502 research outputs found

    St. Thomas and the World State. By Dr. Robert M. Hutchins.

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    St. Thomas and the World State. By Dr. Robert M. Hutchins.

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    Reconversion of Parahydrogen Gas in Surfactant-Coated Glass NMR Tubes

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    The application of parahydrogen gas to enhance the magnetic resonance signals of a diversity of chemical species has increased substantially in the last decade. Parahydrogen is prepared by lowering the temperature of hydrogen gas in the presence of a catalyst; this enriches the para spin isomer beyond its normal abundance of 25% at thermal equilibrium. Indeed, parahydrogen fractions that approach unity can be attained at sufficiently low temperatures. Once enriched, the gas will revert to its normal isomeric ratio over the course of hours or days, depending on the surface chemistry of the storage container. Although parahydrogen enjoys long lifetimes when stored in aluminum cylinders, the reconversion rate is significantly faster in glass containers due to the prevalence of paramagnetic impurities that are present within the glass. This accelerated reconversion is especially relevant for nuclear magnetic resonance (NMR) applications due to the use of glass sample tubes. The work presented here investigates how the parahydrogen reconversion rate is affected by surfactant coatings on the inside surface of valved borosilicate glass NMR sample tubes. Raman spectroscopy was used to monitor changes to the ratio of the (J: 0 → 2) vs. (J: 1 → 3) transitions that are indicative of the para and ortho spin isomers, respectively. Nine different silane and siloxane-based surfactants of varying size and branching structures were examined, and most increased the parahydrogen reconversion time by 1.5×–2× compared with equivalent sample tubes that were not treated with surfactant. This includes expanding the pH2 reconversion time from 280 min in a control sample to 625 min when the same tube is coated with (3-Glycidoxypropyl)trimethoxysilane

    Structuring Joint Action Routines: A Strategy for Facilitating Communication and Language Development in the Classroom

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    The study of early child language has produced a wealth of new data and con­comitant theories over the past decade, and these new perspectives offer important im­plications to those of us engaged in clinical practice. We have noted elsewhere that this current literature on early child language has specific implications for designing ap­propriate targets, contexts, and procedures for language therapy (McLean and Snyder-­McLean, 1978; McLean, Snyder-McLean, and Sack, 1983). In this article, we will con­centrate on these two latter areas: contexts and procedures for language intervention and, more specifically, on the combination of these elements in the form of structured joint action routines

    Late Triassic to Jurassic Magmatic and Tectonic Evolution of the Intermontane Terranes in Yukon, Northern Canadian Cordillera: Transition From Arc to Syn-Collisional Magmatism and Post-Collisional Lithospheric Delamination

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    End-on arc collision and onset of the northern Cordilleran orogen is recorded in Late Triassic to Jurassic plutons in the Intermontane terranes of Yukon, and in development of the synorogenic Whitehorse trough (WT). A synthesis of the extensive data set for these plutons supports interpretation of the magmatic and tectonic evolution of the northern Intermontane terranes. Late Triassic juvenile plutons that locally intrude the Yukon-Tanana terrane represent the northern extension of arc magmatism within Stikinia. Early Jurassic plutons that intrude Stikinia and Yukon-Tanana terranes were emplaced during crustal thickening (200–195 Ma) and subsequent exhumation (190–178 Ma). The syn-collisional magmatism migrated to the south and shows increasing crustal contributions with time. This style of magmatism in Yukon contrasts with coeval, juvenile arc magmatism in British Columbia (Hazelton Group), that records southward arc migration in the Early Jurassic. Exhumation and subsidence of the WT in the north were probably linked to the retreating Hazelton arc by a sinistral transform. East of WT, Early Jurassic plutons intruded into Yukon-Tanana record continued arc magmatism in Quesnellia. Middle Jurassic plutons were intruded after final enclosure of the Cache Creek terrane and imbrication of the Intermontane terranes. The post-collisional plutons have juvenile isotopic compositions that, together with stratigraphic evidence of surface uplift, are interpreted to record asthenospheric upwelling and lithospheric delamination. A revised tectonic model proposes that entrapment of the Cache Creek terrane was the result of Hazelton slab rollback and development of a sinistral transform fault system linked to the collision zone to the north
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