arise in response to the surface boundary conditions. A thermodynamic framework consistent with the proposed model is used to derive a relationship for a specific reaction, an aqueous solubility equilibrium, in two or more solutions. The resulting equation reconciles some potential issues with the transfer free energy model of Tanford. Application of the desolvation energy model to the analysis of a two-state protein folding equilibrium is discussed and contrasted to the application of two other solute models developed by Timasheff and by Parsegian. Future tabulation of solvation energies and bulk water energies may allow biophysical chemists to confirm the mechanism by which secondary solutes influence binding and conformational equilibria and may provide a common ground on which experimentalists and theoreticians can compare and evaluate their result
Simulation of a Dripping Faucet
We present a simulation of a dripping faucet system. A new algorithm based on
Lagrangian description is introduced. The shape of drop falling from a faucet
obtained by the present algorithm agrees quite well with experimental
observations. Long-term behavior of the simulation can reproduce period-one,
period-two, intermittent and chaotic oscillations widely observed in
experiments. Possible routes to chaos are discussed.Comment: 20 pages, 15 figures, J. Phys. Soc. Jpn. (in press
One-Dimensional Approximation of Viscous Flows
Attention has been paid to the similarity and duality between the
Gregory-Laflamme instability of black strings and the Rayleigh-Plateau
instability of extended fluids. In this paper, we derive a set of simple
(1+1)-dimensional equations from the Navier-Stokes equations describing thin
flows of (non-relativistic and incompressible) viscous fluids. This
formulation, a generalization of the theory of drop formation by Eggers and his
collaborators, would make it possible to examine the final fate of
Rayleigh-Plateau instability, its dimensional dependence, and possible
self-similar behaviors before and after the drop formation, in the context of
fluid/gravity correspondence.Comment: 17 pages, 3 figures; v2: refs & comments adde
Hydrophobic, Organically-Modified Silica Gels Enhance the Structure of Encapsulated Apomyoglobin
Insertion of hydrophobic groups in a silica matrix, by addition of propyl- or trifluoropropyltrimethoxysilane, leads to a surprising increase in the helical content of apomyoglobin following encapsulation by the solāgel techniqu
Air entrainment through free-surface cusps
In many industrial processes, such as pouring a liquid or coating a rotating
cylinder, air bubbles are entrapped inside the liquid. We propose a novel
mechanism for this phenomenon, based on the instability of cusp singularities
that generically form on free surfaces. The air being drawn into the narrow
space inside the cusp destroys its stationary shape when the walls of the cusp
come too close. Instead, a sheet emanates from the cusp's tip, through which
air is entrained. Our analytical theory of this instability is confirmed by
experimental observation and quantitative comparison with numerical simulations
of the flow equations
- ā¦