Soot volume fraction measurements over laminar pool flames of biofuels, diesel and blends

© 2018 The Combustion Institute. Biodiesel and blends with petroleum diesel have shown their potential as renewable alternative fuels for engines, with additional benefits of low particulate matter and low sulfate emissions. In this paper we measure the soot volume fraction produced by three different methyl esters processed biodiesels (extracted from palm (PME), soy (SME) and coconut (CME)), and their blends with petroleum diesel, in a series of co-flow stabilized laminar pool flames, using laser induced-incandescence (LII) and laser extinction optical methods. The soot volume fraction measurement results show that all neat biodiesels produce only up to 33% of the total soot volume compared to pure diesel, and that the total soot volume correlates directly with the degree of unsaturation of the biodiesels. Blending leads to approximately linear behaviour of total soot volume, with a shift in slope with smaller sensitivity towards neat diesel

Quantification of carbon particulates produced under open liquid pool and prevaporised flame conditions: Waste cooking oil biodiesel and diesel blends

The soot volume fraction (SVF) of waste cooking oil (WCO) biodiesel and blends was quantified and compared under the same total carbon flow rate via two experimental setups, namely prevaporised diffusion jet flames and pool flames using extinction calibrated laser induced-incandescence (LII). The spatial SVF distribution shows that for diesel-rich fuels, soot formation peaks near the flame and is convected downstream, whereas biodiesel flames show a more evenly distributed SVF at the flame center region. An increase in biodiesel fraction in diesel results in a reduced propensity for soot, as evident in both pool and vapour flames. Comparison of the radial profiles of SVF along the centerline shows broader SVF profiles for pool flames, reflecting the longer residence times for soot diffusion and growth compared to vapour flames, which reflected the lower mass flux for the pool burner. The total soot produced from pool flames was found to be higher than vapour flame by a factor of two for the same fuel mass consumption rate. WCO biodiesel exhibited the lowest total SVF value regardless of flame type owing to the combined effects of lack of aromatic compounds and fuel chemistry. The soot primary particle sizes produced by WCO biodiesel show lower mean diameter values by a factor of approximately 1.5 compared to diesel-produced soot. The pool flames produced carbon particulates of larger mean diameter by around 22% and 8% for diesel and WCO biodiesel, respectively, relative to the counterpart vapour flames, as a result of extended soot surface growth period.Royal Society-Newton Advanced Fellow (NA160115) Academy of Sciences Malaysia (ASM) Malaysian Industry-Government Group for High Technology (MIGHT

Biodiesel sustainability: The global impact of potential biodiesel production on the energy–water–food (EWF) nexus

A data-driven model is used to analyse the global effects of biodiesel on the energy–water–food (EWF) nexus, and to understand the complex environmental correlation. Several criteria to measure the sustainability of biodiesel and four main limiting factors for biodiesel production are discussed in this paper. The limiting factors includes water stress, food stress, feedstock quantity and crude oil price. The 155-country model covers crude oil prices ranging from USD10/bbl to USD160/bbl, biodiesel refinery costs ranging from -USD0.30/L to USD0.30/L and 45 multi-generation biodiesel feedstocks. The model is capable of ascertaining changes arising from biodiesel adoption in terms of light-duty diesel engine emissions (NO, CO, UHC and smoke opacity), water stress index (WSI), dietary energy supply (DES), Herfindahl–Hirschman index (HHI) and short-term energy security. With the addition of potential biodiesel production, the renewable energy sector of global primary energy profile can increase by 0.43%, with maximum increment up to 10.97% for Malaysia. At current crude oil price of USD75/bbl and refinery cost of USD0.1/L, only Benin, Ireland and Togo can produce biodiesel profitably. The model also shows that water requirement varies non-linearly with multi-feedstock biodiesel production as blending ratio increases. Out of the 155 countries, biodiesel production is limited by feedstock quantity for 82 countries, 47 are limited by crude oil price, 20 by water stress and 6 by food stress. The results provide insights for governments to set up environmental policy guidelines, in implementing biodiesel technology as a cleaner alternative to diesel

Experimental and numerical study on soot formation in laminar diffusion flames of biodiesels and methyl esters

