418 research outputs found
Tailoring Electronic Properties in Semiconducting Perovskite Materials Through Octahedral Control
Perovskite oxides, which take the chemical formula ABO3, are a very versatile and interesting materials family, exhibiting properties that include ferroelectricity, ferromagnetism, mixed ionic/electronic conductivity, metal-insulator behavior and multiferroicity. Key to these functionalities is the network of BO6 corner-connected octahedra, which are known to distort and rotate, directly altering electronic and ferroic properties. By controlling the BO6 octahedral distortions and rotations through cationic substitutions, the use of strain engineering, or through the formation of superlattice structures, the functional properties of perovskites can be tuned. Motivating the use of structure-driven design in oxide heterostructures is the prediction of hybrid improper ferroelectricity in A'BO3/ABO3 superlattices. Two key design rules to realizing hybrid improper ferroelectricity are the growth of high quality superlattice structures with odd periodicities of the A / A' layers, and the control of the octahedral rotation pattern. My work explores the rotational response in perovskite oxides to strain and interface effects in thin films of RFeO3 (R = La, Eu). I demonstrate a synchrotron x-ray diffraction technique to identify the rotation pattern that is present in the films. I then establish substrate imprinting as a key tool for controlling the rotation patterns in heterostructures, providing a means to realize the necessary structural variants of the predicted hybrid improper ferroelectricity in superlattices. In addition, by pairing measured diffraction data with a structure factor calculation, I demonstrate how one can extract both A-site and oxygen atomic positions in single crystal perovskite oxide films. Finally, I show results from (LaFeO3)n/(EuFeO3)n superlattices (n = 1-5), synthesized to test the motivating predictions of hybrid improper ferroelectricity in oxide superlattices.Ph.D., Materials Science and Engineering -- Drexel University, 201
Quantum Noise and Polarization Fluctuations in Vertical Cavity Surface Emitting Lasers
We investigate the polarization fluctuations caused by quantum noise in
quantum well vertical cavity surface emitting lasers (VCSELs). Langevin
equations are derived on the basis of a generalized rate equation model in
which the influence of competing gain-loss and frequency anisotropies is
included. This reveals how the anisotropies and the quantum well confinement
effects shape the correlations and the magnitude of fluctuations in ellipticity
and in polarization direction. According to our results all parameters used in
the rate equations may be obtained experimentally from precise time resolved
measurements of the intensity and polarization fluctuations in the emitted
laser light. To clarify the effects of anisotropies and of quantum well
confinement on the laser process in VCSELs we therefore propose time resolved
measurements of the polarization fluctuations in the laser light. In
particular, such measurements allow to distinguish the effects of frequency
anisotropy and of gain-loss anisotropy and would provide data on the spin
relaxation rate in the quantum well structure during cw operation as well as
representing a new way of experimentally determinig the linewidth enhancement
factor alpha.Comment: 16 pages and 3 Figures, RevTex, to be published in Phys. Rev.
