Inorganic nitrogen and glucose additions alter the short-term formation efficiency of mineral associated organic matter carbon

Carbon within mineral associated organic matter (MAOM) is an important persistent form of soil organic carbon (SOC). However, processes driving the retention of new labile C in MAOM are not fully understood. We investigated the effects of glucose and ammonium nitrate (AN) addition on the short-term (72 h) retention of applied 13C-glucose within MAOM. We found an interactive effect of AN addition with the glucose addition rate. Higher rates of glucose addition resulted in proportionally less glucose-C retained, indicating lower MAOM-C formation efficiency. Addition of AN only altered the proportional retention of glucose where glucose was applied at the lowest rate. In this instance glucose-13C recovery increased with AN addition. However, after 72 h there was no treatment difference in total MAOM-C, indicating that any changes in formation efficiency as a result of AN and glucose additions, did not result in differences in total MAOM-C in the short-term. Whether and how this affects the medium and longer-term dynamics of MAOM-C requires further investigation

Information properties of boundary line models for N2O emissions from agricultural soils

Boundary line models for N2O emissions from agricultural soils provide a means of estimating emissions within defined ranges. Boundary line models partition a two-dimensional region of parameter space into sub-regions by means of thresholds based on relationships between N2O emissions and explanatory variables, typically using soil data available from laboratory or field studies. Such models are intermediate in complexity between the use of IPCC emission factors and complex process-based models. Model calibration involves characterizing the extent to which observed data are correctly forecast. Writing the numerical results from graphical two-threshold boundary line models as 3×3 prediction-realization tables facilitates calculation of expected mutual information, a measure of the amount of information about the observations contained in the forecasts. Whereas mutual information characterizes the performance of a forecaster averaged over all forecast categories, specific information and relative entropy both characterize aspects of the amount of information contained in particular forecasts. We calculate and interpret these information quantities for experimental N2O emissions data

Managing fertiliser nitrogen to reduce nitrous oxide emissions and emission intensities from a cultivated Cambisol in Scotland

Emissions of nitrous oxide (N2O) were measured from an arable site in south east Scotland for twelve months during 2011–2012 using an intensive sampling strategy. This fully replicated and blocked field experiment aimed to provide accurate measurements of N2O emissions from one of the UK's principle geoclimatic zones supporting agricultural production and to produce robust N2O emission factors (EFs). Calculated EFs were compared to the IPCC's default Tier 1 EF of 1.25%, and the new value of 1%, to assess their suitability for use in locations throughout the UK. Emissions from ten treatments fertilised with either ammonium nitrate or urea at rates of 0 kgNha−1 to 200 kgN ha−1, and sownwith spring barley,were measured using the static closed chamber technique. Potential N2O mitigation options were investigated; these included the use of a nitrification inhibitor (NI), split fertiliser applications and variations in the formand quantity of fertiliser applied. Crop yieldswere measured to enable calculation of N2O emission intensities for each treatment; this is an important factor to consider when assessing N2O mitigation options due to the need to maintain crop yields. Cumulative N2O emissions varied between 1.32 kg N2O-N ha−1 and 3.82 kg N2O-N ha−1 with a mean 42% decrease in emissions associated with the use of the NI. Increases in crop yield were associatedwith increases inN fertiliser application, and the amendment of treatmentswith a NI and the use of a split fertiliser application significantly decreased crop yields by approximately 10% and 5% respectively. Annual EFs ranged between −0.28% to 1.35%. Emission intensities decreasedwith increasing fertiliser application at low N application rates, and the optimumfertiliser application rate to obtain minimum emissions but maximum crop yield was 160 kg N ha−1. © 2014 Published by Elsevier B.V

Towards country-specific nitrous oxide emission factors for manures applied to arable and grassland soils in the UK

Nitrous oxide (N2O) emission factors (EFs) were calculated from measurements of emissions from livestock manures applied to UK arable crops and grassland as part of a wider research programme to reduce uncertainty in the UK national agricultural N2O inventory and to enhance regional inventory reporting through increased understanding of processes and factors controlling emissions. Field studies were undertaken between 2011 and 2013 at 3 arable and 3 grassland sites in the UK. Nitrous oxide emissions were measured following the autumn and spring application of different manures (pig slurry, cattle slurry, cattle farmyard manure (FYM), pig FYM, poultry layer manure, and broiler litter) at typical rates, using representative manure application and soil incorporation methods. In addition, ammonia emissions and nitrate leaching losses (1 site on a light sandy soil) were measured to calculate indirect N2O losses. IPCC comparable, direct N2O EFs ranged from −0.05 to 2.30% of total nitrogen applied, with the variability driven by a range of factors including differences in manure composition, application method, incorporation and climatic conditions. When data from the autumn applications were pooled, the mean N2O EF from poultry manure (1.52%) was found to be greater (P < 0.001) than from FYM (0.37%) and slurry (0.72%), with no difference found (P = 0.784) in the EF for bandspread compared with surface broadcast slurry application, and no effect (P = 0.328) of the nitrification inhibitor, Dicyandiamide (DCD). For the spring applications, the mean N2O EF for bandspread slurry (0.56%) was greater (P = 0.028) than from surface broadcast slurry (0.31%), but there were no differences (P = 0.212) in the mean N2O EFs from poultry manure (0.52%), slurry (0.44%), and FYM (0.22%). The study did confirm, however, that DCD reduced N2O emissions from slurries applied in the spring by 45%. EF data from this project have been used in the derivation of robust Tier 2 country specific EFs for inclusion in the UK national agriculture greenhouse gas inventory