862 research outputs found
Thermogravimetric and distillation studies on mercury, antimony and arsenic sulfides
Thermogravimetric studies were made on naturally occurring sulfides of mercury,
antimony and arsenic to determine activation energies and Arrhenius rates of reaction
in vacuum and in atmospheres of air and nitrogen. Of the three sulfides only antimony
showed an appreciable change in rate of reaction for the different test conditions.
Distillation results on three flotation concentrates from Alaska mining operations showed that cinnabar (mercury sulfide) could be distilled in a closed system, with over 99 percent recovery of the mercury as metal when the sulfur was reacted with iron. Over 98 percent mercury recovery was obtained from a cinnabar-stibnite (antimony sulfide) concentrate, with less than 1 percent of the antimony distilled from the furnace charge. Cinnabarrealgar-orpiment (arsenic sulfides) could not be separated by distillation and large quantities of soot (condenser residue) formed with the metallic mercury in the condenser
Electronic Structure of Carbon Nanotube Ropes
We present a tight binding theory to analyze the motion of electrons between
carbon nanotubes bundled into a carbon nanotube rope. The theory is developed
starting from a description of the propagating Bloch waves on ideal tubes, and
the effects of intertube motion are treated perturbatively in this basis.
Expressions for the interwall tunneling amplitudes between states on
neighboring tubes are derived which show the dependence on chiral angles and
intratube crystal momenta. We find that conservation of crystal momentum along
the tube direction suppresses interwall coherence in a carbon nanorope
containing tubes with random chiralities. Numerical calculations are presented
which indicate that electronic states in a rope are localized in the transverse
direction with a coherence length corresponding to a tube diameter.Comment: 15 pages, 10 eps figure
Surface tension of the isotropic-nematic interface
We present the first calculations of the pressure tensor profile in the
vicinity of the planar interface between isotropic liquid and nematic liquid
crystal, using Onsager's density functional theory and computer simulation.
When the liquid crystal director is aligned parallel to the interface, the
situation of lowest free energy, there is a large tension on the nematic side
of the interface and a small compressive region on the isotropic side. By
contrast, for perpendicular alignment, the tension is on the isotropic side.
There is excellent agreement between theory and simulation both in the forms of
the pressure tensor profiles, and the values of the surface tension.Comment: Minor changes; to appear in Phys. Rev.
Observation of the Smectic C -- Smectic I Critical Point
We report the first observation of the smectic C--smectic I (C--I) critical
point by Xray diffraction studies on a binary system. This is in confirmity
with the theoretical idea of Nelson and Halperin that coupling to the molecular
tilt should induce hexatic order even in the C phase and as such both C and I
(a tilted hexatic phase) should have the same symmetry. The results provide
evidence in support of the recent theory of Defontaines and Prost proposing a
new universality class for critical points in layered systems.Comment: 9 pages Latex and 5 postscript figures available from
[email protected] on request, Phys.Rev.Lett. (in press
Phase transitions in geometrothermodynamics
Using the formalism of geometrothermodynamics, we investigate the geometric
properties of the equilibrium manifold for diverse thermodynamic systems.
Starting from Legendre invariant metrics of the phase manifold, we derive
thermodynamic metrics for the equilibrium manifold whose curvature becomes
singular at those points where phase transitions of first and second order
occur. We conclude that the thermodynamic curvature of the equilibrium
manifold, as defined in geometrothermodynamics, can be used as a measure of
thermodynamic interaction in diverse systems with two and three thermodynamic
degrees of freedom
Spin Susceptibility and Superexchange Interaction in the Antiferromagnet CuO
Evidence for the quasi one-dimensional (1D) antiferromagnetism of CuO is
presented in a framework of Heisenberg model. We have obtained an experimental
absolute value of the paramagnetic spin susceptibility of CuO by subtracting
the orbital susceptibility separately from the total susceptibility through the
Cu NMR shift measurement, and compared directly with the theoretical
predictions. The result is best described by a 1D antiferromagnetic
Heisenberg (AFH) model, supporting the speculation invoked by earlier authors.
