Evidence for an NO-rebound, mechanism for production of N2O from nitrite by the copper-containing nitrite reductase from Achromobacter cycloclastes

AbstractReduction of NO−2 by the Cu-containing nitrite reductase from Achromobacter cycloclastes produces NO as the primary product initially, but as NO accumulates, NO production levels-off and N2O production becomes significant. Reaction of the enzyme with NO−2 in the presence of NO increases the amount of N2O product significantly, while trapping the NO product as nitrosylhemoglobin or rapid, removal of NO by sparging results in no detectable N2O production. Reaction of the enzyme with 15NO−2 in the presence of 14NO results in rapid formation of the mixed isotope product (14N, 15N)O in ca. 45% yield. In contrast, the presence or absence of NO has no effect on N2O production by a prototypical heme cd1-containing nitrite reductase. These results are consistent with formation of a labile Cu+−NO+ species in the copper enzyme, which normally decomposes to NO. Production of N2O requires that the released NO must rebind to the enzyme to combine with a second NO−2 or a species derived therefrom

Displacement/Length Scaling Relationships for Normal Faults; a Review, Critique, and Revised Compilation

The relationship between normal fault displacement (D) and length (L) varies due to numerous factors, including fault size, maturity, basin tectonic history, and host rock lithology. Understanding how fault D and L relate is useful, given related scaling laws are often used to help refine interpretations of often incomplete, subsurface datasets, which has implications for hydrocarbon and low-carbon energy applications. Here we provide a review of D/L scaling laws for normal faults, discuss factors that could influence these relationships, including both geological factors and errors in measurement, and provide a critique of previously published D/L databases. We then present our newly assembled database of 4059 normal faults from 66 sources that include explicit information on: 1) fault length and displacement, 2) host rock lithology, 3) host basin tectonic history, and 4) maturity, as well as fault D and L through time when these data are available. We find an overall scaling law of D = 0.3L0.92, which is similar to previously published scaling equations and that varies in response to the aforementioned geological factors. Our data show that small faults (<1 m length) tend to be over-displaced compared to larger faults, active faults tend to be over-displaced compared to inactive faults, and faults with stiffer host rock lithologies, like igneous and carbonate rocks, tend to be under-displaced with respect to faults within softer, more compliant host rocks, like clastic sedimentary rocks. Our dynamic D/L through time data show that faults follow the hybrid fault growth model, i.e., they initially lengthen, during which time they will appear under-displaced, before accumulating displacement. To the best of our knowledge, this is the first comprehensive, integrated, critical study of D/L scaling laws for normal faults and the factors influencing their growth. These revised relationships can now be utilized for predicting fault length or displacement when only one variable is available and provide the basis for general understanding D/L scaling laws in the context of normal fault growth. This underpinning database is open-access and is available for analysis and manipulation by the broader structural geology community.publishedVersio

The 2dF Galaxy Redshift Survey: the power spectrum and the matter content of the Universe

The 2dF Galaxy Redshift Survey has now measured in excess of 160000 galaxy redshifts. This paper presents the power spectrum of the galaxy distribution, calculated using a direct Fourier transform based technique. We argue that, within the k-space region 0.02<~k<~0.15hMpc-1, the shape of this spectrum should be close to that of the linear density perturbations convolved with the window function of the survey. This window function and its convolving effect on the power spectrum estimate are analysed in detail. By convolving model spectra, we are able to fit the power-spectrum data and provide a measure of the matter content of the Universe. Our results show that models containing baryon oscillations are mildly preferred over featureless power spectra. Analysis of the data yields 68 per cent confidence limits on the total matter density times the Hubble parameter Ωmh=0.20+/-0.03, and the baryon fraction Ωb/Ωm=0.15+/-0.07, assuming scale-invariant primordial fluctuations

What’s sex got to do with it? A family-based investigation of growing up heterosexual during the twentieth century

This paper explores findings from a cross-generational study of the making of heterosexual relationships in East Yorkshire, which has interviewed women and men within extended families. Using a feminist perspective, it examines the relationship between heterosexuality and adulthood, focussing on sexual attraction, courtship, first kisses, first love and first sex, as mediated within family relationships, and at different historical moments. In this way, the contemporary experiences of young people growing up are compared and contrasted with those of mid-lifers and older adults who formed heterosexual relationships within the context of the changing social and sexual mores of the 1960s/1970s, and the upheavals of World War Two

Cosmic distance-duality as probe of exotic physics and acceleration

In cosmology, distances based on standard candles (e.g. supernovae) and standard rulers (e.g. baryon oscillations) agree as long as three conditions are met: (1) photon number is conserved, (2) gravity is described by a metric theory with (3) photons travelling on unique null geodesics. This is the content of distance-duality (the reciprocity relation) which can be violated by exotic physics. Here we analyse the implications of the latest cosmological data sets for distance-duality. While broadly in agreement and confirming acceleration we find a 2-sigma violation caused by excess brightening of SN-Ia at z > 0.5, perhaps due to lensing magnification bias. This brightening has been interpreted as evidence for a late-time transition in the dark energy but because it is not seen in the d_A data we argue against such an interpretation. Our results do, however, rule out significant SN-Ia evolution and extinction: the "replenishing" grey-dust model with no cosmic acceleration is excluded at more than 4-sigma despite this being the best-fit to SN-Ia data alone, thereby illustrating the power of distance-duality even with current data sets.Comment: 6 pages, 4 colour figures. Version accepted as a Rapid Communication in PR

