Radionuclides in some spring mineral waters in Serbia

Radiochemical analyses ofsome natural mineral bottled waters from different location in Serbia were investigated. Concentrations of all present naturally occurring radionuclides, 238 U, 234U, 232Th, 230Th, 228Th, 228Ra and 226Ra and 234U/238 U, 226Ra/230Th, 228Th /232Th, and 228 Ra/228 Th activity ratios were calculated and discussed. Uranium series disequilibria in the hydrosphere occur due to geochemical differentiation processes resulting with different mobility of the radionuclides from the same series. We have investigated radioactive disequilibrium in the spring waters Crni Guber, Čibutkovica and Studenica, originated from metamorphic rock area. High content of radium isotopes (226Ra, 228Ra) in analysed natural spring waters indicates contribution from other non-water sources, probably environmental sediment.Physical chemistry 2004 : 7th international conference on fundamental and applied aspects of physical chemistry; Belgrade (Serbia); 21-23 September 200

Migration of depleted uranium contamination through the soil

Military use of ammunition with depleted uranium at South Serbia, caused contamination of the environment. Surface soil and soil profile around projectile with depleted uranium were analyzed three years later by high resolution alpha/gamma spectrometry. It was found that activity levels in the soil layer next to the penetrator changes to 1% of initial value at 15 cm distance. This value is about double background uranium level of the soil at the Bratoselce location.Physical chemistry 2004 : 7th international conference on fundamental and applied aspects of physical chemistry; Belgrade (Serbia); 21-23 September 200

Nove međunarodne preporuke i zahtevi u vezi izlaganja u nemedicinske svrhe

BSS Directive 2013/59 entered into force on the 6 February 2014 requiring the Member States to adopt legislation (laws, regulations and administrative provisions) in order to harmonise their national legislation with requirements of this Directive until 6 February 2018. This Directive explicitly defines „non-medical imaging exposure” as deliberate exposure of individuals for other than medical purposes. Those planned exposure situations, if justified need to be subject to the appropriate regulatory framework for optimization of protection, exemption, notification, authorisation, inspection and law enforcement in order to insure safety in operation. The most challenging part is a justification process of „non-medical imaging exposure“ taking into account that regulatory radiation protection authorities have limited responsibility in decision making process. BSS Directive recommends regular periodical review of justified practices involving deliberate exposure of humans for non-medical imaging purposes taking into account new technologies available, magnitude of radiological exposure during screening and other screening objectives. Dose constrains for different categories of exposures (public exposure, occupational exposure) depending on particular application, should be established and used in the optimisation of protection. In addition, appropriate regulatory control should be established and enforced as well as the stakeholder dialoge and the provision of information responsive to stakeholders concerns.BSS direktiva 2013/59 stupila je na snagu 6. februara 2014. godine. To znači da su države članice u obavezi da usvoje legislativu (zakone, uredbe i upravne odredbe) kako bi uskladile svoje nacionalno zakonodavstvo sa zahtevima ove Direktive do 6. februara 2018. godine. Ova Direktiva jasno definiše „nemediciska izlaganja“ kao namerna izlaganja pojedinaca u svrhe koje nisu medicinske. Ukoliko su ove situacije planiranog izlaganja opravdane potrebno je da budu deo regulatornog okvira tj. da se na njih primenjuju zahtevi za: optimizaciju zaštite, izuzimanje, prijavljivanje, odobrenje delatnosti kao i inspekciju i sprovođenje propisa a u cilju obezbeđivanja sigurnosti tokom rada. Najzahtevniji deo je proces opravdavanja nemediciskih izlaganja imajući u vidu da regulatorna tela za zaštitu od zračenja imaju ograničenu odgovornost u procesu donošenja odluke o opravdanosti delatnosti. Preporuka BSS direktive je da se periodično vrši revizija opravdanih delatnosti koje uključuju namerna izlaganja ljudi u nemedicinske svrhe uzimajući u obzir nove dostupne tehnologije, stepen izlaganja zračenju tokom skrininga i druge ciljeve skrininga. U procesu optimizacije zaštite potrebno je uspostaviti i primenjivati ograničenja doza za različite kategorije izlaganja (izlaganje stanovništva, profesionalno izlaganje) u zavisnosti od pojedinačne primene. Takođe, potrebno je uspostaviti i primenjivati odgovarajuću regulatornu kontrolu kao i sprovoditi dijalog i obezbediti odgovarajuće informacije u vezi sa pitanjima svih zainteresovanih strana.Зборник радова : XXIX симпозијум ДЗЗСЦГ : Сребрно језеро, 27-29. септембар 2017. годин

Chemical and radiochemical fractionation of depleted uranium in contaminated soils

