Gas phase hydrogen permeation in alpha titanium and carbon steels

Commercially pure titanium and heats of Armco ingot iron and steels containing from 0.008-1.23 w/oC were annealed or normalized and machined into hollow cylinders. Coefficients of diffusion for alpha-Ti and alpha-Fe were determined by the lag-time technique. Steady state permeation experiments yield first power pressure dependence for alpha-Ti and Sievert's law square root dependence for Armco iron and carbon steels. As in the case of diffusion, permeation data confirm that alpha-titanium is subject to at least partial phase boundary reaction control while the steels are purely diffusion controlled. The permeation rate in steels also decreases as the carbon content increases. As a consequence of Sievert's law, the computed hydrogen solubility decreases as the carbon content increases. This decreases in explained in terms of hydrogen trapping at carbide interfaces. Oxidizing and nitriding the surfaces of alpha-titanium membranes result in a decrease in the permeation rate for such treatment on the gas inlet surfaces but resulted in a slight increase in the rate for such treatment on the gas outlet surfaces. This is explained in terms of a discontinuous TiH2 layer

Adhesion between atomically pure metallic surfaces, part IV Semiannual report

Adhesion between metal couples in vacuum environment and use of contact resistance measurements to evaluate surface contaminatio

Testing extra dimensions with boundaries using Newton's law modifications

Extra dimensions with boundaries are often used in the literature, to provide phenomenological models that mimic the standard model. In this context, we explore possible modifications to Newton's law due to the existence of an extra-dimensional space, at the boundary of which the gravitational field obeys Dirichlet, Neumann or mixed boundary conditions. We focus on two types of extra space, namely, the disk and the interval. As we prove, in order to have a consistent Newton's law modification (i.e., of the Yukawa-type), some of the extra-dimensional spaces that have been used in the literature, must be ruled out.Comment: Published version, title changed, 6 figure

Model for Dissipative Highly Nonlinear Waves in Dry Granular Systems

A model is presented for the characterization of dissipative effects on highly nonlinear waves in one-dimensional dry granular media. The model includes three terms: Hertzian, viscoelastic, and a term proportional to the square of the relative velocity of particles. The model outcomes are confronted with different experiments where the granular system is subject to several constraints for different materials. Excellent qualitative and quantitative agreement between theory and experiments is found.Comment: Link to the Journal: http://prl.aps.org/abstract/PRL/v104/i11/e11800

Spin Structure of Many-Body Systems with Two-Body Random Interactions

We investigate the spin structure of many-fermion systems with a spin-conserving two-body random interaction. We find a strong dominance of spin-0 ground states and considerable correlations between energies and wave functions of low-lying states with different spin, but no indication of pairing. The spectral densities exhibit spin-dependent shapes and widths, and depend on the relative strengths of the spin-0 and spin-1 couplings in the two-body random matrix. The spin structure of low-lying states can largely be explained analytically.Comment: 10 pages, including 3 figure

Degenerate principal series of quantum Harish-Chandra modules

In this paper we study a quantum analogue of a degenerate principal series of $U_q \mathfrak{su}_{n,n}$-modules ($0<q<1$) related to the Shilov boundary of the quantum $n \times n$-matrix unit ball. We give necessary and sufficient conditions for the modules to be simple and unitarizable and investigate their equivalence. These results are q-analogues of known classical results on reducibility and unitarizability of SU(n,n)-modules obtained by Johnson, Sahi, Zhang, Howe and Tan.Comment: 33 pages, 4 figure

Radiation induced zero-resistance states in GaAs/AlGaAs heterostructures: Voltage-current characteristics and intensity dependence at the resistance minima

High mobility two-dimensional electron systems exhibit vanishing resistance over broad magnetic field intervals upon excitation with microwaves, with a characteristic reduction of the resistance with increasing radiation intensity at the resistance minima. Here, we report experimental results examining the voltage - current characteristics, and the resistance at the minima vs. the microwave power. The findings indicate that a non-linear V-I curve in the absence of microwave excitation becomes linearized under irradiation, unlike expectations, and they suggest a similarity between the roles of the radiation intensity and the inverse temperature.Comment: 3 color figures; publishe

Tuning phase-stability and short-range order through Al-doping in (CoCrFeMn)100-xAlx high entropy alloys

For (CoCrFeMn)$_{100-x}$Al$_{x}$ high-entropy alloys, we investigate the phase evolution with increasing Al-content (0 $\le$ x $\le$ 20 at.%). From first-principles theory, the Al-doping drives the alloy structurally from FCC to BCC separated by a narrow two-phase region (FCC+BCC), which is well supported by our experiments. We highlight the effect of Al-doping on the formation enthalpy and electronic structure of (CoCrFeMn)$_{100-x}$Al$_{x}$ alloys. As chemical short-range order (SRO) in multicomponent alloys indicates the nascent local order (and entropy changes), as well as expected low-temperature ordering behavior, we use thermodynamic linear-response within density-functional theory to predict SRO and ordering transformation and temperatures inherent in (CoCrFeMn)$_{100-x}$Al$_{x}$. The predictions agree with our present experimental findings, and other reported ones.Comment: 27 pages, 9 figures, 1 tabl