We also present a semi-quantitative reason why CuO, seemingly of 3D structure,
is unexpectedly a quasi 1D antiferromagnet.Comment: 7 pages including 4 tables and 9 figure
Bianchi Type I Cosmology in Generalized Saez-Ballester Theory via Noether Gauge Symmetry
In this paper, we investigate the generalized Saez-Ballester scalar-tensor
theory of gravity via Noether gauge symmetry (NGS) in the background of Bianchi
type I cosmological spacetime. We start with the Lagrangian of our model and
calculate its gauge symmetries and corresponding invariant quantities. We
obtain the potential function for the scalar field in the exponential form. For
all the symmetries obtained, we determine the gauge functions corresponding to
each gauge symmmetry which include constant and dynamic gauge. We discuss
cosmological implications of our model and show that it is compatible with the
observational data.Comment: 13 pages, 2 figures, accepted for publication in 'European Physical
Journal C
Fluorescent carbon dioxide indicators
Over the last decade, fluorescence has become the dominant tool in biotechnology and medical imaging. These exciting advances have been underpinned by the advances in time-resolved techniques and instrumentation, probe design, chemical / biochemical sensing, coupled with our furthered knowledge in biology. Complementary volumes 9 and 10, Advanced Concepts of Fluorescence Sensing: Small Molecule Sensing and Advanced Concepts of Fluorescence Sensing: Macromolecular Sensing, aim to summarize the current state of the art in fluorescent sensing. For this reason, Drs. Geddes and Lakowicz have invited chapters, encompassing a broad range of fluorescence sensing techniques. Some chapters deal with small molecule sensors, such as for anions, cations, and CO2, while others summarize recent advances in protein-based and macromolecular sensors. The Editors have, however, not included DNA or RNA based sensing in this volume, as this were reviewed in Volume 7 and is to be the subject of a more detailed volume in the near future
Using Carbon Isotope Discrimination to Assess Genotypic Differences in Drought Resistance of Parental Lines of Common Bean
Accurate assessment of crop water uptake (WU) and water use efficiency (WUE) is not easy under field conditions. Carbon isotope discrimination (Δ13C) has been used as a surrogate of WUE to examine crop yield responses to drought and its relationship with WU and WUE. A 2-yr study was conducted (i) to characterize genotypic variation in Δ13C, grain yield, and other physiological parameters in common bean (Phaseolus vulgaris L.) parental lines, and (ii) to examine the relationships between grain Δ13C, shoot Δ13C, and grain yield under well-watered and terminal drought stress conditions. All measured plant traits were strongly influenced by water availability, and genotypic differences in grain yield, shoot Δ13C, and grain Δ13C were found in both watered and terminal drought stress environments. The parental lines were classified into two drought adaptation groups, drought resistant and drought sensitive, based on a yield drought index. High yields under drought conditions were related to (i) greater water uptake, as indicated by high Δ13C in genotypes previously shown to have deeper roots (e.g., SEA 5 and BAT 477), and (ii) increased WUE, denoted by lower Δ13C and greater pod harvest index (PHI) (e.g., SER 16). Coupling of Δ13C measurements with measured yield and yield components analyses, such as PHI, provided an avenue to distinguish different physiological traits among drought resistant genotypes underlying adaptation to water deficit stres
Bubble Entrainment, Spray and Splashing at Hydraulic Jumps
The sudden transition from a high-velocity, supercritical open channel flow into a slow-moving sub-critical flow is a hydraulic jump. Such a flow is characterised by a sudden rise of the free-surface, with some strong energy dissipation and air entrainment, waves and spray. New two-phase flow measurements were performed in the developing flow region using a large-size facility operating at large Reynolds numbers. The experimental results demonstrated the complexity of the flow with a developing mixing layer in which entrained bubbles are advected in a high shear stress flow. The relationship between bubble count rates and void fractions was non-unique in the shear zone, supporting earlier observations of some form of double diffusion process between momentum and air bubbles. In the upper region, the flow consisted primarily of water drops and packets surrounded by air. Visually significant pray and splashing were significant above the jump roller. The present study is the first comprehensive study detailing the two-phase flow properties of both the bubbly and spray regions of hydraulic jumps, a first step towards understanding the interactions between bubble entrainment and droplet ejection processes
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