1,489 research outputs found
Kinetic Monte Carlo simulations of oscillatory shape evolution for electromigration-driven islands
The shape evolution of two-dimensional islands under electromigration-driven
periphery diffusion is studied by kinetic Monte Carlo (KMC) simulations and
continuum theory. The energetics of the KMC model is adapted to the Cu(100)
surface, and the continuum model is matched to the KMC model by a suitably
parametrized choice of the orientation-dependent step stiffness and step atom
mobility. At 700 K shape oscillations predicted by continuum theory are
quantitatively verified by the KMC simulations, while at 500 K qualitative
differences between the two modeling approaches are found.Comment: 7 pages, 6 figure
Wissenschaftliches Arbeiten und Schreiben fĂĽr Maschinenbau-Studierende : Skript zur Vorlesung
Dieses Skript wurde für die Lehrveranstaltung „Einführung in wissenschaftliches Arbeiten und Schreiben" für Maschinenbau-Studierende
erstellt und ist zur Verwendung fĂĽr die Teilnehmer/Teilnehmerinnen der Veranstaltung und Interessierte vorgesehen
Morphological stability of electromigration-driven vacancy islands
The electromigration-induced shape evolution of two-dimensional vacancy
islands on a crystal surface is studied using a continuum approach. We consider
the regime where mass transport is restricted to terrace diffusion in the
interior of the island. In the limit of fast attachment/detachment kinetics a
circle translating at constant velocity is a stationary solution of the
problem. In contrast to earlier work [O. Pierre-Louis and T.L. Einstein, Phys.
Rev. B 62, 13697 (2000)] we show that the circular solution remains linearly
stable for arbitrarily large driving forces. The numerical solution of the full
nonlinear problem nevertheless reveals a fingering instability at the trailing
end of the island, which develops from finite amplitude perturbations and
eventually leads to pinch-off. Relaxing the condition of instantaneous
attachment/detachment kinetics, we obtain non-circular elongated stationary
shapes in an analytic approximation which compares favorably to the full
numerical solution.Comment: 12 page
Spiral Growth and Step Edge Barriers
The growth of spiral mounds containing a screw dislocation is compared to the
growth of wedding cakes by two-dimensional nucleation. Using phase field
simulations and homoepitaxial growth experiments on the Pt(111) surface we show
that both structures attain the same characteristic large scale shape when a
significant step edge barrier suppresses interlayer transport. The higher
vertical growth rate observed for the spiral mounds on Pt(111) reflects the
different incorporation mechanisms for atoms in the top region and can be
formally represented by an enhanced apparent step edge barrier.Comment: 11 pages, 4 figures, partly in colo
Hyperpolarization-Enhanced NMR Spectroscopy of Unaltered Biofluids Using Photo-CIDNP
Altres ajuts: acords transformatius de la UABThe direct and unambiguous detection and identification of individual metabolite molecules present in complex biological mixtures constitute a major challenge in (bio)analytical research. In this context, nuclear magnetic resonance (NMR) spectroscopy has proven to be particularly powerful owing to its ability to provide both qualitative and quantitative atomic-level information on multiple analytes simultaneously in a noninvasive manner. Nevertheless, NMR suffers from a low inherent sensitivity and, moreover, lacks selectivity regarding the number of individual analytes to be studied in a mixture of a myriad of structurally and chemically very different molecules, e.g., metabolites in a biofluid. Here, we describe a method that circumvents these shortcomings via performing selective, photochemically induced dynamic nuclear polarization (photo-CIDNP) enhanced NMR spectroscopy on unmodified complex biological mixtures, i.e., human urine and serum, which yields a single, background-free one-dimensional NMR spectrum. In doing this, we demonstrate that photo-CIDNP experiments on unmodified complex mixtures of biological origin are feasible, can be performed straightforwardly in the native aqueous medium at physiological metabolite concentrations, and act as a spectral filter, facilitating the analysis of NMR spectra of complex biofluids. Due to its noninvasive nature, the method is fully compatible with state-of-the-art metabolomic protocols providing direct spectroscopic information on a small, carefully selected subset of clinically relevant metabolites. We anticipate that this approach, which, in addition, can be combined with existing high-throughput/high-sensitivity NMR methodology, holds great promise for further in-depth studies and development for use in metabolomics and many other areas of analytical research
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