H2 formation via the UV photo-processing of a-C:H nano-particles

Context. The photolysis of hydrogenated amorphous carbon, a-C(:H), dust by UV photon-irradiation in the laboratory leads to the release of H2 as well as other molecules and radicals. This same process is also likely to be important in the interstellar medium. Aims. To investigate molecule formation arising from the photo-dissociatively-driven, regenerative processing of a-C(:H) dust. Methods. We explore the mechanism of a-C(:H) grain photolysis leading to the formation of H2 and other molecules/radicals. Results. The rate constant for the photon-driven formation of H2 from a-C(:H) grains is estimated to be 2x10^-17 cm^3 s^-1. In intense radiation fields photon-driven grain decomposition will lead to fragmentation into daughter species rather than H2 formation. Conclusions. The cyclic re-structuring of arophatic a-C(:H) nano-particles appears to be a viable route to formation of H2 for low to moderate radiation field intensities (1 < G_0 < 10^2), even when the dust is warm (T ~ 50 - 100 K).Comment: 7 pages, 2 figures, accepted for publication in A&

Heavy Rainfall Warning Assessment Tool User Guide. Version 1.2

This report is a User Guide to a PC tool for assessing Heavy Rainfall Warnings. Development of the PC tool formed an important operational output of the Environment Agency and Met Office funded project: "Development of Rainfall Forecast Performance Monitoring Criteria. Phase 1: Development of Methodology and Algorithms" (Jones et al., 2003). The Heavy Rainfall Warning (HRW) Assessment Tool is a toolkit for Microsoft Excel. The tool allows the user to configure an assessment framework for a particular format of Heavy Rainfall Warning, enter and save data for forecasts and ground-truths, and generate a range of performance measures and other statistics for new and previously saved data. Summary tables are presented using Excel's PivotTable feature, from which charts can also be generated. Performance measures are provided to assess forecasts of heavy rainfall in continuous variable, categorical and probability form: these include bias, rmse, R-squared Efficiency, skill scores and the Continuous Brier Score

Production of Millisecond Dips in Sco X-1 Count Rates by Dead Time Effects

Chang et al. (2006) reported millisecond duration dips in the X-ray intensity of Sco X-1 and attributed them to occultations of the source by small trans-Neptunian objects (TNOs). We have found multiple lines of evidence that these dips are not astronomical in origin, but rather the result of high-energy charged particle events in the RXTE PCA detectors. Our analysis of the RXTE data indicates that at most 10% of the observed dips in Sco X-1 could be due to occultations by TNOs, and, furthermore, we find no positive or supporting evidence for any of them being due to TNOs. We therefore believe that it is a mistake to conclude that any TNOs have been detected via occultation of Sco X-1.Comment: Submitted to ApJ; uses emulateapj.cls, 8 pages with 8 figure

High-temperature, long-life thyratron

Thallium and xenon filled thyratron was developed that operates at tube envelope temperatures up to 750 C. This tube performs at peak voltage ratings of 2000 V forward and reverse and at an average current rating of 15 A for up to 11,000 hours

A quantum dynamical comparison of the electronic couplings derived from quantum electrodynamics and Förster theory:Application to 2D molecular aggregates

The objective of this study is to investigate under what circumstances Förster theory of electronic (resonance) energy transfer breaks down in molecular aggregates. This is achieved by simulating the dynamics of exciton diffusion, on the femtosecond timescale, in molecular aggregates using the Liouville–von Neumann equation of motion. Specifically the focus of this work is the investigation of both spatial and temporal deviations between exciton dynamics driven by electronic couplings calculated from Förster theory and those calculated from quantum electrodynamics. The quantum electrodynamics (QED) derived couplings contain medium- and far-zone terms that do not exist in Förster theory. The results of the simulations indicate that Förster coupling is valid when the dipole centres are within a few nanometres of one another. However, as the distance between the dipole centres increases from 2 nm to 10 nm, the intermediate- and far-zone coupling terms play non-negligible roles and Förster theory begins to break down. Interestingly, the simulations illustrate how contributions to the exciton dynamics from the intermediate- and far-zone coupling terms of QED are quickly washed-out by the near-zone mechanism of Förster theory for lattices comprising closely packed molecules. On the other hand, in the case of sparsely packed arrays, the exciton dynamics resulting from the different theories diverge within the 100 fs lifetime of the trajectories. These results could have implications for the application of spectroscopic ruler techniques as well as design principles relating to energy harvesting materials

Notch activates Wnt-4 signalling to control medio-lateral patterning of the pronephros

Previous studies have highlighted a role for the Notch signalling pathway during pronephrogenesis in the amphibian Xenopus laevis, and in nephron development in the mammalian metanephros, yet a mechanism for this function remains elusive. Here, we further the understanding of how Notch signalling patterns the early X. laevis pronephros anlagen, a function that might be conserved in mammalian nephron segmentation. Our results indicate that early phase pronephric Notch signalling patterns the medio-lateral axis of the dorso-anterior pronephros anlagen, permitting the glomus and tubules to develop in isolation. We show that this novel function acts through the Notch effector gene hrt1 by upregulating expression of wnt4. Wnt-4 then patterns the proximal pronephric anlagen to establish the specific compartments that span the medio-lateral axis. We also identified pronephric expression of lunatic fringe and radical fringe that is temporally and spatially appropriate for a role in regulating Notch signalling in the dorso-anterior region of the pronephros anlagen. On the basis of these results, along with data from previous publications, we propose a mechanism by which the Notch signalling pathway regulates a Wnt-4 function that patterns the proximal pronephric anlagen

After the Fall: Legacy Effects of Biogenic Structure on Wind-Generated Ecosystem Processes Following Mussel Bed Collapse

Blue mussels (Mytilus edulis) are ecosystem engineers with strong effects on species diversity and abundances. Mussel beds appear to be declining in the Gulf of Maine, apparently due to climate change and predation by the invasive green crab, Carcinus maenas. As mussels die, they create a legacy of large expanses of shell biogenic structure. In Maine, USA, we used bottom traps to examine effects of four bottom cover types (i.e., live mussels, whole shells, fragmented shells, bare sediment) and wind condition (i.e., days with high, intermediate, and low values) on flow-related ecosystem processes. Significant differences in transport of sediment, meiofauna, and macrofauna were found among cover types and days, with no significant interaction between the two factors. Wind condition had positive effects on transport. Shell hash, especially fragmented shells, had negative effects, possibly because it acted as bed armor to reduce wind-generated erosion and resuspension. Copepods had the greatest mobility and shortest turnover times (0.15 d), followed by nematodes (1.96 d) and the macrofauna dominant, Tubificoides benedeni (2.35 d). Shell legacy effects may play an important role in soft-bottom system responses to wind-generated ecosystem processes, particularly in collapsed mussel beds, with implications for recolonization, connectivity, and the creation and maintenance of spatial pattern

Development of high-temperature, gas-filled, ceramic rectifiers, thyratrons, and voltage-reference tubes Final report, Dec. 15, 1964 - Jan. 26, 1966

Development of high temperature gas filled ceramic rectifiers, thyratrons, and voltage-regulator tube