Deterioration in the water quality of an urbanised estuary with recommendations for improvement

Water quality characteristics of the heavily urbanised and industrialised Swartkops River and Estuary in the Eastern Cape have been the focus of several studies since the 1970s. Overloaded and poorly maintained wastewater treatment works (WWTWs), polluted stormwater runoff and solid waste have all contributed to the deterioration in the water quality of the river and estuary. The objective of this study was to determine the current water quality status of the Swartkops Estuary, by investigating spatial and temporal variability in physico-chemical parameters and phytoplankton biomass and where possible relate this to historical water quality data. The present study found evidence suggesting that water is not flushed as efficiently from the upper reaches of the estuary as was previously recorded. Reduced vertical mixing results in strong stratification and persistent eutrophic conditions with phytoplankton blooms (> 20 μg chl a·L−1), extending from the middle reaches to the tidal head of the estuary. The Motherwell Canal was and still is a major source of nitrogen (particularly ammonium) to the estuary, but the Swartkops River is the primary source of phosphorus with excessive inputs from the cumulative effect of three WWTWs upstream. An analysis of historical water quality data in the Swartkops Estuary (1995 to 2013) shows that all recorded dissolved inorganic phosphorus measurements were classified as hypertrophic (> 0.1 mg P·L−1), whereas 41% of dissolved inorganic nitrogen measurements were either mesotrophic or eutrophic. If nutrient removal methods at the three WWTWs were improved and urban runoff into the Motherwell Canal better managed, it is likely that persistent phytoplankton blooms and health risks associated with eutrophication could be reduced.Keywords: Swartkops Estuary, nutrients, salinity, eutrophication, microalga

Characterization of polychlorinated biphenyls in surface sediments of the North End Lake, Port Elizabeth, South Africa

The distribution and concentrations of 6 indicator polychlorinated biphenyl (PCB) congeners, nos. 28, 52, 101, 138, 153 and 180, were determined in surface  sediments from the North End Lake in Port Elizabeth, South Africa. Forty-two  surficial sediment samples were collected from different locations covering the  region that receives the majority of the industrial waste, urban effluents and runoff  and thus expected to be contaminated with different degrees of contamination. The analysis was achieved by gas chromatography-mass spectrometry (GC/MS) using  the internal standard method. The total PCB concentrations in the samples ranged from 1.60 to 3.06 ng·g-1 dry weight (dw). The concentrations of congener profiles showed significant differences. Generally, the highest PCB concentrations were  associated with high organic matter contents and small grain size. The highly  chlorinated PCBs dominated with regards to the levels in sediments. PCB 138 was the major contributor to the total PCBs and was detected at 100% of sites. This study provided a snapshot of the PCB contamination status in the North End Lake  sediments, and allowed for a comparison between the investigated system and other systems worldwide.Keywords: PCBs, sediments, organic matter, particle size, North End Lak

Classification of estuaries in the Ciskei and Transkei regions based on physical and botanical characteristics

For the first time a comprehensive botanical survey has taken place in the Ciskei and Transkei estuaries, Eastern Cape Province, South Africa. In total 54 plant species were found in the 92 estuaries surveyed. These plants could be divided into the following five habitat complexes; reed and sedge beds (23 species), salt marsh (20 species), mangrove forest (4 species), macroalgal assemblages (3 species) and swamp forest (4 species). Ordination showed that salinity and depth were important in influencing the distribution of species. Salinity separated salt marsh from reed and sedge species and depth separated mangrove and associated species (e.g. Zostera capensis, Halophila ovalis and Acrostichum aureum) from reed and sedge species.Based on the plant species composition the estuaries could be divided into those that were permanently open versus those that were temporarily open/closed. The characteristic habitat complexes for the permanently open estuaries were intertidal salt marsh and mangrove forest. This region is a transition between the warm temperate and subtropical biogeographic zones and both permanently open and temporarily open/closed estuaries showed divisions at the Great Kei and Mngazana estuaries. In permanently open estuaries mangrove forest occurred north of the Great Kei Estuary and swamp forest north of the Mngazana Estuary. In temporarily open/closed estuaries reed and sedge beds occurred north of the Great Kei River and swamp forest, reed and sedge beds occurred north of the Mngazana Estuary where they replaced the salt marsh. The temporarily open/closed estuaries in the Ciskei were characterised by salt marsh and macroalgae. Submerged macrophytes such as Ruppia cirrhosa and Potamogeton pectinatus were also common. Salt marsh occurred because of high water column salinity and wide intertidal and supratidal zones. These estuaries were characterised by seawater washing into the estuary over the berm at the mouth and thus had high salinity. The variation in physical environment, changes in climate and transition between biogeographic regions has resulted in regions of high biodiversity. Mangrove, salt marsh and swamp forest species are found in the same region

Salt secretion, proline accumulation and increased branching confer tolerance to drought and salinity in the endemic halophyte Limonium linifolium

