435 research outputs found
Contact angle measurements on superhydrophobic Carbon Nanotube Forests : effect of fluid pressure
In this paper the effect of pressure on the contact angle of a water drop on
superhydrophobic Carbon Nanotube (CNT) forests is studied. Superhydrophobic CNT
forests are obtained from a new and simple functionalization strategy, based on
the gold-thiol affinity. Using a specifically devised experimental setup, we
then show that these surfaces are able to withstand high excess pressures
(larger than 10 kPa) without transiting toward a roughness-invaded state,
therefore preserving their low adhesion properties. Together with the
relatively low technical cost of the process, this robustness versus pressure
makes such surfaces very appealing for practical integration into microfluidic
systems.Comment: accepted for publication in Europhysics Letter
Improved sensitivity of H.E.S.S.-II through the fifth telescope focus system
The Imaging Atmospheric Cherenkov Telescope (IACT) works by imaging the very
short flash of Cherenkov radiation generated by the cascade of relativistic
charged particles produced when a TeV gamma ray strikes the atmosphere. This
energetic air shower is initiated at an altitude of 10-30 km depending on the
energy and the arrival direction of the primary gamma ray. Whether the best
image of the shower is obtained by focusing the telescope at infinity and
measuring the Cherenkov photon angles or focusing on the central region of the
shower is a not obvious question. This is particularly true for large size IACT
for which the depth of the field is much smaller. We address this issue in
particular with the fifth telescope (CT5) of the High Energy Stereoscopic
System (H.E.S.S.); a 28 m dish large size telescope recently entered in
operation and sensitive to an energy threshold of tens of GeVs. CT5 is equipped
with a focus system, its working principle and the expected effect of focusing
depth on the telescope sensitivity at low energies (50-200 GeV) is discussed.Comment: In Proceedings of the 33rd International Cosmic Ray Conference
(ICRC2013), Rio de Janeiro (Brazil
Slippage of water past superhydrophobic carbon nanotube forests in microchannels
We present in this letter an experimental characterization of liquid flow
slippage over superhydrophobic surfaces made of carbon nanotube forests,
incorporated in microchannels. We make use of a micro-PIV (Particule Image
Velocimetry) technique to achieve the submicrometric resolution on the flow
profile necessary for accurate measurement of the surface hydrodynamic
properties. We demonstrate boundary slippage on the Cassie superhydrophobic
state, associated with slip lengths of a few microns, while a vanishing slip
length is found in the Wenzel state, when the liquid impregnates the surface.
Varying the lateral roughness scale L of our carbon nanotube forest-based
superhydrophobic surfaces, we demonstrate that the slip length varies linearly
with L in line with theoretical predictions for slippage on patterned surfaces.Comment: under revie
Piercing an interface with a brush: collaborative stiffening
The hairs of a painting brush withdrawn from a wetting liquid self-assemble
into clumps whose sizes rely on a balance between liquid surface tension and
hairs bending rigidity. Here we study the situation of an immersed carpet in an
evaporating liquid bath : the free extremities of the hairs are forced to
pierce the liquid interface. The compressive capillary force on the tip of
flexible hairs leads to buckling and collapse. However we find that the
spontaneous association of hairs into stronger bundles may allow them to resist
capillary buckling. We explore in detail the different structures obtained and
compare them with similar patterns observed in micro-structured surfaces such
as carbon nanotubes "forests".Comment: 9 pages, 6 figure
Making a splash with water repellency
A 'splash' is usually heard when a solid body enters water at large velocity.
