Twisted [(R3P)PdX] groups above dicarbaborane ligands: 4-dimethylsulfido-3-iodo-3-triphenylphosphine-closo-3-pallada-1,2-dicarbadodecaborane and 3-dimethylphenylphosphine-3-chloro-4-dimethylsulfido-closo-3-pallada-1,2-dicarbadodecaborane

The structural analyses of [3-(PPh₃)-3-I-4-(SMe₂)-closo-3,1,2-PdC₂B₉H₁₀] or [Pd(C₄H₁₆B₉S)I(C₁₈H₁₅P)], (I), and [3-(PPhMe₂)-3-Cl-4-(SMe₂)-closo-3,1,2-PdC₂B₉H₁₀] or [Pd(C₄H₁₆B₉S)Cl(C₈H₁₁P)], (II), show that in comparison with [3-(PR₃)2-closo-3,1,2-PdC₂B₉H₁₁] the presence of the 4-SMe₂ group causes the [PdX(PR₃)] unit (X = halogen) to twist about an axis passing through the Pd atom and the directly opposite B atom of the carbaborane ligand. The halogen atoms are located almost directly above a C atom in the C₂B₃ face, and the conformations of the [PdX(PR₃)] units above the C₂B₃ faces are not those predicted from molecular orbital calculations of the closo-3,1,2-PdC₂B₉ system. The fact that the variation from the predicted conformation is greater in the case of (I) than in (II) may be ascribed to the greater steric interactions induced by the I atom in (I) compared with the Cl atom in (II)

Rapid Oscillations in Cataclysmic Variables. XV. HT Camelopardalis (= RX J0757.0+6306)

We present photometry and spectroscopy of HT Camelopardalis, a recently discovered X-ray-bright cataclysmic variable. The spectrum shows bright lines of H, He I, and He II, all moving with a period of 0.059712(1) d, which we interpret as the orbital period. The star's brightness varies with a strict period of 515.0592(2) s, and a mean full amplitude of 0.11 mag. These properties qualify it as a /bona fide/ DQ Herculis star (intermediate polar) -- in which the magnetism of the rapidly rotating white dwarf channels accretion flow to the surface. Normally at V=17.8, the star shows rare and very brief outbursts to V=12-13. We observed one in December 2001, and found that the 515 s pulse amplitude had increased by a factor of ~100 (in flux units). A transient orbital signal may also have appeared.Comment: PDF, 19 pages, 3 tables, 6 figures; accepted, in press, to appear June 2002, PASP; more info at http://cba.phys.columbia.edu

The Dwarf Nova PQ Andromedae

We report a photometric study of the WZ Sagittae-type dwarf nova PQ Andromedae. The light curve shows strong (0.05 mag full amplitude) signals with periods of 1263(1) and 634(1) s, and a likely double-humped signal with P=80.6(2) min. We interpret the first two as nonradial pulsation periods of the underlying white dwarf, and the last as the orbital period of the underlying binary. We estimate a distance of 150(50) pc from proper motions and the two standard candles available: the white dwarf and the dwarf-nova outburst. At this distance, the K magnitude implies that the secondary is probably fainter than any star on the main sequence -- indicating a mass below the Kumar limit at 0.075 M_sol. PQ And may be another "period bouncer", where evolution now drives the binary out to longer period.Comment: PDF, 13 pages, 2 figures; accepted, in press, to appear September 2005, PASP; more info at http://cba.phys.columbia.edu

Application of Sinboron Fibrous Monoliths for Air Breathing Engine Applications

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/76640/1/AIAA-2005-3646-549.pd

A protected area influences genotype-specific survival and the structure of a Canis hybrid zone

It is widely recognized that protected areas can strongly influence ecological systems and that hybridization is an important conservation issue. However, previous studies have not explicitly considered the influence of protected areas on hybridization dynamics. Eastern wolves are a species of special concern and their distribution is largely restricted to a protected population in Algonquin Provincial Park (APP), Ontario, Canada, where they are the numerically dominant canid. We studied intrinsic and extrinsic factors influencing survival and cause-specific mortality of hybrid and parental canids in the three-species hybrid zone between eastern wolves, eastern coyotes, and gray wolves in and adjacent to APP. Mortality risk for eastern wolves in areas adjacent to APP was significantly higher than for other sympatric Canis types outside of APP, and for eastern wolves and other canids within APP. Outside of APP, the annual mortality rate of all canids by harvest (24%) was higher than for other causes of death (4–7%). Furthermore, eastern wolves (hazard ratio ¼ 3.5) and nonresidents (transients and dispersing animals, hazard ratio ¼ 2.7) were more likely to die from harvest relative to other Canis types and residents, respectively. Thus, eastern wolves dispersing from APP were especially vulnerable to harvest mortality. For residents, eastern wolf survival was more negatively influenced by increased road density than for other Canis types, further highlighting the sensitivity of eastern wolves to human disturbance. A cycle of dispersal from APP followed by high rates of mortality and hybridization appears to maintain eastern wolves at low density adjacent to APP, limiting the potential for expansion beyond the protected area. However, high survival and numerical dominance of eastern wolves within APP suggest that protected areas can allow rare hybridizing species to persist even if their demographic performance is compromised and barriers to hybridization are largely absent in the adjacent matrix