Biodiesel and blends with petroleum diesel are promising renewable alternative fuels for engines. In the present study, the soot concentration generated from four biodiesels, two pure methyl esters, and their blends with petroleum diesel are measured in a series of fully pre-vapourised co-flow diffusion flames. The experimental measurements are conducted using planar laser induced-incandescence (LII) and laser extinction optical methods. The results show that the maximum local soot volume fractions of neat biodiesels are 24.4% - 41.2% of pure diesel, whereas the mean soot volume fraction of neat biodiesel cases was measured as 11.3% - 21.3% of pure diesel. The addition of biodiesel to diesel not only reduces the number of inception particles, but also inhibits their surface growth. The discretised population balance modelling of a complete set of soot processes is employed to compute the 2D soot volume fraction and size distribution across the tested flames. The results show that the model also demonstrates a reduction of both soot volume fraction and primary particle size by adding biodiesel fuels. However, it is not possible to clearly determine which factors are responsible for the reduction from the comparison alone. Moreover, analysis of the discrepancies between numerical and experimental results for diesel and low-blending cases offers an insight for the refinement of soot formation modelling of combustion with large-molecule fuels.Bo Tian is supported by the fellowship provided by ZEPI. C. T. Chong is supported by the Newton Advanced Fellowship of the Royal Society (NA160115). Anxiong Liu gratefully acknowledges the financial support of the Chinese Scholarship Council (CSC) and the EPSRC grant No. EP/S012559/1

An Exercise in Reverse Engineering for Safety-Critical Systems: An Experience for the Classroom

Since the Y2K crisis, reverse engineering has become a major area of work in industrial software application development, but lacks emphasis in US academia. This issue is exemplified by the high demand for software systems in new and expanding software application areas, which has resulted in systems being implemented before the requirements and design phases have been completed. Towards the maintenance of such systems, it is necessary to conducted reverse engineering for the derivation of software documentation for requirements and high-level and low-level design. When this scenario exists in the domain of safety-critical system, particularly in the aviation industry, reverse engineering takes on greater value because such software systems have to undergo development regulations and certification restrictions. This work reports on the pedagogical revelations gained from conducting reverse engineering on a software system that was developed and deployed for use in managing the assignment of commercial aircrafts to airport terminal gates. The software system incorporated genetic algorithms solutions and was implemented on a high-speed multi-processor system. The reverse engineering methodology applied was based on the RTCA DO-178C Software Considerations in Airborne Systems and Equipment Certification specification for onboard avionic software systems

Modelling the nucleon wave function from soft and hard processes

Current light-cone wave functions for the nucleon are unsatisfactory since they are in conflict with the data of the nucleon's Dirac form factor at large momentum transfer. Therefore, we attempt a determination of a new wave function respecting theoretical ideas on its parameterization and satisfying the following constraints: It should provide a soft Feynman contribution to the proton's form factor in agreement with data; it should be consistent with current parameterizations of the valence quark distribution functions and lastly it should provide an acceptable value for the \jp \to N \bar N decay width. The latter process is calculated within the modified perturbative approach to hard exclusive reactions. A simultaneous fit to the three sets of data leads to a wave function whose $x$-dependent part, the distribution amplitude, shows the same type of asymmetry as those distribution amplitudes constrained by QCD sum rules. The asymmetry is however much more moderate as in those amplitudes. Our distribution amplitude resembles the asymptotic one in shape but the position of the maximum is somewhat shifted.Comment: 32 pages RevTex + PS-file with 5 figures in uu-encoded, compressed fil

Early Clinical and Subclinical Visual Evoked Potential and Humphrey's Visual Field Defects in Cryptococcal Meningitis.

Cryptococcal induced visual loss is a devastating complication in survivors of cryptococcal meningitis (CM). Early detection is paramount in prevention and treatment. Subclinical optic nerve dysfunction in CM has not hitherto been investigated by electrophysiological means. We undertook a prospective study on 90 HIV sero-positive patients with culture confirmed CM. Seventy-four patients underwent visual evoked potential (VEP) testing and 47 patients underwent Humphrey's visual field (HVF) testing. Decreased best corrected visual acuity (BCVA) was detected in 46.5% of patients. VEP was abnormal in 51/74 (68.9%) right eyes and 50/74 (67.6%) left eyes. VEP P100 latency was the main abnormality with mean latency values of 118.9 (±16.5) ms and 119.8 (±15.7) ms for the right and left eyes respectively, mildly prolonged when compared to our laboratory references of 104 (±10) ms (p<0.001). Subclinical VEP abnormality was detected in 56.5% of normal eyes and constituted mostly latency abnormality. VEP amplitude was also significantly reduced in this cohort but minimally so in the visually unimpaired. HVF was abnormal in 36/47 (76.6%) right eyes and 32/45 (71.1%) left eyes. The predominant field defect was peripheral constriction with an enlarged blind spot suggesting the greater impact by raised intracranial pressure over that of optic neuritis. Whether this was due to papilloedema or a compartment syndrome is open to further investigation. Subclinical HVF abnormalities were minimal and therefore a poor screening test for early optic nerve dysfunction. However, early optic nerve dysfunction can be detected by testing of VEP P100 latency, which may precede the onset of visual loss in CM

Thermal Assisted Oxygen Annealing for High Efficiency Planar CH3NH3PbI3 Perovskite Solar Cells

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