This phenomena originates from the formation of an air cavity resulting from
the complex transient dynamics of the free interface during the impact. The
classical picture of impacts on free surfaces relies solely on fluid inertia,
arguing that surface properties and viscous effects are negligible at
sufficiently large velocities. In strong contrast to this large-scale
hydrodynamic viewpoint, we demonstrate in this study that the wettability of
the impacting body is a key factor in determining the degree of splashing. This
unexpected result is illustrated in Fig.1: a large cavity is evident for an
impacting hydrophobic sphere (1.b), contrasting with the hydrophilic sphere's
impact under the very same conditions (1.a). This unforeseen fact is
furthermore embodied in the dependence of the threshold velocity for air
entrainment on the contact angle of the impacting body, as well as on the ratio
between the surface tension and fluid viscosity, thereby defining a critical
capillary velocity. As a paradigm, we show that superhydrophobic impacters make
a big 'splash' for any impact velocity. This novel understanding provides a new
perspective for impacts on free surfaces, and reveals that modifications of the
detailed nature of the surface -- involving physico-chemical aspects at the
nanometric scales -- provide an efficient and versatile strategy for
controlling the water entry of solid bodies at high velocity.Comment: accepted for publication in Nature Physic
Low frequency Raman studies of multi-wall carbon nanotubes: experiments and theory
In this paper, we investigate the low frequency Raman spectra of multi-wall
carbon nanotubes (MWNT) prepared by the electric arc method. Low frequency
Raman modes are unambiguously identified on purified samples thanks to the
small internal diameter of the MWNT. We propose a model to describe these
modes. They originate from the radial breathing vibrations of the individual
walls coupled through the Van der Waals interaction between adjacent concentric
walls. The intensity of the modes is described in the framework of bond
polarization theory. Using this model and the structural characteristics of the
nanotubes obtained from transmission electron microscopy allows to simulate the
experimental low frequency Raman spectra with an excellent agreement. It
suggests that Raman spectroscopy can be as useful regarding the
characterization of MWNT as it is in the case of single-wall nanotubes.Comment: 4 pages, 2 eps fig., 2 jpeg fig., RevTex, submitted to Phys. Rev.
van der Waals interaction in nanotube bundles : consequences on vibrational modes
We have developed a pair-potential approach for the evaluation of van der
Waals interaction between carbon nanotubes in bundles.
Starting from a continuum model, we show that the intertube modes range from
to . Using a non-orthogonal tight-binding approximation
for describing the covalent intra-tube bonding in addition, we confirme a
slight chiral dependance of the breathing mode frequency and we found that this
breathing mode frequency increase by 10 % if the nanotube lie inside a
bundle as compared to the isolated tube.Comment: 5 pages, 2 figure
The camera of the fifth H.E.S.S. telescope. Part I: System description
In July 2012, as the four ground-based gamma-ray telescopes of the H.E.S.S.
(High Energy Stereoscopic System) array reached their tenth year of operation
in Khomas Highlands, Namibia, a fifth telescope took its first data as part of
the system. This new Cherenkov detector, comprising a 614.5 m^2 reflector with
a highly pixelized camera in its focal plane, improves the sensitivity of the
current array by a factor two and extends its energy domain down to a few tens
of GeV.
The present part I of the paper gives a detailed description of the fifth
H.E.S.S. telescope's camera, presenting the details of both the hardware and
the software, emphasizing the main improvements as compared to previous
H.E.S.S. camera technology.Comment: 16 pages, 13 figures, accepted for publication in NIM
Atmospheric aerosols at the Pierre Auger Observatory and environmental implications
The Pierre Auger Observatory detects the highest energy cosmic rays.
Calorimetric measurements of extensive air showers induced by cosmic rays are
performed with a fluorescence detector. Thus, one of the main challenges is the
atmospheric monitoring, especially for aerosols in suspension in the
atmosphere. Several methods are described which have been developed to measure
the aerosol optical depth profile and aerosol phase function, using lasers and
other light sources as recorded by the fluorescence detector. The origin of
atmospheric aerosols traveling through the Auger site is also presented,
highlighting the effect of surrounding areas to atmospheric properties. In the
aim to extend the Pierre Auger Observatory to an atmospheric research platform,
a discussion about a collaborative project is presented.Comment: Regular Article, 16 pages, 12 figure
Superconductivity in Ropes of Single-Walled Carbon Nanotubes
We report measurements on ropes of Single Walled Carbon Nanotubes (SWNT) in
low-resistance contact to non-superconducting (normal) metallic pads, at low
voltage and at temperatures down to 70 mK. In one sample, we find a two order
of magnitude resistance drop below 0.55 K, which is destroyed by a magnetic
field of the order of 1T, or by a d.c. current greater than 2.5 microA. These
features strongly suggest the existence of superconductivity in ropes of SWNT.Comment: Accepted for publication in Phys. Rev. Let
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