A measurement of the cosmological mass density from clustering in the 2dF Galaxy Redshift Survey

The large-scale structure in the distribution of galaxies is thought to arise from the gravitational instability of small fluctuations in the initial density field of the Universe. A key test of this hypothesis is that forming superclusters of galaxies should generate a systematic infall of other galaxies. This would be evident in the pattern of recessional velocities, causing an anisotropy in the inferred spatial clustering of galaxies. Here we report a precise measurement of this clustering, using the redshifts of more than 141,000 galaxies from the two-degree-field (2dF) galaxy redshift survey. We determine the parameter β = Ω0.6/b = 0.43 +/- 0.07, where Ω is the total mass-density parameter of the Universe and b is a measure of the `bias' of the luminous galaxies in the survey. (Bias is the difference between the clustering of visible galaxies and of the total mass, most of which is dark.) Combined with the anisotropy of the cosmic microwave background, our results favour a low-density Universe with Ω ~ 0.3

The 2dF Galaxy Redshift Survey: a targeted study of catalogued clusters of galaxies

We have carried out a study of known clusters within the 2dF Galaxy Redshift Survey (2dFGRS) observed areas and have identified 431 Abell, 173APM and 343 EDCC clusters. Precise redshifts, velocity dispersions and new centroids have been measured for the majority of these objects, and this information is used to study the completeness of these catalogues, the level of contamination from foreground and background structures along the cluster's line of sight, the space density of the clusters as a function of redshift, and their velocity dispersion distributions. We find that the Abell and EDCC catalogues are contaminated at the level of about 10 per cent, whereas the APM catalogue suffers only 5 per cent contamination. If we use the original catalogue centroids, the level of contamination rises to approximately 15 per cent for the Abell and EDCC catalogues, showing that the presence of foreground and background groups may alter the richness of clusters in these catalogues. There is a deficiency of clusters at z~0.05 that may correspond to a large underdensity in the Southern hemisphere. From the cumulative distribution of velocity dispersions for these clusters, we derive a space density of σ>1000kms-1 clusters of 3.6×10-6h3Mpc-3. This result is used to constrain models for structure formation; our data favour low-density cosmologies, subject to the usual assumptions concerning the shape and normalization of the power spectrum

The 2dF galaxy redshift survey: near-infrared galaxy luminosity functions

We combine the Two Micron All Sky Survey (2MASS) Extended Source Catalogue and the 2dF Galaxy Redshift Survey to produce an infrared selected galaxy catalogue with 17173 measured redshifts. We use this extensive data set to estimate the galaxy luminosity functions in the J- and KS-bands. The luminosity functions are fairly well fitted by Schechter functions with parameters MJ*-5logh=-22.36+/-0.02, αJ=-0.93+/-0.04, ΦJ*=0.0104+/-0.0016h3Mpc-3 in the J-band and MKS*-5logh=-23.44+/-0.03, αKS=-0.96+/-0.05, ΦKS*=0.0108+/-0.0016h3Mpc-3 in the KS-band (2MASS Kron magnitudes). These parameters are derived assuming a cosmological model with Ω0=0.3 and Λ0=0.7. With data sets of this size, systematic rather than random errors are the dominant source of uncertainty in the determination of the luminosity function. We carry out a careful investigation of possible systematic effects in our data. The surface brightness distribution of the sample shows no evidence that significant numbers of low surface brightness or compact galaxies are missed by the survey. We estimate the present-day distributions of bJ-KS and J-KS colours as a function of the absolute magnitude and use models of the galaxy stellar populations, constrained by the observed optical and infrared colours, to infer the galaxy stellar mass function. Integrated over all galaxy masses, this yields a total mass fraction in stars (in units of the critical mass density) of Ωstarsh=(1.6+/-0.24)×10-3 for a Kennicutt initial mass function (IMF) and Ωstarsh=(2.9+/-0.43)×10-3 for a Salpeter IMF. These values are consistent with those inferred from observational estimates of the total star formation history of the Universe provided that dust extinction corrections are modest

Expanded Vandermonde powers and sum rules for the two-dimensional one-component plasma

The two-dimensional one-component plasma (2dOCP) is a system of $N$ mobile particles of the same charge $q$ on a surface with a neutralising background. The Boltzmann factor of the 2dOCP at temperature $T$ can be expressed as a Vandermonde determinant to the power $\Gamma=q^{2}/(k_B T)$. Recent advances in the theory of symmetric and anti-symmetric Jack polymonials provide an efficient way to expand this power of the Vandermonde in their monomial basis, allowing the computation of several thermodynamic and structural properties of the 2dOCP for $N$ values up to 14 and $\Gamma$ equal to 4, 6 and 8. In this work, we explore two applications of this formalism to study the moments of the pair correlation function of the 2dOCP on a sphere, and the distribution of radial linear statistics of the 2dOCP in the plane

Neoproterozoic to Cambrian granitoids of northern Mozambique and Dronning Maud Land Antarctica.

第2回極域科学シンポジウム/第31回極域地学シンポジウム 11月17日（木） 国立極地研究所　2階大会議