3,700 research outputs found
Proton modified Pt zeolite fuel cell electrocatalysts
NaY Zeolite is selected as a suitable material to host 1.5 wt% Platinum (Pt) loading on zeolite using ion exchange method (a) Pt(NH3)4(NO3)2 without excess NH4NO3 nitrate and (b) Pt(NH3)4(NO3)2 with excess NH4NO3 nitrate. The structure/reactivity relationship of Pt nanoparticle has been experimentally studied via Nafion@ bound electrodes to investigate the interaction nature of Pt with zeolite and electron transfer using the extended X-ray adsorption fine structure (EXAFS) and Pt particle was predicted at 0.7 – 1.5 (nm). Pt oxides can be electrochemically reduced via a hydrogen ‘spillover’ phenomenon. A highly dispersed small Pt particle distribution can be achieved with excessive H+ ions on zeolite acidic sites
Neutron Scattering Measurements of Spatially Anisotropic Magnetic Exchange Interactions in Semiconducting K0.85Fe1.54Se2 (TN=280 K)
We use neutron scattering to study the spin excitations associated with the
stripe antiferromagnetic (AFM) order in semiconducting
KFeSe (= K). We show that the spin wave spectra
can be accurately described by an effective Heisenberg Hamiltonian with highly
anisotropic in-plane couplings at = K. At high temperature (=
K) above , short range magnetic correlation with anisotropic correlation
lengths are observed. Our results suggest that, despite the dramatic difference
in the Fermi surface topology, the in-plane anisotropic magnetic couplings are
a fundamental property of the iron based compounds; this implies that their
antiferromagnetism may originate from local strong correlation effects rather
than weak coupling Fermi surface nesting.Comment: 5 pages, 4 figure
Magnetic ground state of FeSe
Elucidating the nature of the magnetism of a high-temperature superconductor
is crucial for establishing its pairing mechanism. The parent compounds of the
cuprate and iron-pnictide superconductors exhibit N\'eel and stripe magnetic
order, respectively. However, FeSe, the structurally simplest iron-based
superconductor, shows nematic order (Ts = 90 K), but not magnetic order in the
parent phase, and its magnetic ground state is intensely debated. Here, we
report inelastic neutron-scattering experiments that reveal both stripe and
N\'eel spin fluctuations over a wide energy range at 110 K. On entering the
nematic phase, a substantial amount of spectral weight is transferred from the
N\'eel to the stripe spin fluctuations. Moreover, the total fluctuating
magnetic moment of FeSe is ~ 60% larger than that in the iron pnictide
BaFe2As2. Our results suggest that FeSe is a novel S = 1 nematic
quantum-disordered paramagnet interpolating between the N\'eel and stripe
magnetic instabilities.Comment: Supplementary information included; accepted by Nature Communication
Experimental quantum "Guess my Number" protocol using multiphoton entanglement
We present an experimental demonstration of a modified version of the
entanglement-assisted "Guess my Number" protocol for the reduction of
communication complexity among three separated parties. The results of
experimental measurements imply that the separated parties can compute a
function of distributed inputs by exchanging less classical information than by
using any classical strategy. And the results also demonstrate the advantages
of entanglement-enhanced communication, which is very close to quantum
communication. The advantages are based on the properties of
Greenberger-Horne-Zeilinger states.Comment: 4 pages, 2 figure
RF-thermal-structural-RF coupled analysis on the travelling wave disk-loaded accelerating structure
Travelling wave (TW) disk-loaded accelerating structure is one of the key
components in normal conducting (NC) linear accelerators, and has been studied
for many years. In the design process, usually after the dimensions of each
cell and the two couplers are finalized, the structure is fabricated and tuned,
and then the whole structure characteristics can be measured by the vector
network analyzer. Before the structure fabrication, the whole structure
characteristics are less simulated limited by the available computer
capability. In this paper, we described the method to do the
RF-thermal-structural-RF coupled analysis on the TW disk-loaded structure with
one single PC. In order to validate our method, we first analyzed and compared
our RF simulation results on the 3m long BEPCII structure with the
corresponding experimental results, which shows very good consistency. Finally,
the RF-thermal-structure-RF coupled analysis results on the 1.35m long NSC KIPT
