Strong interrelationship between anomalous electric-field induced lattice strain along non-polar direction and domain reorientation in pseudorhombohedral piezoelectric ceramic BiScO3-PbTiO3

The lattice strain and domain switching behaviour was investigated as a function of cyclic field and grain orientation for a pseudorhombohedral composition of the high Curie point piezoelectric system xBiScO3 - (1-x)PbTiO3 (x = 0.40) by in-situ electric field diffraction technique with high energy synchrotron x-rays. Along the field direction, the system exhibts five time large strain along 100 as compared to the 111 direction. A one-to-one correspondence between the 200 lattice strain and the 111 domain switching suggests a strong correlation between the two phenomena.Comment: 11 pages, 7 figure

Fluoride toxicity in grape vines : a case study

The onset of visual damage varied with the season. The symptoms consisted of marginal and tip necrosis in the early stages with the necrotic areas gradually expanding between the veins. In severe cases the leaves shed. Old leaves were affected first although foliage of any age was affected in cases of severe fluoride pollution. Plant analysis indicated that damage was associated with concentrations in excess of 20 ppm fluoride

Student Perceptions of Faculty, Staff, and Students Carrying Concealed Weapons on Campus

Reactions to gun violence and potential policies regarding gun control are often reactions to fear with schools being the focal point of gun control dialogue. From elementary schools to college campuses, the concealed carry debate exists. Should we allow staff, faculty, and at the college-level, students to carry concealed guns? Students at a private college in Florida were surveyed in regards to their attitudes towards concealed carry and campus safety. We tested a number of hypotheses related to how much time students spend being exposed to media, student perceptions of safety, and their attitudes toward concealed weapons on campus. Results show low levels of support for armed campus safety and concealed weapons for faculty among our student sample. Students were even less comfortable with other students being armed on campus. In support of previous research, conservative students were more likely to believe the media spends too much time covering gun violence. While our results show mixed support of previous research on concealed weapons our findings are particularly interesting due to our close proximity to two recent mass shootings in Florida

Low temperature dielectric relaxation in ordinary perovskite ferroelectrics: enlightenment from high-energy x-ray diffraction

Ordinary ferroelectrics exhibit a second order phase transition that is characterized by a sharp peak in the dielectric permittivity at a frequency-independent temperature. Furthermore, these materials show a low temperature dielectric relaxation that appears to be a common behavior of perovskite systems. Tetragonal lead zirconate titanate is used here as a model system in order to explore the origin of such an anomaly, since there is no consensus about the physical phenomenon involved in it. Crystallographic and domain structure studies are performed from temperature dependent synchrotron x-ray diffraction measurement. Results indicate that the dielectric relaxation cannot be associated with crystallographic or domain configuration changes. The relaxation process is then parameterized by using the Vogel–Fulcher–Tammann phenomenological equation. Results allow us to hypothesize that the observed phenomenon is due to changes in the dynamic behavior of the ferroelectric domains related to the fluctuation of the local polarization.Postprint (author's final draft

Effect of dusts on tomato production

The phytotoxicity of bauxite, cement flue, mud lake, alumina and kaolin dusts were examined on tomatoes. Mud lake white dust caused severe leaf scorch, affected plant growth and resulted in no harvestable yield. Flue dust applied daily depressed market yield of fruit from 64 t ha to 42 t ha. Flue dust applied at 3.1 t ha had no effect. There was no phytotoxic effect from bauxite, alumina or kaolin

Ergodicity reflected in macroscopic and microscopic field-dependent behavior of BNT-based relaxors

The effect of heterovalent B-site doping on ergodicity of relaxor ferroelectrics is studied using (1 - y)(0.81Bi(1/2)Na(1/2)TiO(3)-0.19Bi(1/2)K(1/2)TiO(3))-yBiZn(1/2)Ti(1/2)O(3) (BNT-BKT-BZT) with y - {0.02;0.03;0.04} as a model system. Both the large- and small-signal parameters are studied as a function of electric field. The crystal structure is assessed by means of neutron diffraction in the initial state and after exposure to a high electric field. In order to measure ferroelastic domain textures, diffraction patterns of the poled samples are collected as a function of sample rotation angle. Piezoresponse force microscopy (PFM) is employed to probe the microstructure for polar regions at a nanoscopic scale. For low electric fields E < 2 kV.mm(-1), large- and small-signal constitutive behavior do not change with composition. At high electric fields, however, drastic differences are observed due to a field-induced phase transition into a long-range ordered state. It is hypothesized that increasing BZT content decreases the degree of non-ergodicity; thus, the formation of long-range order is impeded. It is suggested that frozen and dynamic polar nano regions exist to a different degree, depending on the BZT content. This image is supported by PFM measurements. Moreover, PFM measurements suggest that the relaxation mechanism after removal of the bias field is influenced by surface chargesopen2

Electric-field-induced phase transformation at a lead-free morphotropic phase boundary: Case study in a 93%(Bi0.5Na0.5)TiO3-7% BaTiO3 piezoelectric ceramic

The electric-field-induced strain in 93%(Bi0.5Na0.5)TiO3-7%BaTiO3 polycrystalline ceramic is shown to be the result of an electric-field-induced phase transformation from a pseudocubic to tetragonal symmetry. High-energy x-ray diffraction is used to illustrate the microstructural nature of the transformation. A combination of induced unit cell volumetric changes, domain texture, and anisotropic lattice strains are responsible for the observed macroscopic strain. This strain mechanism is not analogous to the high electric-field-induced strains observed in lead-based morphotropic phase boundary systems. Thus, systems which appear cubic under zero field should not be excluded from the search for lead-free piezoelectric compositions.open1127

Role of Composition and Structure on the Properties of Metal/Multifunctional Ceramic Interfaces

The formation of intermetallic secondary phases, such as Pt3Pb, has been observed experimentally at PbTiO3/Pt and Pb(Zr,Ti)O3/Pt, or PZT/Pt, interfaces. Density functional theory calculations are used here to calculate the work of adhesion of these interfacial systems with and without the secondary intermetallic phase. The charge density maps of the interfaces reveal the electronic interactions at the interface and the impact of the secondary phase. In addition, Bader charge analysis provides a quantitative assessment of electron transfer from the perovskites to the Pt. Analysis of the band diagrams indicates an increase of the potential barrier associated with electron transfer due to the formation of the Pt3Pb at PZT/Pt interfaces