Strong electron correlations in cobalt valence tautomers

We have examined cobalt based valence tautomer molecules such as Co(SQ)$_2$(phen) using density functional theory (DFT) and variational configuration interaction (VCI) approaches based upon a model Hamiltonian. Our DFT results extend earlier work by finding a reduced total energy gap (order 0.6 eV) between high temperature and low temperature states when we fully relax the coordinates (relative to experimental ones). Futhermore we demonstrate that the charge transfer picture based upon formal valence arguments succeeds qualitatively while failing quantitatively due to strong covalency between the Co 3$d$ orbitals and ligand $p$ orbitals. With the VCI approach, we argue that the high temperature, high spin phase is strongly mixed valent, with about 30 % admixture of Co(III) into the predominantly Co(II) ground state. We confirm this mixed valence through a fit to the XANES spectra. Moreover, the strong electron correlations of the mixed valent phase provide an energy lowering of about 0.2-0.3 eV of the high temperature phase relative to the low temperature one. Finally, we use the domain model to account for the extraordinarily large entropy and enthalpy values associated with the transition.Comment: 10 pages, 4 figures, submitted to J. Chem. Phy

The Effect of Inkjet Ink Composition on Rheology And Jetting Behaviour

This work presents recent results on the way linear and non linear viscoelastic properties of the fluids affect the jetting mechanism. Recent progress on quantitative characterising both high frequency linear (LVE) and non-linear (NLVE) viscoelasticity of fluids allows fluids to be assessed for their jettability before using such materials in a DoD print head. In term of linear viscoelastic measurements, the Piezo Axial Vibrator (PAV) was used to probe the rheology of the fluids on a frequency range between 10Hz and 10000Hz. A filament stretching apparatus, called the “Cambridge Trimaster”, was used in combination with high speed cinematography, to characterize the fluids high speed stretching and break-up behaviour. The series of fluids investigated here consist in dilutions of mono disperse polystyrene with different molecular weight (110, 210, 306 and 488 kg/mol respectively) diluted in diethyl phthalate. The choice of polymer weights and concentrations were chosen to match both the complex viscosity and the LVE. However, non linear rheological data experiments exhibit differences in the fluid relaxation time and filament break-up mechanism. Ultra-high speed cinematography of DoD jetting events were correlated with filament break-up experiments and demonstrated that fluid rheology provides valuable information on the jetting quality of the fluids

Quasi-particle scattering and protected nature of topological states in a parent topological insulator Bi2_2Se3_3

We report on angle resolved photoemission spectroscopic studies on a parent topological insulator (TI), Bi$_2$Se$_3$. The line width of the spectral function (inverse of the quasi-particle lifetime) of the topological metallic (TM) states shows an anomalous behavior. This behavior can be reasonably accounted for by assuming decay of the quasi-particles predominantly into bulk electronic states through electron-electron interaction and defect scattering. Studies on aged surfaces reveal that topological metallic states are very much unaffected by the potentials created by adsorbed atoms or molecules on the surface, indicating that topological states could be indeed protected against weak perturbations.Comment: accepted for publication in Phys. Rev. B(R

Transport in Graphene Tunnel Junctions

We present a technique to fabricate tunnel junctions between graphene and Al and Cu, with a Si back gate, as well as a simple theory of tunneling between a metal and graphene. We map the differential conductance of our junctions versus probe and back gate voltage, and observe fluctuations in the conductance that are directly related to the graphene density of states. The conventional strong-suppression of the conductance at the graphene Dirac point can not be clearly demonstrated, but a more robust signature of the Dirac point is found: the inflection in the conductance map caused by the electrostatic gating of graphene by the tunnel probe. We present numerical simulations of our conductance maps, confirming the measurement results. In addition, Al causes strong n-doping of graphene, Cu causes a moderate p-doping, and in high resistance junctions, phonon resonances are observed, as in STM studies.Comment: 22 pages, 5 figure

Epitaxial growth and the magnetic properties of orthorhombic YTiO3 thin films

High-quality YTiO3 thin films were grown on LaAlO3 (110) substrates at low oxygen pressures (<10-8 Torr) using pulsed laser deposition. The in-plane asymmetric atomic arrangements at the substrate surface allowed us to grow epitaxial YTiO3 thin films, which have an orthorhombic crystal structure with quite different a- and b-axes lattice constants. The YTiO3 film exhibited a clear ferromagnetic transition at 30 K with a saturation magnetization of about 0.7 uB/Ti. The magnetic easy axis was found to be along the [1-10] direction of the substrate, which differs from the single crystal easy axis direction, i.e., [001].Comment: 14 pages, 4 figure

Spinor Dynamics in an Antiferromagnetic Spin-1 Condensate

We observe coherent spin oscillations in an antiferromagnetic spin-1 Bose-Einstein condensate of sodium. The variation of the spin oscillations with magnetic field shows a clear signature of nonlinearity, in agreement with theory, which also predicts anharmonic oscillations near a critical magnetic field. Measurements of the magnetic phase diagram agree with predictions made in the approximation of a single spatial mode. The oscillation period yields the best measurement to date of the sodium spin-dependent interaction coefficient, determining that the difference between the sodium spin-dependent s-wave scattering lengths $a_{f=2}-a_{f=0}$ is $2.47\pm0.27$ Bohr radii.Comment: 5 pages, 2 figures. Changes: added reference, minor correction

Refugees, trauma and adversity-activated development

The nature of the refugee phenomenon is examined and the position of mental health professionals is located in relation to it. The various uses of the word 'trauma' are explored and its application to the refugee context is examined. It is proposed that refugees' response to adversity is not limited to being traumatized but includes resilience and Adversity-Activated Development (AAD). Particular emphasis is given to the distinction between resilience and AAD. The usefulness of the 'Trauma Grid' in the therapeutic process with refugees is also discussed. The Trauma Grid avoids global impressions and enables a more comprehensive and systematic way of identifying the individual refugee's functioning in the context of different levels, i.e. individual, family, community and society/culture. Finally, I discuss implications for therapeutic work with refugees