3 research outputs found
Machine Learning and Energy Minimization Approaches for Crystal Structure Predictions: A Review and New Horizons
Predicting crystal structure has
always been a challenging problem
for physical sciences. Recently, computational methods have been built
to predict crystal structure with success but have been limited in
scope and computational time. In this paper, we review computational
methods such as density functional theory and machine learning methods
used to predict crystal structure. We also explored the breadth versus
accuracy of building a model to predict across any crystal structure
using machine learning. We extracted 24 913 unique chemical
formulas existing between 290 and 310 K from the Pearson Crystal Database.
Of these 24 913 formulas, there exists 10 711 unique
crystal structures referred to as entry prototypes. Common entries
might have hundreds of chemical compositions, while the vast majority
of entry prototypes is represented by fewer than ten unique compositions.
To include all data in our predictions, entry prototypes that lacked
a minimum number of representatives were relabeled as “Other”.
By selecting the minimum numbers to be 150, 100, 70, 40, 20, and 10,
we explored how limiting class sizes affected performance. Using each
minimum number to reorganize the data, we looked at the classification
performance metrics: accuracy, precision, and recall. Accuracy ranged
from 97 ± 2 to 85 ± 2%; average precision ranged from 86
± 2 to 79 ± 2%, while average recall ranged from 73 ±
2 to 54 ± 2% for minimum-class representatives from 150 to 10,
respectively
Solution-Based Carbohydrate Synthesis of Individual Solid, Hollow, and Porous Carbon Nanospheres Using Spray Pyrolysis
A facile and scalable solution-based, spray pyrolysis synthesis technique was used to synthesize individual carbon nanospheres with specific surface area (SSA) up to 1106 m<sup>2</sup>/g using a novel metal-salt catalyzed reaction. The carbon nanosphere diameters were tunable from 10 nm to several micrometers by varying the precursor concentrations. Solid, hollow, and porous carbon nanospheres were achieved by simply varying the ratio of catalyst and carbon source without using any templates. These hollow carbon nanospheres showed adsorption of to 300 mg of dye per gram of carbon, which is more than 15 times higher than that observed for conventional carbon black particles. When evaluated as supercapacitor electrode materials, specific capacitances of up to 112 F/g at a current density of 0.1 A/g were observed, with no capacitance loss after 20 000 cycles
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Stable, Heat-Conducting Phosphor Composites for High-Power Laser Lighting
Solid-state lighting using laser
diodes is an exciting new development that requires new phosphor geometries
to handle the greater light fluxes involved. The greater flux from
the source results in more conversion and therefore more conversion
loss in the phosphor, which generates self-heating, surpassing the
stability of current encapsulation strategies used for light-emitting
diodes, usually based on silicones. Here, we present a rapid method
using spark plasma sintering (SPS) for preparing ceramic phosphor
composites of the canonical yellow-emitting phosphor Ce-doped yttrium
aluminum garnet (Ce:YAG) combined with a chemically compatible and
thermally stable oxide, α-Al<sub>2</sub>O<sub>3</sub>. SPS allows
for compositional modulation, and phase fraction, microstructure,
and luminescent properties of ceramic composites with varying compositions
are studied here in detail. The relationship between density, thermal
conductivity, and temperature rise during laser-driven phosphor conversion
is elucidated, showing that only modest densities are required to
mitigate thermal quenching in phosphor composites. Additionally, the
scattering nature of the ceramic composites makes them ideal candidates
for laser-driven white lighting in reflection mode, where Lambertian
scattering of blue light offers great color uniformity, and a luminous
flux >1000 lm is generated using a single commercial laser diode
coupled to a single phosphor element