Temporal evolution and instability in a viscoelastic dielectric elastomer

Dielectric elastomer transducers are being developed for applications in stretchable electronics, tunable optics, biomedical devices, and soft machines. These transducers exhibit highly nonlinear electromechanical behavior: a dielectric membrane under voltage can form wrinkles, undergo snap-through instability, and suffer electrical breakdown. We investigate temporal evolution and instability by conducting a large set of experiments under various prestretches and loading rates, and by developing a model that allows viscoelastic instability. We use the model to classify types of instability, and map the experimental observations according to prestreches and loading rates. The model describes the entire set of experimental observations. A new type of instability is discovered, which we call wrinkle-to-wrinkle transition. A flat membrane at a critical voltage forms wrinkles and then, at a second critical voltage, snaps into another state of winkles of a shorter wavelength. This study demonstrates that viscoelasticity is essential to the understanding of temporal evolution and instability of dielectric elastomers.Engineering and Applied Science

Large, Uni-directional Actuation in Dielectric Elastomers Achieved By Fiber Stiffening

Cylindrical actuators are made with dielectric elastomer sheets stiffened with fibers in the hoop direction. When a voltage is applied through the thickness of the sheets, large actuation strains are achievable in the axial direction, with or without pre-straining and mechanical loading. For example, actuation strains of 35.8% for a cylinder with a prestrain of 40%, and 28.6% for a cylinder without pre-strain have been achieved without any optimization. Furthermore, the actuation strain is independent of the aspect ratio of the cylinder, so that both large strains and large displacements are readily actuated by using long cylinders.Physic

3-(4-Meth­oxy­benzyl­idene)-1,5-dioxa­spiro­[5.5]undecane-2,4-dione

In the title mol­ecule, C17H18O5, which was prepared by the reaction of (R)-1,5-dioxaspiro­[5.5]undecane-2,4-dione and 4-meth­oxy­benzaldehyde with ethanol, the 1,3-dioxane ring is in a distorted envelope conformation with the spiro C atom forming the flap. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds

Highly deformable actuators made of dielectric elastomers clamped by rigid rings

In the nascent field of soft machines, soft materials are used to create devices that actuate robots, sense environment, monitor health, and harvest energy. The soft materials undergo large deformation in response to external stimuli, often leading to instability that is usually undesirable but sometimes useful. Here, we study a dielectric elastomer membrane sandwiched between two soft conductors, rolled into a hollow tube, pre-stretched in the hoop direction, and fixed at the ends of the tube to two rigid rings. This structure functions as an electromechanical transducer when the two rings are subject to a mechanical force and the two conductors are subject to an electrical voltage. We formulate a computational model by using a variational principle and calculate the large and inhomogeneous deformation by solving a nonlinear boundary-value problem. We demonstrate that large actuation strains are achievable when the height-to-radius ratio of the tube is small and the hoop pre-stretch is large. The model provides a tool to analyze various modes of instability and optimize the electromechanical performance.Engineering and Applied Science

Giant, Voltage-Actuated Deformation of a Dielectric Elastomer under Dead Load

Far greater voltage-actuated deformation is achievable for a dielectric elastomer under equal-biaxial dead load than under rigid constraint usually employed. Areal strains of 488% are demonstrated. The dead load suppresses electric breakdown, enabling the elastomer to survive the snap-through electromechanical instability. The breakdown voltage is found to increase with the voltage ramp rate. A nonlinear model for viscoelastic dielectric elastomers is developed and shown to be consistent with the experimental observations.Engineering and Applied Science

800nm fiber Bragg Grating sensing interrogation system using TFBG and CCD array

An 800nm band fiber Bragg grating sensing interrogation system using TFBG as the core wavelength division component is presented. A charge coupled device (CCD) linear array is put on the focal plane of the lens to detect the light. TFBG is used to tap light out of the fiber core to fiber cladding. The sensing wavelength is 795 to 830nm, with accuracy of 20pm and scan speed 100Hz. Using FBG sensor, we achieve the temperature sensitivity as 1.8°C and strain sensitivity as 18με

Identify submitochondria and subchloroplast locations with pseudo amino acid composition: Approach from the strategy of discrete wavelet transform feature extraction

AbstractIt is very challenging and complicated to predict protein locations at the sub-subcellular level. The key to enhancing the prediction quality for protein sub-subcellular locations is to grasp the core features of a protein that can discriminate among proteins with different subcompartment locations. In this study, a different formulation of pseudoamino acid composition by the approach of discrete wavelet transform feature extraction was developed to predict submitochondria and subchloroplast locations. As a result of jackknife cross-validation, with our method, it can efficiently distinguish mitochondrial proteins from chloroplast proteins with total accuracy of 98.8% and obtained a promising total accuracy of 93.38% for predicting submitochondria locations. Especially the predictive accuracy for mitochondrial outer membrane and chloroplast thylakoid lumen were 82.93% and 82.22%, respectively, showing an improvement of 4.88% and 27.22% when other existing methods were compared. The results indicated that the proposed method might be employed as a useful assistant technique for identifying sub-subcellular locations. We have implemented our algorithm as an online service called SubIdent (http://bioinfo.ncu.edu.cn/services.aspx)

Highly Stretchable and Transparent Ionogels as Nonvolatile Conductors for Dielectric Elastomer Transducers

Large deformation of soft materials is harnessed to provide functions in the nascent field of soft machines. This paper describes a new class of systems enabled by highly stretchable, transparent, stable ionogels. We synthesize an ionogel by polymerizing acrylic acid in ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate ([C2mim][EtSO4]). The ionogel exhibits desired attributes of adequate conductivity (0.22 S m−1), low elastic modulus (∼3 kPa), large rupturing stretch (∼4.6), and negligible hysteresis and degradation after cyclic stretches of large amplitude. Using the ionogel and a dielectric elastomer, we fabricate electromechanical transducers that achieve a voltage-induced areal strain of 140%. The ionogel is somewhat hygroscopic, but the transducers remain stable after a million cycles of excitation in a dry oven and in air. The transparency of the ionogels enable the transducers with conductors placed in the path of light, and the nonvolatility of the ionogels enable the transducers to be used in open air.Engineering and Applied Science

Suppression of hepatic natural killer activity by liver metastasis of cancer and restoration of killer activity by oral administration of a Basidomycetes-derived polysaccharide, PSK.

PSK (Krestin) is a protein-bound polysaccharide with antitumor and immunomodulatory activity. In this study, the effects of the oral administration of PSK were investigated on the natural killer (NK) activity of liver-associated lymphocytes and their subfractions separated by density gradient centrifugation, in WKAH rats with liver metastasis of KDA hepatoma. PSK was administered orally, at a dose of 500 mg/kg once a day for 3 weeks. The NK activity of nonparenchymal liver cells (NPLC) and their subfractions, including large granular lymphocytes (LGL), was markedly augmented by this treatment. The effects of oral PSK were also examined in CDF1 mice with liver metastases of Colon 26 adenocarcinoma; the survival of tumor-bearing mice was prolonged and both metastatic foci and liver weight were decreased. These results suggest that PSK may be effective for the suppression of liver metastasis through activation of liver-associated NK cells.</p