linac accelerating structure are presented.Comment: 5 pages, 16 figures, Submitted to the Chinese Physics C (Formerly
High Energy Physics and Nuclear Physics
Loss of Conformational Stability in Calmodulin upon Methionine Oxidation
We have used electrospray ionization mass spectrometry (ESI-MS), circular dichroism (CD), and fluorescence spectroscopy to investigate the secondary and tertiary structural consequences that result from oxidative modification of methionine residues in wheat germ calmodulin (CaM), and prevent activation of the plasma membrane Ca-ATPase. Using ESI-MS, we have measured rates of modification and molecular mass distributions of oxidatively modified CaM species (CaMox) resulting from exposure to H2O2. From these rates, we find that oxidative modification of methionine to the corresponding methionine sulfoxide does not predispose CaM to further oxidative modification. These results indicate that methionine oxidation results in no large-scale alterations in the tertiary structure of CaMox, because the rates of oxidative modification of individual methionines are directly related to their solvent exposure. Likewise, CD measurements indicate that methionine oxidation results in little change in the apparent α-helical content at 28°C, and only a small (0.3 ± 0.1 kcal mol−1) decrease in thermal stability, suggesting the disruption of a limited number of specific noncovalent interactions. Fluorescence lifetime, anisotropy, and quenching measurements of N-(1-pyrenyl)-maleimide (PMal) covalently bound to Cys26 indicate local structural changes around PMal in the amino-terminal domain in response to oxidative modification of methionine residues in the carboxyl-terminal domain. Because the opposing globular domains remain spatially distant in both native and oxidatively modified CaM, the oxidative modification of methionines in the carboxyl-terminal domain are suggested to modify the conformation of the amino-terminal domain through alterations in the structural features involving the interdomain central helix. The structural basis for the linkage between oxidative modification and these global conformational changes is discussed in terms of possible alterations in specific noncovalent interactions that have previously been suggested to stabilize the central helix in CaM
Defining Human Embryo Phenotypes by Cohort-Specific Prognostic Factors
Hundreds of thousands of human embryos are cultured yearly at in vitro fertilization (IVF) centers worldwide, yet the vast majority fail to develop in culture or following transfer to the uterus. However, human embryo phenotypes have not been formally defined, and current criteria for embryo transfer largely focus on characteristics of individual embryos. We hypothesized that embryo cohort-specific variables describing sibling embryos as a group may predict developmental competence as measured by IVF cycle outcomes and serve to define human embryo phenotypes.We retrieved data for all 1117 IVF cycles performed in 2005 at Stanford University Medical Center, and further analyzed clinical data from the 665 fresh IVF, non-donor cycles and their associated 4144 embryos. Thirty variables representing patient characteristics, clinical diagnoses, treatment protocol, and embryo parameters were analyzed in an unbiased manner by regression tree models, based on dichotomous pregnancy outcomes defined by positive serum beta-human chorionic gonadotropin (beta-hCG). IVF cycle outcomes were most accurately predicted at approximately 70% by four non-redundant, embryo cohort-specific variables that, remarkably, were more informative than any measures of individual, transferred embryos: Total number of embryos, number of 8-cell embryos, rate (percentage) of cleavage arrest in the cohort and day 3 follicle stimulating hormone (FSH) level. While three of these variables captured the effects of other significant variables, only the rate of cleavage arrest was independent of any known variables.Our findings support defining human embryo phenotypes by non-redundant, prognostic variables that are specific to sibling embryos in a cohort
Dirac Equation at Finite Temperature
In this paper, we propose finite temperature Dirac equation, which can
describe the quantum systems in an arbitrary temperature for a relativistic
particle of spin-1/2. When the temperature T=0, it become Dirac equation. With
the equation, we can study the relativistic quantum systems in an arbitrary
temperature.Comment: arXiv admin note: text overlap with arXiv:1005.2751,
arXiv:hep-ph/0004125, arXiv:hep-ph/0005272 by other author
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