Silica nanoparticles as a highly efficient catalyst for the one-pot synthesis of sterically congested 2-(dibenzylamino)-2-aryl acetamide derivatives from by phthaldehyde isomers, isocyanides and dibenzylamine

A green and efficient method for the preparation of 2-(dibenzylamino)-2-aryl acetamide derivatives via a three-component reaction of an isocyanide, dibenzylamine and a phthalaldehyde derivative in the presence of silica nanoparticles (silica NPs, ca. 42 nm) as a catalyst under solvent free conditions at room temperature is described. The ease of work-up, green chemistry conditions and high yields of the products make this procedure a useful addition to modern synthetic methods. The silica nanoparticles that used in this reaction as a catalyst were prepared by thermal decomposition of rice hulls. Simple, green and cheap method for the preparation of the nanocatalyst represents a major advantage for this process. The structures of these compounds were confirmed by IR, 1H and 13C NMR spectroscopy. KEY WORDS: Silica nanoparticles, Nanocatalyst, Isocyanide, Phthalaldehyde Bull. Chem. Soc. Ethiop. 2016, 30(3), 413-420DOI: http://dx.doi.org/10.4314/bcse.v30i3.

The strong coupling constant from lattice QCD with N_f=2 dynamical quarks

We compute $\Lambda_{\bar{MS}}$ for two flavors of light dynamical quarks using non-perturbatively $O(a)$ improved Wilson fermions. We improve on a recent calculation by employing Pad\'e-improved two-loop and three-loop perturbation theory to convert the lattice numbers to the $\bar{MS}$ scheme.Comment: Contribution to Lattice 2001 (matrix elements), typo correcte

Optical study on doped polyaniline composite films

Localization driven by disorder has a strong influence on the conducting property of conducting polymer. A class of authors hold the opinion that disorder in the material is homogeneous and conducting polymer is disordered metal close to Anderson-Mott Metal-Insulator transition, while others treat the disorder as inhomogeneous and have the conclusion that conducting polymer is a composite of ordered metallic regions and disordered insulating regions. The morphology of conducting polymers is an important factor that have influence on the type and extent of disorder. Different protonic acids used as dopants and moisture have affection on polymer chain arrangement and interchain interactions. A PANI-CSA film, two PANI-CSA/PANI-DBSA composite films with different dopants ratio, and one of the composite films with different moisture content are studied. Absolute reflectivity measurements are performed on the films. Optical conductivity and the real part of dielectric function are calculated by Kramers-Kronig(KK) relations. $\sigma_1(\omega)$ and $\epsilon_1(\omega)$ derivate from simple Drude model in low frequency range and tendencies of the three sample are different and non-monotonic. The Localization Modified Drude model(LMD) in the framework of Anderson-Mott theory can not give a good fit to the experimental data. By introducing a distribution of relaxation time into LMD, reasonable fits for all three samples are obtained. This result supports the inhomogeneous picture.Comment: 6 figures, 7 page

3D characterization of CdSe nanoparticles attached to carbon nanotubes

The crystallographic structure of CdSe nanoparticles attached to carbon nanotubes has been elucidated by means of high resolution transmission electron microscopy and high angle annular dark field scanning transmission electron microscopy tomography. CdSe rod-like nanoparticles, grown in solution together with carbon nanotubes, undergo a morphological transformation and become attached to the carbon surface. Electron tomography reveals that the nanoparticles are hexagonal-based with the (001) planes epitaxially matched to the outer graphene layer.Comment: 7 pages, 8 figure

First Order Bipolaronic Transition at Finite Temperature in the Holstein Model

We investigate the Holstein model by using the dynamical mean-field theory combined with the exact diagonalization method. Below a critical temperature Tcr, a coexistence of the polaronic and the bipolaronic solutions is found for the same value of the electron-phonon coupling $ in the range gc1(T)<g<gc2(T). In the coexistence region, the system shows a first order phase transition from the bipolaronic to the polaronic states as T decreases at T=Tp(<Tcr), where the double occupancy and the lattice fluctuation together with the anharmonicity of the effective ion potential change discontinuously without any symmetry breaking. The obtained bipolaronic transition seems to be consistent with the rattling transition in the beta-pyrochlore oxide KOs2O6.Comment: 5 pages, 5 figures, J. Phys. Soc. Jpn. 79 (2010) 09370

