Influence of surfactants on the structure of titanium oxide gels : experiments and simulations

We report here on experimental and numerical studies of the influence of surfactants on mineral gel synthesis. The modification of the gel structure when the ratios water-precursor and water-surfactant vary is brought to the fore by fractal dimension measures. A property of {\em polydispersity of the initial hydrolysis} is proposed to explain these results, and is successfuly tested through numerical experiments of three dimensional chemically limited aggregation.Comment: 12 pages, 4 Postscript figures, uses RevTe

Discontinuous percolation transitions in real physical systems

We study discontinuous percolation transitions (PT) in the diffusion-limited cluster aggregation model of the sol-gel transition as an example of real physical systems, in which the number of aggregation events is regarded as the number of bonds occupied in the system. When particles are Brownian, in which cluster velocity depends on cluster size as $v_s \sim s^{\eta}$ with $\eta=-0.5$, a larger cluster has less probability to collide with other clusters because of its smaller mobility. Thus, the cluster is effectively more suppressed in growth of its size. Then the giant cluster size increases drastically by merging those suppressed clusters near the percolation threshold, exhibiting a discontinuous PT. We also study the tricritical behavior by controlling the parameter $\eta$, and the tricritical point is determined by introducing an asymmetric Smoluchowski equation.Comment: 5 pages, 5 figure

A new conjecture extends the GM law for percolation thresholds to dynamical situations

The universal law for percolation thresholds proposed by Galam and Mauger (GM) is found to apply also to dynamical situations. This law depends solely on two variables, the space dimension d and a coordinance numberq. For regular lattices, q reduces to the usual coordination number while for anisotropic lattices it is an effective coordination number. For dynamical percolation we conjecture that the law is still valid if we use the number q_2 of second nearest neighbors instead of q. This conjecture is checked for the dynamic epidemic model which considers the percolation phenomenon in a mobile disordered system. The agreement is good.Comment: 8 pages, latex, 3 figures include

Kinetic Antiferromagnetism in the Triangular Lattice

We show that the motion of a single hole in the infinite $U$ Hubbard model with frustrated hopping leads to weak metallic antiferromagnetism of kinetic origin. An intimate relationship is demonstrated between the simplest versions of this problem in 1 and 2 dimensions, and two of the most subtle many body problems, namely the Heisenberg Bethe ring in 1-d and the 2-dimensional triangular lattice Heisenberg antiferromagnet.Comment: 10 pages, 2 figures, 5 supplementary figures; Figures fixe

Stochastic Model for the Motion of a Particle on an Inclined Rough Plane and the Onset of Viscous Friction

Experiments on the motion of a particle on an inclined rough plane have yielded some surprising results. For example, it was found that the frictional force acting on the ball is viscous, {\it i.e.} proportional to the velocity rather than the expected square of the velocity. It was also found that, for a given inclination of the plane, the velocity of the ball scales as a power of its radius. We present here a one dimensional stochastic model based on the microscopic equations of motion of the ball, which exhibits the same behaviour as the experiments. This model yields a mechanism for the origins of the viscous friction force and the scaling of the velocity with the radius. It also reproduces other aspects of the phase diagram of the motion which we will discuss.Comment: 19 pages, latex, 11 postscript figures in separate uuencoded fil

Small Angle Scattering by Fractal Aggregates: A Numerical Investigation of the Crossover Between the Fractal Regime and the Porod Regime

Fractal aggregates are built on a computer using off-lattice cluster-cluster aggregation models. The aggregates are made of spherical particles of different sizes distributed according to a Gaussian-like distribution characterised by a mean $a_0$ and a standard deviation $\sigma$. The wave vector dependent scattered intensity $I(q)$ is computed in order to study the influence of the particle polydispersity on the crossover between the fractal regime and the Porod regime. It is shown that, given $a_0$, the location $q_c$ of the crossover decreases as $\sigma$ increases. The dependence of $q_c$ on $\sigma$ can be understood from the evolution of the shape of the center-to-center interparticle-distance distribution function.Comment: RevTex, 4 pages + 6 postscript figures, compressed using "uufiles", published in Phys. Rev. B 50, 1305 (1994

Kondo spin liquid and magnetically long-range ordered states in the Kondo necklace model

A simplified version of the symmetric Kondo lattice model, the Kondo necklace model, is studied by using a representation of impurity and conduction electron spins in terms of local Kondo singlet and triplet operators. Within a mean field theory, a spin gap always appears in the spin triplet excitation spectrum in 1D, leading to a Kondo spin liquid state for any finite values of coupling strength $t/J$ (with $t$ as hopping and $J$ as exchange); in 2D and 3D cubic lattices the spin gaps are found to vanish continuously around $(t/J)_c\approx 0.70$ and $(t/J)_c\approx 0.38$, respectively, where quantum phase transitions occur and the Kondo spin liquid state changes into an antiferromagnetically long-range ordered state. These results are in agreement with variational Monte Carlo, higher-order series expansion, and recent quantum Monte Carlo calculations for the symmetric Kondo lattice modelComment: Revtex, four pages, three figures; to be published in Physical Review B1, 1 July (2000