Ion Thruster Development at NASA Lewis Research Center

Recent ion propulsion technology efforts at NASA's Lewis Research Center including development of kW-class xenon ion thrusters, high power xenon and krypton ion thrusters, and power processors are reviewed. Thruster physical characteristics, performance data, life projections, and power processor component technology are summarized. The ion propulsion technology program is structured to address a broad set of mission applications from satellite stationkeeping and repositioning to primary propulsion using solar or nuclear power systems

Resource selection at homesites by wolves and eastern coyotes in a \u3ci\u3eCanis\u3c/i\u3e hybrid zone

We modeled resource selection by wolves (Canis spp.), eastern coyotes (C. latrans), and admixed canids during the pup-rearing season at den and rendezvous sites (collectively, homesites) within a largely unprotected landscape proposed as the recovery zone for federally and provincially threatened eastern wolves (C. lycaon) in Ontario, Canada. Overall, canids selected wetlands, while avoiding secondary roads and open-structure rock-grass habitat patches. Packs with greater wolf ancestry selected wetlands and tertiary roads more strongly, while avoiding mixed conifer-hardwood forests. Contrary to our prediction, canids with greater coyote ancestry did not establish homesites closer to roads, which likely mitigated their risk of human-caused mortality during pup-rearing. Packs exhibited increased selection of wetlands within territories as a function of increasing availability of wetlands. Packs with abundant access to wetlands may prioritize this habitat type to exploit beavers, a valuable prey species during pup-rearing. Packs with higher pup survival selected hardwood forests and avoided conifer forests more than packs with lower pup survival. This is consistent with our understanding of habitat relations of the main prey species for canids in central Ontario and suggests that selecting prey-rich habitat types at homesites increases fitness. A proposed goal of eastern wolf recovery is numerical and geographical expansion outside of the population core in Algonquin Provincial Park. Thus, our results provide valuable information for conservation by quantifying resource selection of wolves, coyotes, and hybrids during pup-rearing and identifying links between fitness and homesite selection

The Effect of Ischemic Preconditioning on Repeated Sprint Cycling Performance

Purpose: Ischemic preconditioning enhances exercise performance. We tested the hypothesis that ischemic preconditioning would improve intermittent exercise in the form of a repeated sprint test during cycling ergometry.Methods: In a single-blind, crossover study, 14 recreationally active men (mean ± SD age, 22.9 ± 3.7 yr; height, 1.80 ± 0.07 m; and mass, 77.3 ± 9.2 kg) performed twelve 6-s sprints after four 5-min periods of bilateral limb occlusion at 220 mm Hg (ischemic preconditioning) or 20 mm Hg (placebo).Results: Ischemic preconditioning resulted in a 2.4% ± 2.2%, 2.6% ± 2.7%, and 3.7% ± 2.4% substantial increase in peak power for sprints 1, 2, and 3, respectively, relative to placebo, with no further changes between trials observed for any other sprint. Similar findings were observed in the first three sprints for mean power output after ischemic preconditioning (2.8% ± 2.5%, 2.6% ± 2.5%, and 3.4% ± 2.1%, for sprints 1, 2, and 3, respectively), relative to placebo. Fatigue index was not substantially different between trials. At rest, tissue saturation index was not different between the trials. During the ischemic preconditioning/placebo stimulus, there was a -19.7% ± 3.6% decrease in tissue saturation index in the ischemic preconditioning trial, relative to placebo. During exercise, there was a 5.4% ± 4.8% greater maintenance of tissue saturation index in the ischemic preconditioning trial, relative to placebo. There were no substantial differences between trials for blood lactate, electromyography (EMG) median frequency, oxygen uptake, or rating of perceived exertion (RPE) at any time points.Conclusion: Ischemic preconditioning improved peak and mean power output during the early stages of repeated sprint cycling and may be beneficial for sprint sports

QZ Serpentis: A Dwarf Nova with a 2-Hour Orbital Period and an Anomalously Hot, Bright Secondary Star

We present spectroscopy and time-series photometry of the dwarf nova QZ Ser. The spectrum shows a rich absorption line spectrum of type K4 +- 2. K-type secondary stars are generally seen in dwarf novae with orbital periods P-orb around 6 h, but in QZ Ser the absorption radial velocities show an obvious modulation (semi-amplitude 207(5) km/s) at P-orb = 119.752(2) min, much shorter than typical for such a relatively warm and prominent secondary spectrum. The H-alpha emission-line velocity is modulated at the same period and roughly opposite phase. Time-series photometry shows flickering superposed on a modulation with two humps per orbit, consistent with ellipsoidal variation of the secondary's light. QZ Ser is a second example of a relatively short-period dwarf nova with a surprisingly warm secondary. Model calculations suggest that the secondary is strongly enhanced in helium, and had already undergone significant nuclear evolution when mass transfer began. Several sodium absorption features in the secondary spectrum are unusually strong, which may indicate that the present-day surface was the site of CNO-cycle hydrogen burning in the past.Comment: 11 pages, 3 postscript figures, 1 jpeg greyscale figure. Accepted for publication in PAS