IODP Expeditions 303 and 306 Monitor Miocene-Quaternary Climate in the North Atlantic

Introduction The IODP Expeditions 303 and 306 drilling sites were chosen for two reasons: (1) to capture Miocene-Quaternary millennial-scale climate variability in sensitive regions at the mouth of the Labrador Sea and in the North Atlantic icerafted debris (IRD) belt (Ruddiman et al., 1977), and (2) to provide the sedimentary and paleomagnetic attributes, including adequate sedimentation rates, for constructinghigh-resolution isotopic and magnetic stratigraphies.High accumulation rates, reaching 20 cm ky-1, permit the study of millennial-scale variations in climate and in the Earth's magnetic fi eld over the past several million years, when the amplitude and frequency of climate variability changed substantially. Shipboard logging and scanning data (magnetic susceptibility and remanence, density, natural gamma radiation, digital images and color refl ectance) and post-expedition x-ray fl uorescence (XRF) scanning datahave revealed that the sediment cores recovered on Expeditions 303 and 306 contain detailed histories of millennial-scale climate and geomagnetic fi eld variability throughout the late Miocene to Quaternary epochs. The climate proxies will be integrated with paleomagnetic data to place the records of millennial-scale climate change into a high resolution stratigraphy based on oxygen isotope andrelative paleomagnetic intensity (RPI). The paleomagnetic record of polarity reversals, excursions and RPI in these cores is central to the construction of the stratigraphic template and will provide detailed documentation of geomagnetic fi eld behavior

Climate variability and ice-sheet dynamics during the last three glaciations

AbstractA composite North Atlantic record from DSDP Site 609 and IODP Site U1308 spans the past 300,000 years and shows that variability within the penultimate glaciation differed substantially from that of the surrounding two glaciations. Hematite-stained grains exhibit similar repetitive down-core variations within the Marine Isotope Stage (MIS) 8 and 4–2 intervals, but little cyclic variability within the MIS 6 section. There is also no petrologic evidence, in terms of detrital carbonate-rich (Heinrich) layers, for surging of the Laurentide Ice Sheet through the Hudson Strait during MIS 6. Rather, very high background concentration of iceberg-rafted debris (IRD) indicates near continuous glacial meltwater input that likely increased thermohaline disruption sensitivity to relatively weak forcing events, such as expanded sea ice over deepwater formation sites. Altered (sub)tropical precipitation patterns and Antarctic warming during high orbital precession and low 65°N summer insolation appear related to high abundance of Icelandic glass shards and southward sea ice expansion. Differing European and North American ice sheet configurations, perhaps aided by larger variations in eccentricity leading to cooler summers, may have contributed to the relative stability of the Laurentide Ice Sheet in the Hudson Strait region during MIS 6

Testing the relationship between timing of geomagnetic reversals/excursions and phase of orbital cycles using circular statistics and Monte Carlo simulations

Fuller (Fuller, M., Geomagnetic field intensity, excursions, reversals and the 41,000-yr obliquity signal, Earth Planet. Sci. Lett. 245 (2006) 605–615.) pointed out that, for 9 reversals over the last 3 Myr, reversal age has a non-random relationship to the phase of orbital obliquity. Our analysis, based on Rayleigh tests, indicates that reversals have no preferred phase distribution in the obliquity cycle at the 5% significance level over the last 3 Myr. There is, however, a statistically significant relationship (at the 5% level) between reversal age and the phase of orbital eccentricity for the last 3 Myr, although this relationship breaks down on adding just a few reversals beyond 3 Ma. Over the last 5 Myr, reversals preferentially occurred during decrease of the maximum obliquity envelope although, yet again, the relationship does not hold as additional reversals are added to the analysis, no matter which timescale is tested. The Rayleigh tests are all based on the assumption of no uncertainty in reversal/excursion age, or in orbital solutions. Monte Carlo simulations indicate that reversal/excursion ages would have to be known within 5–10 kyr to resolve a preferred phase in obliquity similar to that advocated by Fuller (Fuller, M., Geomagnetic field intensity, excursions, reversals and the 41,000-yr obliquity signal, Earth Planet. Sci. Lett. 245 (2006) 605–615.) over the last 3 Myr. Reversal/excursion ages would have to be known within ~15 kyr to resolve a preferred phase in orbital eccentricity for reversals over the last 3 Myr, and within ~40 kyr for the last 25 Myr. Comparison of astrochronological reversal timescales indicates that reversal age uncertainties exceed these limits, making it unlikely that a relationship of reversal/excursion age to the phase of obliquity or eccentricity would be resolvable. In the case of the obliquity envelope, the critical levels of reversal age uncertainty (~50 kyr for 0–3 Ma, ~200 kyr for 0–5 Ma, and ~400 kyr for 0–25 Ma) are less stringent. The presence of a significant relationship between reversal age and phase of the obliquity envelope for the last 5 Myr, but not further back in time, implies either larger than expected reversal age uncertainties in pre-Pliocene polarity timescales and a link between reversal age and the obliquity envelope, or, more probably, the fortuitous occurrence of a low probability relationship over the last 5 Ma that has no mechanistic implication