The results of the chemical and radiochemical characterization of depleted uranium present in the soils since it was used in Balkan intervention, 1999, are presented. The contamination levels and uranium fractionation in the soil substrates was examined using radiation spectrometry methods and by application of the five-step sequential extraction procedure. Alpha-spectrometric uranium isotopic analysis enabled to find out the recently appeared uranium in the environment mobility and/or fixation into stable forms in the soil, distinguishing depleted from naturally occurring uranium on the basis of 234U/238U and 235U/238U activities ratios.Physical chemistry 2006 : 8th international conference on fundamental and applied aspects of physical chemistry; Belgrade (Serbia); 26-29 September 200

Nove međunarodne preporuke i zahtevi u vezi izlaganja u nemedicinske svrhe

BSS Directive 2013/59 entered into force on the 6 February 2014 requiring the Member States to adopt legislation (laws, regulations and administrative provisions) in order to harmonise their national legislation with requirements of this Directive until 6 February 2018. This Directive explicitly defines „non-medical imaging exposure” as deliberate exposure of individuals for other than medical purposes. Those planned exposure situations, if justified need to be subject to the appropriate regulatory framework for optimization of protection, exemption, notification, authorisation, inspection and law enforcement in order to insure safety in operation. The most challenging part is a justification process of „non-medical imaging exposure“ taking into account that regulatory radiation protection authorities have limited responsibility in decision making process. BSS Directive recommends regular periodical review of justified practices involving deliberate exposure of humans for non-medical imaging purposes taking into account new technologies available, magnitude of radiological exposure during screening and other screening objectives. Dose constrains for different categories of exposures (public exposure, occupational exposure) depending on particular application, should be established and used in the optimisation of protection. In addition, appropriate regulatory control should be established and enforced as well as the stakeholder dialoge and the provision of information responsive to stakeholders concerns.BSS direktiva 2013/59 stupila je na snagu 6. februara 2014. godine. To znači da su države članice u obavezi da usvoje legislativu (zakone, uredbe i upravne odredbe) kako bi uskladile svoje nacionalno zakonodavstvo sa zahtevima ove Direktive do 6. februara 2018. godine. Ova Direktiva jasno definiše „nemediciska izlaganja“ kao namerna izlaganja pojedinaca u svrhe koje nisu medicinske. Ukoliko su ove situacije planiranog izlaganja opravdane potrebno je da budu deo regulatornog okvira tj. da se na njih primenjuju zahtevi za: optimizaciju zaštite, izuzimanje, prijavljivanje, odobrenje delatnosti kao i inspekciju i sprovođenje propisa a u cilju obezbeđivanja sigurnosti tokom rada. Najzahtevniji deo je proces opravdavanja nemediciskih izlaganja imajući u vidu da regulatorna tela za zaštitu od zračenja imaju ograničenu odgovornost u procesu donošenja odluke o opravdanosti delatnosti. Preporuka BSS direktive je da se periodično vrši revizija opravdanih delatnosti koje uključuju namerna izlaganja ljudi u nemedicinske svrhe uzimajući u obzir nove dostupne tehnologije, stepen izlaganja zračenju tokom skrininga i druge ciljeve skrininga. U procesu optimizacije zaštite potrebno je uspostaviti i primenjivati ograničenja doza za različite kategorije izlaganja (izlaganje stanovništva, profesionalno izlaganje) u zavisnosti od pojedinačne primene. Takođe, potrebno je uspostaviti i primenjivati odgovarajuću regulatornu kontrolu kao i sprovoditi dijalog i obezbediti odgovarajuće informacije u vezi sa pitanjima svih zainteresovanih strana.Зборник радова : XXIX симпозијум ДЗЗСЦГ : Сребрно језеро, 27-29. септембар 2017. годин

Radijacioni rizik

Једно од основних питања у области заштите од зрачења је процена прихватљивости ризика од зрачења, што је формулисано и кроз три принципа заштите од зрачења: оправданост, оптимизација и ограничење дозе. Спровођење ових принципа је сложен процес који захтева примену низа активности и вештина из различитих области од правно регулаторних до уско стручних тј. природно техничких или хуманитарно медицинских наука. Почетне тачке у разматрању примене извора зрачења су процена користи тј. добробити од примене извора зрачења и процена радијационог ризика коју та примена носи. У овом раду су такође разматране и вредности доза тј. шта сматрамо високим а шта ниским дозама, приступ процени радијационог ризика као и преглед вредности за неке границе излагања.Having in mind that all human activities carry some sort of risks, one of the main issue of radiation protection is assessment of the acceptability of risks of using radiation sources. This is also, the first step of applying ALARA principle. Risk is a synonym for probability of harmful effect and takes into account probability of happening some events and severity of consequences. This is complicated task in which have to be involved many specialist and skills from different parts of science. The paper discussed some effective dose values, the way of calculation risks from low doses and connection of dose and risks with terms from regular usage such as: high doses, low doses and very low doses.Зборник радова : XXIX симпозијум ДЗЗСЦГ : Сребрно језеро, 27-29. септембар 2017. годин

