The spin 1/2 Heisenberg star with frustration II: The influence of the embedding medium

We investigate the spin 1/2 Heisenberg star introduced in J. Richter and A. Voigt, J. Phys. A: Math. Gen. {\bf 27}, 1139 (1994). The model is defined by $H=J_1 \sum_{i=1}^{N}{{\bf s}_0{\bf s}_i} + J_2 H_{R}\{{\bf s}_i\}$ ; $J_1,J_2 \ge 0$ , $i=1,...,N$. In extension to the Ref. we consider a more general $H_{R}\{{\bf s}_i\}$ describing the properties of the spins surrounding the central spin ${\bf s}_0$. The Heisenberg star may be considered as an essential structure element of a lattice with frustration (namely a spin embedded in a magnetic matrix $H_R$) or, alternatively, as a magnetic system $H_R$ with a perturbation by an extra spin. We present some general features of the eigenvalues, the eigenfunctions as well as the spin correlation $\langle {\bf s}_0{\bf s}_i \rangle$ of the model. For $H_R$ being a linear chain, a square lattice or a Lieb-Mattis type system we present the ground state properties of the model in dependence on the frustration parameter $\alpha=J_2/J_1$. Furthermore the thermodynamic properties are calculated for $H_R$ being a Lieb--Mattis antiferromagnet.Comment: 16 pages, uuencoded compressed postscript file, accepted to J. Phys. A: Math. Ge

The square-kagome quantum Heisenberg antiferromagnet at high magnetic fields: The localized-magnon paradigm and beyond

We consider the spin-1/2 antiferromagnetic Heisenberg model on the two-dimensional square-kagome lattice with almost dispersionless lowest magnon band. For a general exchange coupling geometry we elaborate low-energy effective Hamiltonians which emerge at high magnetic fields. The effective model to describe the low-energy degrees of freedom of the initial frustrated quantum spin model is the (unfrustrated) square-lattice spin-1/2 $XXZ$ model in a $z$-aligned magnetic field. For the effective model we perform quantum Monte Carlo simulations to discuss the low-temperature properties of the square-kagome quantum Heisenberg antiferromagnet at high magnetic fields. We pay special attention to a magnetic-field driven Berezinskii-Kosterlitz-Thouless phase transition which occurs at low temperatures.Comment: 6 figure

Enhanced magnetocaloric effect in frustrated magnetic molecules with icosahedral symmetry

We investigate the magnetocaloric properties of certain antiferromagnetic spin systems that have already been or very likely can be synthesized as magnetic molecules. It turns out that the special geometric frustration which is present in antiferromagnets that consist of corner-sharing triangles leads to an enhanced magnetocaloric effect with high cooling rates in the vicinity of the saturation field. These findings are compared with the behavior of a simple unfrustrated spin ring as well as with the properties of the icosahedron. To our surprise, also for the icosahedron large cooling rates can be achieved but due to a different kind of geometric frustration.Comment: 5 pages, 8 figures, more information at http://obelix.physik.uni-osnabrueck.de/~schnack

Structured identification of business improvement opportunities using Life Cycle Assessment : A case study in the gas turbine industry

Part of: Seliger, Günther (Ed.): Innovative solutions : proceedings / 11th Global Conference on Sustainable Manufacturing, Berlin, Germany, 23rd - 25th September, 2013. - Berlin: Universitätsverlag der TU Berlin, 2013. - ISBN 978-3-7983-2609-5 (online). - http://nbn-resolving.de/urn:nbn:de:kobv:83-opus4-40276. - pp. 205–209.In the last two decades the power sector has been adopting environmental conscious practices in several business areas and processes. Bridging the identification of environmental “hot-spots” in the product life cycle and the implementation and execution of an environmental management system requires an integrated approach starting with a Life Cycle Assessment to identify the improvement potentials; then analyzing the current management and product development systematics in use, and finally mapping the environmental practices against the improvement potential. The improvement tracking will be embedded in the management system as an Environmental Improvement Roadmap, mapping the efforts required to realize the goals. The methodology has been implemented in pilot studies, focusing on the processes performed in-house to enable further decisions on process alternatives and providing reliable information for strategic decisions within the Siemens Environmental Product Portfolio

Linear independence of localized magnon states

At the magnetic saturation field, certain frustrated lattices have a class of states known as "localized multi-magnon states" as exact ground states. The number of these states scales exponentially with the number $N$ of spins and hence they have a finite entropy also in the thermodynamic limit $N\to \infty$ provided they are sufficiently linearly independent. In this article we present rigorous results concerning the linear dependence or independence of localized magnon states and investigate special examples. For large classes of spin lattices including what we called the orthogonal type and the isolated type as well as the kagom\'{e}, the checkerboard and the star lattice we have proven linear independence of all localized multi-magnon states. On the other hand the pyrochlore lattice provides an example of a spin lattice having localized multi-magnon states with considerable linear dependence.Comment: 23 pages, 6 figure