Origin of apparent magnetic excursions in deep-sea sediments from Mendeleev-Alpha Ridge, Arctic Ocean

Arctic deep-sea sediments often record intervals of negative inclination of natural remanence that are tens of centimeters thick, implying magnetic excursions with durations of tens of thousand years that far exceed excursion durations estimated elsewhere, and the lack of tight age control usually provides excessive freedom in the labeling of Arctic excursions. Fortuitous variations in sedimentation rate have been invoked to explain the “amplified” excursions. Alternating field demagnetization of natural remanent magnetization (NRM) of sediment cores 08JPC, 10JPC, 11JPC, and 13JPC recovered by the Healy Oden Trans-Arctic Expedition in August 2005 (HOTRAX05) to the Mendeleev-Alpha Ridge yields apparent magnetic “excursions” in sediments deposited in the Brunhes Chron. Thermal demagnetization of the NRM, however, implies multiple magnetization components with negative inclination components usually “unblocked” below ?350°C. Analysis of isothermal remanent magnetization acquisition curves from magnetic extracts indicates two magnetic coercivity components superimposed on one another. Magnetic experiments conducted under high and low temperatures show features that are characteristic for (titano)magnetite and titanomaghemite. Presence of the two magnetic phases is further confirmed by elemental mapping on a scanning electron microscope equipped for X-ray energy dispersive spectroscopy (EDS) and by high-resolution X-ray diffraction (XRD). It is unlikely that anomalously thick intervals of negative inclination in these Brunhes-aged sediments are caused by unusual behavior of the magnetic field in the Arctic area. We therefore attribute low and negative NRM inclinations in these cores to partially self-reversed chemical remanent magnetizations, apparently carried by titanomaghemite and acquired during the oxidation of detrital (titano)magnetite grains. The high Ti contents and high oxidation states indicated by EDS and XRD data provide the conditions required for partial self-reversal by ionic reordering during diagenetic maghemitization, and this process appears to have affected all HOTRAX05 cores collected from the Mendeleev-Alpha Ridge

Origin of orbital periods in the sedimentary relative paleointensity records

Orbital cycles with 100 kyr and/or 41 kyr periods, detected in some sedimentary normalized remanence (relative paleointensity) records by power spectral analysis or wavelet analysis, have been attributed either to orbital forcing of the geodynamo, or to lithologic contamination. In this study, local wavelet power spectra (LWPS) with significance tests have been calculated for seven relative paleointensity (RPI) records from different regions of the world. The results indicate that orbital periods (100 kyr and/or 41 kyr) are significant in some RPI records during certain time intervals, and are not significant in others. Time intervals where orbital periods are significant are not consistent among the RPI records, implying that orbital periods in these RPI records may not have a common origin such as orbital forcing on the geodynamo. Cross-wavelet power spectra (|XWT|) and squared wavelet coherence (WTC) between RPI records and orbital parameters further indicate that common power exists at orbital periods but is not significantly coherent, and exhibits variable phase relationships, implying that orbital periods in RPI records are not caused directly by orbital forcing. Similar analyses for RPI records and benthic oxygen isotope records from the same sites show significant coherence and constant in-phase relationships during time intervals where orbital periods were significant in the RPI records, indicating that orbital periods in the RPI records are most likely due to climatic ‘contamination’. Although common power exists at orbital periods for RPI records and their normalizers with significant coherence during certain time intervals, phase relationships imply that ‘contamination’ (at orbital periods) is not directly due to the normalizers. Orbital periods are also significant in the NRM intensity records, and ‘contamination’ in RPI records can be attributed to incomplete normalization of the NRM records. Further tests indicate that ‘contamination’ is apparently not directly related to physical properties such as density or carbonate content, or to the grain size proxy κARM/κ. However, WTC between RPI records and the grain size proxy ARM/IRM implies that ARM/IRM does reflect the ‘contamination’ in some RPI records. It appears that orbital periods were introduced into the NRM records (and have not been normalized when calculating RPI records) through magnetite grain size variations reflected in the ARM/IRM grain size proxy. The orbital power in ARM/IRM for some North Atlantic sites is probably derived from bottom-current velocity variations that are orbitally modulated and are related to the vigor of thermohaline circulation and the production of North Atlantic Deep Water (NADW). In the case of ODP Site 983, the orbital power in RPI appears to exhibit a shift from 41-kyr to 100-kyr period at the mid-Pleistocene climate transition (~750 ka), reinforcing the climatic origin of these orbital periods. RPI records from the Atlantic and Pacific oceans, and RPI records with orbital periods eliminated by band-pass filters, are highly comparable with each other in the time domain, and are coherent and in-phase in time-frequency space, especially at non-orbital periods, indicating that ‘contamination’, although present (at orbital periods) is not debilitating to these RPI records as a global signal that is primarily of geomagnetic origin