Single atom quantum walk with 1D optical superlattices

A proposal for the implementation of quantum walks using cold atom technology is presented. It consists of one atom trapped in time varying optical superlattices. The required elements are presented in detail including the preparation procedure, the manipulation required for the quantum walk evolution and the final measurement. These procedures can be, in principle, implemented with present technology.Comment: 6 pages, 7 figure

Search for a dark vector gauge boson decaying to π+π−\pi^+ \pi^- using η→π+π−γ\eta \rightarrow \pi^+\pi^- \gamma decays

We report a search for a dark vector gauge boson $U^\prime$ that couples to quarks in the decay chain $D^{*+} \to D^0 \pi^+, D^0 \to K^0_S \eta, \eta \to U^\prime \gamma$, $U^\prime \to \pi^+ \pi^-$. No signal is found and we set a mass-dependent limit on the baryonic fine structure constant of $10^{-3} - 10^{-2}$ in the $U^\prime$ mass range of 290 to 520 MeV/$c^2$. This analysis is based on a data sample of 976 fb$^{-1}$ collected by the Belle experiment at the KEKB asymmetric-energy $e^+e^-$ collider.Comment: 6 pages, 4 figure

Search for the 0−−0^{--} Glueball in Υ(1S)\Upsilon(1S) and Υ(2S)\Upsilon(2S) decays

We report the first search for the $J^{PC}=0^{--}$ glueball in $\Upsilon(1S)$ and $\Upsilon(2S)$ decays with data samples of $(102\pm2)$ million and $(158\pm4)$ million events, respectively, collected with the Belle detector. No significant signals are observed in any of the proposed production modes, and the 90\% credibility level upper limits on their branching fractions in $\Upsilon(1S)$ and $\Upsilon(2S)$ decays are obtained. The inclusive branching fractions of the $\Upsilon(1S)$ and $\Upsilon(2S)$ decays into final states with a $\chi_{c1}$ are measured to be \BR(\Upsilon(1S)\to \chi_{c1}+ anything) = (1.90\pm 0.43(stat.)\pm 0.14(syst.))\times 10^{-4} with an improved precision over prior measurements and \BR(\Upsilon(2S)\to \chi_{c1}+ anything) = (2.24\pm 0.44(stat.)\pm 0.20(syst.))\times 10^{-4} for the first time.Comment: 19 pages, 17 figures, Fig.10b was polished, but all the results unchanged. Paper was published in PR

Study of e+e- => B(*) B(*)-bar pi+- at sqrt(s)=10.866 GeV

We report the analysis of the three-body e+e- => B B-bar pi, B B*-bar pi, and B* B*-bar pi processes, including the first observation of the Zb+-(10610) =>[B B*-bar+c.c.]+- and Zb+-(10650) => [B*B*-bar]+- transitions. We measure visible cross sections for the three-body production of sigma_vis(e+e- => [B B*-bar+c.c.]+-pi-+=(11.2+-1.0(stat.)+-1.2(syst.)) pb and sigma_vis(e+e- => [B*B*-bar]+-pi-+)=(5.61+-0.73(stat.)+-0.66(syst.)) pb and set a 90% C.L. upper limit of sigma_vis(e+e- => [BB-bar]+-pi-+)<2.1 pb. The results are based on a 121.4 1/fb data sample collected with the Belle detector at a center-of-mass energy near the Y(5S) peak.Comment: 8 pages, 2 figure

Study of Excited Ξc\Xi_c States Decaying into Ξc0\Xi_c^0 and Ξc+\Xi_c^+ Baryons

Using a data sample of 980 ${\rm fb}^{-1}$ of $e^+e^-$ annihilation data taken with the Belle detector operating at the KEKB asymmetric-energy $e^+e^-$ collider, we report the results of a study of excited $\Xi_c$ states that decay, via the emission of photons and/or charged pions, into $\Xi_c^0$ or $\Xi_c^+$ ground state charmed-strange baryons. We present new measurements of the masses of all members of the $\Xi_c^{\prime}$, $\Xi_c(2645)$, $\Xi_c(2790)$, $\Xi_c(2815)$, and $\Xi_c(2980)$ isodoublets, measurements of the intrinsic widths of those that decay strongly, and evidence of previously unknown transitions.Comment: Submitted to PR