First-principles calculations of a high-pressure synthesized compound PtC

First-principles density-functional method is used to study the recently high-pressure synthesized compound PtC. It is confirmed by our calculations that the platinum carbide has a zinc-blende ground-state phase at zero pressure and the rock-salt structure is a high-pressure phase. The theoretical transition pressure from zinc-blende to rock-salt is determined to be 52GPa. Furthermore, our calculation shows the possibility that the experimentally synthesized PtC by Ono et al. under high pressure condition might undergo a transition from rock-salt structure to zinc-blende after the pressure quench to ambient condition.Comment: A revised versio

Out of plane effect on the superconductivity of Sr2-xBaxCuO3+y with Tc up to 98K

A series of new Sr2-xBaxCuO3+y (0 x 0.6) superconductors were prepared using high-pressure and high-temperature synthesis. A Rietveld refinement based on powder x-ray diffraction confirms that the superconductors crystallize in the K2NiF4-type structure of a space group I4/mmm similar to that of La2CuO4 but with partially occupied apical oxygen sites. It is found that the superconducting transition temperature Tc of this Ba substituted Sr2CuO3+y superconductor with constant carrier doping level, i.e., constant d, is controlled not only by order/disorder of apical-O atoms but also by Ba content. Tcmax =98 K is achieved in the material with x=0.6 that reaches the record value of Tc among the single-layer copper oxide superconductors, and is higher than Tc=95K of Sr2CuO3+y with optimally ordered apical-O atoms. There is Sr-site disorder in Sr2-xBaxCuO3+y which might lead to a reduction of Tc. The result indicates that another effect surpasses the disorder effect that is related either to the increased in-plane Cu-O bond length or to elongated apical-O distance due to Ba substitution with larger cation size. The present experiment demonstrates that the optimization of local geometry out of the Cu-O plane can dramatically enhance Tc in the cuprate superconductors.Comment: 23 Pages, 1 Table, 5 Figure

Hawking radiation from the Schwarzschild black hole with a global monopole via gravitational anomaly

Hawking flux from the Schwarzschild black hole with a global monopole is obtained by using Robinson and Wilczek's method. Adopting a dimension reduction technique, the effective quantum field in the (3+1)--dimensional global monopole background can be described by an infinite collection of the (1+1)--dimensional massless fields if neglecting the ingoing modes near the horizon, where the gravitational anomaly can be cancelled by the (1+1)--dimensional black body radiation at the Hawking temperature.Comment: 4 pages, no figure, 3nd revsion with one reference adde

Ozone Inhalation Attenuated the Effects of Budesonide on Aspergillus fumigatus-Induced Airway Inflammation and Hyperreactivity in Mice.

Inhaled glucocorticoids form the mainstay of asthma treatment because of their anti-inflammatory effects in the lung. Exposure to the air pollutant ozone (O3) exacerbates chronic airways disease. We and others showed that presence of the epithelial-derived surfactant protein-D (SP-D) is important in immunoprotection against inflammatory changes including those induced by O3 inhalation in the airways. SP-D synthesis requires glucocorticoids. We hypothesized here that O3 exposure impairs glucocorticoid responsiveness (including SP-D production) in allergic airway inflammation. The effects of O3 inhalation and glucocorticoid treatment were studied in a mouse model of allergic asthma induced by sensitization and challenge with Aspergillus fumigatus (Af) in vivo. The role of O3 and glucocorticoids in regulation of SP-D expression was investigated in A549 and primary human type II alveolar epithelial cells in vitro. Budesonide inhibited airway hyperreactivity, eosinophil counts in the lung and bronchoalveolar lavage (BAL) and CCL11, IL-13, and IL-23p19 release in the BAL of mice sensitized and challenged with Af (p < 0.05). The inhibitory effects of budesonide were attenuated on inflammatory changes and were completely abolished on airway hyperreactivity after O3 exposure of mice sensitized and challenged with Af. O3 stimulated release of pro-neutrophilic mediators including CCL20 and IL-6 into the airways and impaired the inhibitory effects of budesonide on CCL11, IL-13 and IL-23. O3 also prevented budesonide-induced release of the immunoprotective lung collectin SP-D into the airways of allergen-challenged mice. O3 had a bi-phasic direct effect with early (<12 h) inhibition and late (>48 h) activation of SP-D mRNA (sftpd) in vitro. Dexamethasone and budesonide induced sftpd transcription and translation in human type II alveolar epithelial cells in a glucocorticoid receptor and STAT3 (an IL-6 responsive transcription factor) dependent manner. Our study indicates that O3 exposure counteracts the effects of budesonide on airway inflammation, airway hyperreactivity, and SP-D production. We speculate that impairment of SP-D expression may contribute to the acute O3-induced airway inflammation. Asthmatics exposed to high ambient O3 levels may become less responsive to glucocorticoid treatment during acute exacerbations

High-Pressure Induced Structural Phase Transition in CaCrO4: Evidence from Raman Scattering Studies

Raman spectroscopic studies have been carried out on CaCrO4 under pressure up to 26GPa at ambient temperature. The Raman spectra showed CaCrO4 experienced a continuous structural phase transition started at near 6GPa, and finished at about 10GPa. It is found that the high-pressure phase could be quenched to ambient conditions. Pressure dependence of the Raman peaks suggested there existed four pressure regions related to different structural characters. We discussed these characters and inferred that the nonreversible structural transition in CaCrO4, most likely was from a zircon-type (I41/amd) ambient phase to a scheelite-type high pressure structure (I41/a).Comment: submitte

Words are Malleable: Computing Semantic Shifts in Political and Media Discourse

Recently, researchers started to pay attention to the detection of temporal shifts in the meaning of words. However, most (if not all) of these approaches restricted their efforts to uncovering change over time, thus neglecting other valuable dimensions such as social or political variability. We propose an approach for detecting semantic shifts between different viewpoints--broadly defined as a set of texts that share a specific metadata feature, which can be a time-period, but also a social entity such as a political party. For each viewpoint, we learn a semantic space in which each word is represented as a low dimensional neural embedded vector. The challenge is to compare the meaning of a word in one space to its meaning in another space and measure the size of the semantic shifts. We compare the effectiveness of a measure based on optimal transformations between the two spaces with a measure based on the similarity of the neighbors of the word in the respective spaces. Our experiments demonstrate that the combination of these two performs best. We show that the semantic shifts not only occur over time, but also along different viewpoints in a short period of time. For evaluation, we demonstrate how this approach captures meaningful semantic shifts and can help improve other tasks such as the contrastive viewpoint summarization and ideology detection (measured as classification accuracy) in political texts. We also show that the two laws of semantic change which were empirically shown to hold for temporal shifts also hold for shifts across viewpoints. These laws state that frequent words are less likely to shift meaning while words with many senses are more likely to do so.Comment: In Proceedings of the 26th ACM International on Conference on Information and Knowledge Management (CIKM2017