89 research outputs found

    Ballistic nanofriction

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    Sliding parts in nanosystems such as Nano ElectroMechanical Systems (NEMS) and nanomotors, increasingly involve large speeds, and rotations as well as translations of the moving surfaces; yet, the physics of high speed nanoscale friction is so far unexplored. Here, by simulating the motion of drifting and of kicked Au clusters on graphite - a workhorse system of experimental relevance -- we demonstrate and characterize a novel "ballistic" friction regime at high speed, separate from drift at low speed. The temperature dependence of the cluster slip distance and time, measuring friction, is opposite in these two regimes, consistent with theory. Crucial to both regimes is the interplay of rotations and translations, shown to be correlated in slow drift but anticorrelated in fast sliding. Despite these differences, we find the velocity dependence of ballistic friction to be, like drift, viscous

    DNA nanomapping using CRISPR-Cas9 as a programmable nanoparticle

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    Physical mapping of DNA can be used to detect structural variants and for whole-genome haplotype assembly. Here, the authors use CRISPR-Cas9 and high-speed atomic force microscopy to ‘nanomap’ single molecules of DNA

    Metallic, magnetic and molecular nanocontacts

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    Scanning tunnelling microscopy and break-junction experiments realize metallic and molecular nanocontacts that act as ideal one-dimensional channels between macroscopic electrodes. Emergent nanoscale phenomena typical of these systems encompass structural, mechanical, electronic, transport, and magnetic properties. This Review focuses on the theoretical explanation of some of these properties obtained with the help of first-principles methods. By tracing parallel theoretical and experimental developments from the discovery of nanowire formation and conductance quantization in gold nanowires to recent observations of emergent magnetism and Kondo correlations, we exemplify the main concepts and ingredients needed to bring together ab initio calculations and physical observations. It can be anticipated that diode, sensor, spin-valve and spin-filter functionalities relevant for spintronics and molecular electronics applications will benefit from the physical understanding thus obtained

    Humanism from a chemist

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    Probe Microscopy

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    CORE-LEVEL ELECTRON ELECTRON COINCIDENCE SPECTROSCOPY

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    Two electron‐spectrometer systems designed for electron–electron coincidence spectroscopy are described. One, based on two hemispherical analyzers and x‐ray excitation, is especially suited for Auger‐photoelectron coincidence spectroscopy (APECS) of solids and surfaces. The other, using a cylindrical mirror analyzer, a hemispherical analyzer, and electron‐beam excitation is designed for near‐dipole (e, 2e) spectroscopy of gaseous samples. Typical results obtained with these instruments are presented
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