A solvable model of a random spin-1/2 XY chain

The paper presents exact calculations of thermodynamic quantities for the spin-1/2 isotropic XY chain with random lorentzian intersite interaction and transverse field that depends linearly on the surrounding intersite interactions.Comment: 14 pages (Latex), 2 tables, 13 ps-figures included, (accepted for publication in Phys.Rev.B

Regularly alternating spin-1/2 anisotropic XY chains: The ground-state and thermodynamic properties

Using the Jordan-Wigner transformation and continued fractions we calculate rigorously the thermodynamic quantities for the spin-1/2 transverse Ising chain with periodically varying intersite interactions and/or on-site fields. We consider in detail the properties of the chains having a period of the transverse field modulation equal to 3. The regularly alternating transverse Ising chain exhibits several quantum phase transition points, where the number of transition points for a given period of alternation strongly depends on the specific set of the Hamiltonian parameters. The critical behavior in most cases is the same as for the uniform chain. However, for certain sets of the Hamiltonian parameters the critical behavior may be changed and weak singularities in the ground-state quantities appear. Due to the regular alternation of the Hamiltonian parameters the transverse Ising chain may exhibit plateau-like steps in the zero-temperature dependence of the transverse magnetization vs. transverse field and many-peak temperature profiles of the specific heat. We compare the ground-state properties of regularly alternating transverse Ising and transverse XX chains and of regularly alternating quantum and classical chains. Making use of the corresponding unitary transformations we extend the elaborated approach to the study of thermodynamics of regularly alternating spin-1/2 anisotropic XY chains without field. We use the exact expression for the ground-state energy of such a chain of period 2 to discuss how the exchange interaction anisotropy destroys the spin-Peierls dimerized phase

Dynamic and thermodynamic properties of the generalised diamond chain model for azurite

The natural mineral azurite Cu3(CO3)2(OH)2 is an interesting spin-1/2 quantum antiferromagnet. Recently, a generalised diamond chain model has been established as a good description of the magnetic properties of azurite with parameters placing it in a highly frustrated parameter regime. Here we explore further properties of this model for azurite. First, we determine the inelastic neutron scattering spectrum in the absence of a magnetic field and find good agreement with experiments, thus lending further support to the model. Furthermore, we present numerical data for the magnetocaloric effect and predict that strong cooling should be observed during adiabatic (de)magnetisation of azurite in magnetic fields slightly above 30T. Finally, the presence of a dominant dimer interaction in azurite suggests the use of effective Hamiltonians for an effective low-energy description and we propose that such an approach may be useful to fully account for the three-dimensional coupling geometry.Comment: 19 pages, 6 figures; to appear in: J. Phys.: Condens. Matter (special issue on geometrically frustrated magnetism

High spin cycles: topping the spin record for a single molecule verging on quantum criticality

The cyclisation of a short chain into a ring provides fascinating scenarios in terms of transforming a finite array of spins into a quasiinfinite structure. If frustration is present, theory predicts interesting quantum critical points, where the ground state and thus lowtemperature properties of a material change drastically upon even a small variation of appropriate external parameters. This can be visualised as achieving a very high and pointed summit where the way down has an infinity of possibilities, which by any parameter change will be rapidly chosen, in order to reach the final ground state. Here we report a mixed 3d/4f cyclic coordination cluster that turns out to be very near or even at such a quantum critical point. It has a ground state spin of S = 60, the largest ever observed for a molecule (120 times that of a single electron). [Fe10Gd10(Me-tea)10(Me-teaH)10(NO3)10]\ub720MeCN forms a nano-torus with alternating gadolinium and iron ions with a nearest neighbour Fe\u2013Gd coupling and a frustrating next-nearest neighbour Fe\u2013Fe coupling. Such a spin arrangement corresponds to a cyclic delta or saw-tooth chain, which can exhibit unusual frustration effects. In the present case, the quantum critical point bears a \u2018flatland\u2019 of tens of thousands of energetically degenerate states between which transitions are possible at no energy costs with profound caloric consequences. Entropy-wise the energy flatland translates into the pointed summit overlooking the entropy landscape. Going downhill several target states can be reached depending on the applied physical procedure which offers new prospects for addressability

Influence of quantum fluctuations on zero-temperature phase transitions between collinear and noncollinear states in frustrated spin systems

We study a square-lattice spin-half Heisenberg model where frustration is introduced by competing nearest-neighbor bonds of different signs. We discuss the influence of quantum fluctuations on the nature of the zero-temperature phase transitions from phases with collinear magnetic order at small frustration to phases with noncollinear spiral order at large frustration. We use the coupled cluster method (CCM) for high orders of approximation (up to LSUB6) and the exact diagonalization of finite systems (up to 32 sites) to calculate ground-state properties. The role of quantum fluctuations is examined by comparing the ferromagnetic-spiral and the antiferromagnetic-spiral transition within the same model. We find clear evidence that quantum fluctuations prefer collinear order and that they may favour a first order transition instead of a second order transition in case of no quantum fluctuations.Comment: 6 pages, 6 Postscipt figures; Accepted for publication in Phys. Rev.