Natural and artificial (90Sr) radionuclides in some carbonated mineral waters used in Serbia

A radiological characterization of 7 different carbonated mineral water samples collected in the local supermarkets in the area of Belgrade (produced in Serbia) was carried out. Analysis included determination of gross alpha and gross beta activities. The obtained results showed that the natural activity concentrations of alpha and beta emitting radionuclides in carbonated mineral water samples were within World Health Organization recommended levels, except for the Heba Strong and Kiseljak samples where the beta activity exceeds 1 Bq/L. For these two water samples gamma spectrometry analysis was performed as well as determination of 90Sr by oxalic method. The instrumentation used to count the gross alpha and gross beta activities, as well as for 90Sr, was a/b low level proportional counter Thermo Eberline FHT 770 T. Gamma spectrometric measurements were performed using a HPGe Canberra detector with a counting efficiency of 20%. The annual effective dose equivalent due to ingestion of investigated waters was calculated for age group >17, and obtained values are lower than 0.1 mSv recommended reference level. Finally, a comparison of the investigated waters with worldwide data was made. [Projekat Ministarstva nauke Republike Srbije, br. III43009

Natural radioactivity of some spring and bottled mineral waters from several central Balkan sites, as a way of their characterization

In this work, a study of the radioactive content of some spring and bottled mineral waters originating fi-om metamorphic rock areas was carried out. A high content of radium isotopes (Ra-226, Ra-228), was found by radiometric analysis in the spring waters: Studenica (Ra-226: 289 mBq/L), Cibutkovica (Ra-226: 92, 4 mBq/L, Ra-228: 610 mBq/L), and Crni Guber (Ra-226: 120 mBq/L, Ra-228: 1170 mBq/L). On the other hand, the radiochemical results showed a higher concentration of U-238 in the bottled mineral water samples (dissolved uranium concentrations were from 0.21 mBq[L, for Kopaonik to 71.5 mBq/L fo Skadarska) than in the spring water samples (dissolved uranium concentrations were very low approximate to 10 mBq/L). The concentrations of all the present naturally occuring radionuclides: U-238, U-234, Th-232, Th-230, Th-228, Ra-228 and Ra-226 were determined by alpha/gamma spectrometric analysis. The activity ratios U-234/U-238, Ra-226/Th-230 and Th-228/Th-232, Ra-228/Th-228 were calculated and are discussed as an indication of the radioactive disequilibrium in bothe the U-238 and Th-232 radioactive series. The high contents of radium isotopes with respect to the equilibrium values expected from the respective parents Th-232/(Th-232 series) and Th-230 (U-238 series) found in the spring water samples is the main evidence for the existence of significant radioactive disequilibrium in both the radioactive series

Heavy metal content of pm10 and pm2.5 within urban area of Belgrade

An assessment of air quality of Belgrade was performed by determining the trace element content in airborne PM10 and PM2.5 in two years period. Samples were collected at two locations in a heavy polluted area. The concentrations of Al, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn were determined with AAS. Results indicated that the ambient concentration of Zn in the PM10 and PM2.5 was the highest (1389.18 and 1998.00 ng m-3 respectively). Also, the highest enrichment factor (EF) value was obtained for Zn, folowing with high EF for Cd and Pb in PM10, reflecting the importance of anthropogenic inputs. The limit values of toxic trace elements from WHO and EC Air quality guidelines were not exceeded except for Ni.Physical chemistry 2006 : 8th international conference on fundamental and applied aspects of physical chemistry; Belgrade (Serbia); 26-29 September 200

Variations of Pm10 Mass Concentrations and Correlations with Other Pollutants in Belgrade Urban Area

In this paper, we present the PM10 levels measured at an urban residential background site in New Belgrade in Omladinskih Brigada Street, at 15 m height (roof) The aerosol samples were collected using a European standard sampler in four seasonal campaigns conducted in autumn Nov 13-Dec 03 2007 winter Feb 07-28, 2008 spring May 06-28, 2008 and summer July 17-August 15 2008 The results were compared with PM10 mass concentrations measured with a Horiba automatic station at street level at the same sampling site and at three more sites within the Belgrade municipal monitoring network The results show that the PM10 values in the Belgrade urban area were high during autumn and winter campaigns (heating season) with a number of samples exceeding the 24-h limit value of 50 mu g m(3) On the roof station, a maximum daily value of 209 mu g m(3) was measured in the autumn campaign, with 14 values out of 20 measurements exceeding the 24-h limit In winter, 14 out of 19 measurements exceeded the limit, with a maximum value of 196 mu g m(3) During the spring campaign, the number of exceedances was three out of 22 All values during the summer campaign were below 50 mu g m(3) The roof station equipped with the European Standard instrument showed systematically higher values than the street-level automatic monitor PM10 values at all sites followed the same trend The highest concentrations at all monitoring sites were observed during the autumn, Nov 20-25, 2007, and winter, Feb 19-23, 200