Paleomagnetism of Quaternary sediments from Lomonosov Ridge and Yermak Plateau: implications for age models in the Arctic Ocean

Inclination patterns of natural remanent magnetization (NRM) in Quaternary sediment cores from the Arctic Ocean have been widely used for stratigraphic correlation and the construction of age models, however, shallow and negative NRM inclinations in sediments deposited during the Brunhes Chron in the Arctic Ocean appear to have a partly diagenetic origin. Rock magnetic and mineralogical studies demonstrate the presence of titanomagnetite and titanomaghemite. Thermal demagnetization of the NRM indicates that shallow and negative inclination components are largely “unblocked” below ?300 °C, consistent with a titanomaghemite remanence carrier. Following earlier studies on the Mendeleev–Alpha Ridge, shallow and negative NRM inclination intervals in cores from the Lomonosov Ridge and Yermak Plateau are attributed to partial self-reversed chemical remanent magnetization (CRM) carried by titanomaghemite formed during seafloor oxidation of host (detrital) titanomagnetite grains. Distortion of paleomagnetic records due to seafloor maghemitization appears to be especially important in the perennially ice covered western (Mendeleev–Alpha Ridge) and central Arctic Ocean (Lomonosov Ridge) and, to a lesser extent, near the ice edge (Yermak Plateau). On the Yermak Plateau, magnetic grain size parameters mimic the global benthic oxygen isotope record back to at least marine isotope stage 6, implying that magnetic grain size is sensitive to glacial–interglacial changes in bottom-current velocity and/or detrital provenance

Dating late Quaternary planktonic foraminifer Neogloboquadrina pachyderma from the Arctic Ocean using amino acid racemization

The long-term rate of racemization for amino acids preserved in planktonic foraminifera was determined by using independently dated sediment cores from the Arctic Ocean. The racemization rates for aspartic acid (Asp) and glutamic acid (Glu) in the common taxon, Neogloboquadrina pachyderma, were calibrated for the last 150 ka using 14C ages and the emerging Quaternary chronostratigraphy of Arctic Ocean sediments. An analysis of errors indicates realistic age uncertainties of about ±12% for Asp and ±17% for Glu. Fifty individual tests are sufficient to analyze multiple subsamples, identify outliers, and derive robust sample mean values. The new age equation can be applied to verify and refine age models for sediment cores elsewhere in the Arctic Ocean, a critical region for understanding the dynamics of global climate change

Response of Iberian Margin sediments to orbital and suborbital forcing over the past 420 ka

Here we report 420 kyr long records of sediment geochemical and color variations from the southwestern Iberian Margin. We synchronized the Iberian Margin sediment record to Antarctic ice cores and speleothem records on millennial time scales and investigated the phase responses relative to orbital forcing of multiple proxy records available from these cores. Iberian Margin sediments contain strong precession power. Sediment “redness” (a* and 570–560 nm) and the ratio of long-chain alcohols to n-alkanes (C26OH/(C26OH + C29)) are highly coherent and in-phase with precession. Redder layers and more oxidizing conditions (low alcohol ratio) occur near precession minima (summer insolation maxima). We suggest these proxies respond rapidly to low-latitude insolation forcing by wind-driven processes (e.g., dust transport, upwelling, precipitation). Most Iberian Margin sediment parameters lag obliquity maxima by 7–8 ka, indicating a consistent linear response to insolation forcing at obliquity frequencies driven mainly by high-latitude processes. Although the lengths of the time series are short (420 ka) for detecting 100 kyr eccentricity cycles, the phase relationships support those obtained by Shackleton []. Antarctic temperature and the Iberian Margin alcohol ratios (C26OH/(C26OH + C29)) lead eccentricity maxima by 6 kyr, with lower ratios (increased oxygenation) occurring at eccentricity maxima. CO2, CH4, and Iberian SST are nearly in phase with eccentricity, and minimum ice volume (as inferred from Pacific δ18Oseawater) lags eccentricity maxima by 10 kyr. The phase relationships derived in this study continue to support a potential role of the Earth's carbon cycle in contributing to the 100 kyr cycle