12 research outputs found
Towards a Cost-Benefit-Analysis of Data-Driven Business Models
The emergence of data-driven business models calls for their systematic design and evaluation. In this paper, we focus on a first step towards a Cost-Benefit-Analysis of data-driven business models. Within data-driven business models, data act as enabler for the development of innovative services. However, to justify internal funding of new services, an assessment of the financial impact for the service at hand is often required. We approach this by identifying drivers of cost and benefit based on the Service Business Model Canvases of twenty cases. Based on the results, all drivers and their associated models for quantification were consolidated into a single meta-model. With this, we provide a basis for the economic assessment of service ideas and their refinement during the design process
Independent electrical tuning of separated quantum dots in coupled photonic crystal cavities
Systems of photonic crystal cavities coupled to quantum dots are a promising
architecture for quantum networking and quantum simulators. The ability to
independently tune the frequencies of laterally separated quantum dots is a
crucial component of such a scheme. Here, we demonstrate independent tuning of
laterally separated quantum dots in photonic crystal cavities coupled by
in-plane waveguides by implanting lines of protons which serve to electrically
isolate different sections of a diode structure.Comment: 3 pages, 3 figure
Strain-tuning of quantum dot optical transitions via laser-induced surface defects
We discuss the fine-tuning of the optical properties of self-assembled
quantum dots by the strain perturbation introduced by laser-induced surface
defects. We show experimentally that the quantum dot transition red-shifts,
independently of the actual position of the defect, and that such frequency
shift is about a factor five larger than the corresponding shift of a
micropillar cavity mode resonance. We present a simple model that accounts for
these experimental findings.Comment: 9 pages, 6 figures. To appear in Phys. Rev.
Tuning micropillar cavity birefringence by laser induced surface defects
We demonstrate a technique to tune the optical properties of micropillar
cavities by creating small defects on the sample surface near the cavity region
with an intense focused laser beam. Such defects modify strain in the
structure, changing the birefringence in a controllable way. We apply the
technique to make the fundamental cavity mode polarization-degenerate and to
fine tune the overall mode frequencies, as needed for applications in quantum
information science.Comment: RevTex, 7 pages, 4 figures (accepted for publication in Applied
Physics Letters
CNOT and Bell-state analysis in the weak-coupling cavity QED regime
We propose an interface between the spin of a photon and the spin of an
electron confined in a quantum dot embedded in a microcavity operating in the
weak coupling regime. This interface, based on spin selective photon reflection
from the cavity, can be used to construct a CNOT gate, a multi-photon entangler
and a photonic Bell-state analyzer. Finally, we analyze experimental
feasibility, concluding that the schemes can be implemented with current
technology.Comment: 4 pages, 2 figure
Optical modes in oxide-apertured micropillar cavities
We present a detailed experimental characterization of the spectral and
spatial structure of the confined optical modes for oxide-apertured micropillar
cavities, showing good-quality Hermite-Gaussian profiles, easily mode-matched
to external fields. We further derive a relation between the frequency
splitting of the transverse modes and the expected Purcell factor. Finally, we
describe a technique to retrieve the profile of the confining refractive index
distribution from the spatial profiles of the modes.Comment: 4 pages, 3 figure
BUSINESS MODEL TRANSFORMATION PATTERNS OF DATA-DRIVEN INNOVATIONS
Driven by advances in information and communication technologies (ICT), manifold business opportunities emerge in diverse industries. In this development, data plays an important role as an essential element of change and economic growth. As a consequence of this development, the analysis of service business models and the role of data in these models has become a focus of interest in practice and research. This paper focuses on international companies that implemented successfully data-driven innovations and aims, in particular, at the analysis of the effects of data-driven innovation on companies’ business models. Based on a multiple case study method, this paper proposes four different transformation patterns: (1) cooperative value innovation, (2) customer-centric value innovation, (3) cooperative productivity improvement, and (4) company-centric productivity improvement. These patterns show that data-driven innovations enable a transformation from product to service-oriented offerings. Furthermore, an optimization of internal and external processes and thus, of the productivity is possible
