Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)(2)MoB16H15C2Ph2](-) anion

Fusion of nine-vertex [1-Ph-nido-1-CB8H11] with [Mo(CH3CN)3(CO)3] in the presence of tetramethylnaphthalenediamine gives the nineteen-vertex macropolyhedral metallaborane anion [(CO)2MoB16H15C2Ph]− with a molybdenum(VI) twelve-atom coordination sphere

Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)(4)(O-2)Pt2B10H10]

[(PMe2Ph)(4)Pt2B10H10] 1 reversibly takes up atmospheric dioxygen to give the fluxional dioxygen-dimetallaborane complex [(PMe2Ph)(4)(O-2)Pt2B10H10] 2, which has Pt-Pt 2.7143(3), Pt-O 2.141(4) and 2.151(4) and O-O 1.434(6) Angstrom

Causal Entropy Bound for Non-Singular Cosmologies

The conditions for validity of the Causal Entropy Bound (CEB) are verified in the context of non-singular cosmologies with classical sources. It is shown that they are the same conditions that were previously found to guarantee validity of the CEB: the energy density of each dynamical component of the cosmic fluid needs to be sub-Planckian and not too negative, and its equation of state needs to be causal. In the examples we consider, the CEB is able to discriminate cosmologies which suffer from potential physical problems more reliably than the energy conditions appearing in singularity theorems.Comment: 16 pages, no figures, acknowledgments adde

Black hole gas in the early universe

We consider the early universe at temperatures close to the fundamental scale of gravity (M_D << M_Planck) in models with extra dimensions. At such temperatures a small fraction of particles will experience transplanckian collisions that may result in microscopic black holes (BHs). BHs colder than the environment will gain mass, and as they grow their temperature drops further. We study the dynamics of a system (a black hole gas) defined by radiation at a given temperature coupled to a distribution of BHs of different mass. Our analysis includes the production of BHs in photon-photon collisions, BH evaporation, the absorption of radiation, collisions of two BHs to give a larger one, and the effects of the expansion. We show that the system may follow two different generic paths depending on the initial temperature of the plasma.Comment: 17 pages, version to appear in JCA

The Height of a Giraffe

A minor modification of the arguments of Press and Lightman leads to an estimate of the height of the tallest running, breathing organism on a habitable planet as the Bohr radius multiplied by the three-tenths power of the ratio of the electrical to gravitational forces between two protons (rather than the one-quarter power that Press got for the largest animal that would not break in falling over, after making an assumption of unreasonable brittleness). My new estimate gives a height of about 3.6 meters rather than Press's original estimate of about 2.6 cm. It also implies that the number of atoms in the tallest runner is very roughly of the order of the nine-tenths power of the ratio of the electrical to gravitational forces between two protons, which is about 3 x 10^32.Comment: 12 pages, LaTe

Bounds on the cosmological abundance of primordial black holes from diffuse sky brightness: single mass spectra

We constrain the mass abundance of unclustered primordial black holes (PBHs), formed with a simple mass distribution and subject to the Hawking evaporation and particle absorption from the environment. Since the radiative flux is proportional to the numerical density, an upper bound is obtained by comparing the calculated and observed diffuse background values, (similarly to the Olbers paradox in which point sources are considered) for finite bandwidths. For a significative range of formation redshifts the bounds are better than several values obtained by other arguments $\Omega_{pbh} \leq 10^{-10}$; and they apply to PBHs which are evaporating today.Comment: 20 pages, 5 figures, to appear in PR

Homothetic Self-Similar Solutions of the Three-Dimensional Brans-Dicke Gravity

All homothetic self-similar solutions of the Brans-Dicke scalar field in three-dimensional spacetime with circular symmetry are found in closed form.Comment: latex, five pages, without figur

Brans-Dicke Theory and primordial black holes in Early Matter-Dominated Era

We show that primordial black holes can be formed in the matter-dominated era with gravity described by the Brans-Dicke theory. Considering an early matter-dominated era between inflation and reheating, we found that the primordial black holes formed during that era evaporate at a quicker than those of early radiation-dominated era. Thus, in comparison with latter case, less number of primordial black holes could exist today. Again the constraints on primordial black hole formation tend towards the larger value than their radiation-dominated era counterparts indicating a significant enhancement in the formation of primordial black holes during the matter-dominaed era.Comment: 9 page

Primordial black holes in braneworld cosmologies: Formation, cosmological evolution and evaporation

We consider the population evolution and evaporation of primordial black holes in the simplest braneworld cosmology, Randall-Sundrum type II. We demonstrate that black holes forming during the high-energy phase of this theory (where the expansion rate is proportional to the density) have a modified evaporation law, resulting in a longer lifetime and lower temperature at evaporation, while those forming in the standard regime behave essentially as in the standard cosmology. For sufficiently large values of the AdS radius, the high-energy regime can be the one relevant for primordial black holes evaporating at key epochs such as nucleosynthesis and the present. We examine the formation epochs of such black holes, and delimit the parameter regimes where the standard scenario is significantly modified.Comment: 9 pages RevTeX4 file with four figures incorporated, minor changes to match published versio