Selectively oxidised vertical cavity surface emitting lasers with 50% power conversion efficiency
Includes bibliographical references (page 209).Index-guided vertical cavity top-surface emitting laser diodes have been fabricated from an all epitaxial structure with conducting mirrors by selective lateral oxidation of AlGaAs. Low voltage, a 78% slope efficiency, and a 350μA threshold current in a single device combine to yield a maximum power conversion efficiency of 50% at less than a 2mA drive current. The device operates in a single mode up to 1.5mW
High-frequency modulation of oxide-confined vertical cavity surface emitting lasers
Includes bibliographical references (page 458).High-speed studies of packaged, submilliampere threshold, oxide-confined vertical cavity surface emitting lasers show modulation bandwidths > 16GHz. Very high modulation current efficiency factors occur at low bias but decrease as the modulation bandwidth and frequency of the relative intensity noise peak saturate at higher currents
Self-pulsing oxide-confined vertical-cavity lasers with ultralow operating current
Includes bibliographical references (page 460).Selectively oxidised vertical-cavity lasers which exhibit self-pulsatin glasing at currents as low as 470nA are reported. Characteristics including linearly polarised emission, narrow linewidths and coherent near- and far-field diffraction indicate that these devices operate as lasers at DC currents 1mA
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InAlGaP vertical cavity surface emitting lasers (VCSELs): Processing and performance
(Al{sub y}Ga{sub 1{minus}y}){sup 1{minus}x}In{sub x}P semiconductor alloys lattice-matched to GaAs are widely used in visible optoelectronic devices. One of the most recent developments in this area is the AlGaInP-based red vertical cavity surface emitting laser (VCSEL). These lasers, which employ AlGaInP active regions and AlGaAs distributed Bragg reflectors (DBRs), have demonstrated continuous-wave (CW) lasing over the 630--690 nm region of the spectrum. Applications for these lasers include plastic fiber data communications, laser printing and bar code scanning. In this paper, the authors present an overview of recent developments in the processing and performance of AlGaInP based VCSELs. This overview will include a review of the general heterostructure designs that have been employed, as well as the performance of lasers fabricated by both ion implantation and selective oxidation
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Uniformity and performance of selectively oxidized VCSEL arrays
The authors report the uniformity characteristics of low threshold 1,060 nm and high power 850 nm 8 x 8 individually addressable oxide-confined VCSEL arrays. Uniformity of lasing thresholds and operating characteristics are described, as well as thermal issues for 2-dimensional laser arrays
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Fabrication issues of oxide-confined VCSELs
To insert high-performance oxide-confined vertical-cavity surface- emitting lasers (VCSELs) into the manufacturing arena, we have examined the critical parameters that must be controlled to establish a repeatable and uniform wet thermal oxidation process for AlGaAs. These parameters include the AlAs mole fraction, sample temperature, carrier gas flow, and bubbler water temperature. Knowledge of these parameters has enable the compilation of oxidation rate data for AlGaAs which exhibits an Arrhenius rate dependence. The compositionally dependent activation energies for Al{sub x}Ga{sub 1-x}As layers of x=1.00, 0.98, and 0.92 are found to be 1.24, 1.75, and 1.88 eV, respectively. 7 figs, 1 tab, 14 refs
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Fabrication, Packaging, and Performance of VCSELs and Photodetectors for Space Applications
Optocouplers are used for a variety of applications aboard spacecraft including electrical isolation, switching and power transfer. Commercially available light emitting diode (LED)-based optocouplers have experienced severe degradation of light output due to extensive displacement damage occurring in the semiconductor lattice caused by energetic proton bombardment. A new optocoupler has been designed and fabricated which utilizes vertical cavity surface emitting laser (VCSEL) and resonant cavity photodetector (RCPD) technologies for the optocoupler emitter and detector, respectively. Linear arrays of selectively oxidized GaAs/AlGaAs VCSELS and RCPDS, each designed to operate at a wavelength of 850nm, were fabricated using an airbridge contacting scheme. The airbridged contacts were designed to improve packaging yields and device reliability by eliminating the use of a polyimide planarizing layer which provided poor adhesion to the bond pad metallization. Details of the airbridged optocoupler fabrication process are reported. Discrete VCSEL and RCPD devices were characterized at temperatures between {minus}100 to 100 C. Devices were packaged in a face-to-face configuration to form a single channel optocoupler and its performance was evaluated under conditions of high-energy proton bombardment
Two-element phased array of antiguided vertical-cavity lasers
We demonstrate for the first time anti-guided coupling of two adjacent vertical-cavity surface-emitting lasers (VCSEL's), obtaining a 1-by-2 phase-locked array at 869 nm. The lateral index modification required for anti-guiding is achieved by a patterned 3-rim etch performed between two epitaxial growths. In contrast with prior evanescently coupled VCSEL's, adjacent anti-guided VCSEL's can emit in-phase and produce a single on-axis lobe in the far field. Greater than 2 mW of in-phase output power is demonstrated with two VCSEL's separated by 8 {micro}m. Moreover, phase locking of two VCSEL's separated by 20 {micro}m is observed, indicating the possibility of a new class of optical circuits based upon VCSEL's that interact horizontally and emit vertically
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