Permanent tuning of quantum dot transitions to degenerate microcavity resonances
Quantum Matter and Optic
Donor-Free Phosphenium–Metal(0)–Halides with Unsymmetrically Bridging Phosphenium Ligands
Reactions of (cod)MCl<sub>2</sub> (cod = 1,5 cyclooctadiene, M = Pd, Pt) with <i>N</i>-heterocyclic
secondary phosphines or diphosphines produced complexes [(NHP)MCl]<sub>2</sub> (NHP = <i>N</i>-heterocyclic phosphenium). The
Pd complex was also accessible from a chlorophosphine precursor and
Pd<sub>2</sub>(dba)<sub>3</sub>. Single-crystal X-ray diffraction
studies established the presence of dinuclear complexes that contain
μ-bridging NHP ligands in an unsymmetrical binding mode and
display a surprising change in metal coordination geometry from distorted
trigonal (M = Pd) to T-shaped (M = Pt). DFT calculations on model
compounds reproduced these structural features for the Pt complex
but predicted an unusual <i>C</i><sub>2<i>v</i></sub>-symmetric molecular structure with two different metal coordination
environments for the Pd species. The deviation between this structure
and the actual centrosymmetric geometry is accounted for by the prediction
of a flat energy hypersurface, which permits large distortions in
the orientation of the NHP ligands at very low energetic cost. The
DFT results and spectroscopic studies suggest that the title compounds
should be described as phosphenium–metal(0)–halides
rather than conventional phosphido complexes of divalent metal cations
and indicate that the NHP ligands receive net charge donation from
the metals but retain a distinct cationic character. The unsymmetric
NHP binding mode is associated with an unequal distribution of σ-donor/π-acceptor
contributions in the two M–P bonds. Preliminary studies indicate
that reactions of the Pd complex with phosphine donors provide a viable
source of ligand-stabilized, zerovalent metal atoms and metal(0)–halide
fragments
Phosphenium Hydride Reduction of [(cod)MX<sub>2</sub>] (M = Pd, Pt; X = Cl, Br): Snapshots on the Way to Phosphenium Metal(0) Halides and Synthesis of Metal Nanoparticles
The
outcome of the reduction of [(cod)PtX<sub>2</sub>] (X = Cl,
Br; cod = 1,5-cyclooctadiene) with N-heterocyclic phosphenium hydrides <sup>R</sup>NHP–H depends strongly on the steric demand of the <i>N</i>-aryl group R and the nature of X. Reaction of [(cod)PtCl<sub>2</sub>] with <sup>Dipp</sup>NHP–H featuring bulky N-Dipp
groups produced an unprecedented monomeric phosphenium metal(0) halide
[(<sup>Dipp</sup>NHP)(<sup>Dipp</sup>NHP–H)PtCl] stabilized
by a single phosphine ligand. The phosphenium unit exhibits a pyramidal
coordination geometry at the phosphorus atom and may according to
DFT calculations be classified as a Z-type ligand. In contrast, reaction
of [(cod)PtBr<sub>2</sub>] with the sterically less protected <sup>Mes</sup>NHP–H afforded a mixture of donor-ligand free oligonuclear
complexes [{(<sup>Mes</sup>NHP)PtBr}<sub><i>n</i></sub>]
(<i>n</i> = 2, 3), which are structural analogues of known
palladium complexes with μ<sub>2</sub>-bridging phosphenium
units. All reductions studied proceed via spectroscopically detectable
intermediates, several of which could be unambiguously identified
by means of multinuclear (<sup>1</sup>H, <sup>31</sup>P, <sup>195</sup>Pt) NMR spectroscopy and computational studies. The experimental
findings reveal that the phosphenium hydrides in these multistep processes
adopt a dual function as ligands and hydride transfer reagents. The
preference for the observed intricate pathways over seemingly simpler
ligand exchange processes is presumably due to kinetic reasons. The
attempt to exchange the bulky phosphine ligand in [(<sup>Dipp</sup>NHP)(<sup>Dipp</sup>NHP–H)PtCl] by Me<sub>3</sub>P resulted
in an unexpected isomerization to a platinum(0) chlorophosphine complex
via a formal chloride migration from platinum to phosphorus, which
accentuates the electrophilic nature of the phosphenium ligand. Phosphenium
metal(0) halides of platinum further show a surprising thermal stability,
whereas the palladium complexes easily disintegrate upon gentle heating
in dimethyl sulfoxide to yield metal nanoparticles, which were characterized
by TEM and XRD studies