AbstractLimonium linifolium (L.f.) Kuntze co-occurs with Bassia diffusa (Thunb.) Kuntze in the upper intertidal ranges of salt marshes in South Africa. Predictions of climate change indicate that there would be large variations in inundation and salinity in salt marshes in which L. linifolium occurs. The aims of this study were to investigate its tolerances to water and salinity variations similar to these predicted conditions. Plants were treated to tidal, drought and submerged conditions each at five salinity levels (0, 8, 18, 35 and 45psu), for two months. Growth measurements showed that the plant was tolerant to a wide range of salinity under both tidal and drought conditions, but was susceptible to complete submergence, with high membrane damage in tidal-treated plants. Plants died within 2weeks of complete submergence. Branching increased in drought-treated plants, decreased with increasing salinity and correlated positively with shoot area (r=0.927). Results showed that L. linifolium tolerates drought by accumulating large quantities of proline and oxalic acid, and excreting excess salts for water potential balance. Salt secretion is an important adaptation for a plant that thrives in a highly variable saline habitat. Further studies on the reproductive resilience of the species would shed more light on long term resilience of salt marshes in which the species occur, if the climate changes as predicted. This is important for salt marsh species diversity, as this plant is endemic to South Africa

Multivariate analysis of the dominant and sub-dominant epipelic diatoms and water quality data from South African rivers

Data are presented on the distribution of the dominant and sub-dominant epipelic diatoms found in South African rivers from different regions of the country. A multivariate analysis identified 36 diatom species that were associated with different levels of TDS, PO4, NH4 and SiO2. Three groups of rivers were identified. Group I consisted of sites with high PO4 and SiO2, which corresponded to Durban Metropolitan Area sites, Kruger National Park rivers, the rivers in the Johannesburg Metropolitan Area and the Orange River. In these rivers 12 diatom species were identified that might  indicate those water quality characteristics. Group II included stations where the water quality had high TDS and NH4 values which were associated with most stations in the Swartkops River in the Eastern Cape. The indicators in this group comprised 12 diatom species. Group III were from sampling stations where the water had low levels of minerals, i.e. the upper reaches of the Gamtoos River and the Swartkops River in the Eastern Cape, the Olifants River in the Northern Cape, rivers sampled in KwaZulu-Natal and the Northern Cape. At these sites, 13 diatom species were found as dominants in this better water quality. Water quality data collected during this study showed that over 50% of the river systems display some degree of eutrophication and thus efforts should be made to reduce inputs of nutrients and pollutants to those rivers.Keywords: ammonium, diatoms, phosphate, rivers, South Africa, total dissolved solid

Progress Report on the Fluorox Process for April 30, 1957-January 14, 1958

Progress in the Fluorox program is reported. The chemical reaction of primary interest in the Fluorox program is the oxidation of UF/sub 4/ with O/sub 2/, 2UF/sub 4/ + O/sub 2/ = UO/sub 2/F/sub 2/ + UF/sub 6/; however, to study this process at higher temperatures, the thermal decomposition of UO/sub 2/F/sub 2/, 3UO/sub 2/F/sub 2/ = 2/3 U/sub 3 /O/sub 8/ + UF/sub 6/ + 1/3 O/sub 2/, is being investigated by thermogravimetric methods in the temperature range 750 to 900 deg C. A fluidized bed reactor and a flame reactor have been used successfully to perform the continuous oxidation of UF/sub 4/ with O/sub 2/. The 3-in. fluidized bed reactor was operated up to 825 deg C on both a continuous and batch basis while the flame reactor was used to continuously react finely divided UF/sub 4/ with O/sub 2/ in a CO-O/sub 2/ flame at temperatures greater than 1200 deg C. (auth

Transverse momentum dependence in gluon distribution and fragmentation functions

We investigate the twist two gluon distribution functions for spin 1/2 hadrons, emphasizing intrinsic transverse momentum of the gluons. These functions are relevant in leading order in the inverse hard scale in scattering processes such as inclusive leptoproduction or Drell-Yan scattering, or more general in hard processes in which at least two hadrons are involved. They show up in azimuthal asymmetries. For future estimates of such observables, we discuss specific bounds on these functions.Comment: 14 pages, revtex, 7 Postscript figure

Phase structures of strong coupling lattice QCD with finite baryon and isospin density

Quantum chromodynamics (QCD) at finite temperature (T), baryon chemical potential (\muB) and isospin chemical potential (\muI) is studied in the strong coupling limit on a lattice with staggered fermions. With the use of large dimensional expansion and the mean field approximation, we derive an effective action written in terms of the chiral condensate and pion condensate as a function of T, \muB and \muI. The phase structure in the space of T and \muB is elucidated, and simple analytical formulas for the critical line of the chiral phase transition and the tricritical point are derived. The effects of a finite quark mass (m) and finite \muI on the phase diagram are discussed. We also investigate the phase structure in the space of T, \muI and m, and clarify the correspondence between color SU(3) QCD with finite isospin density and color SU(2) QCD with finite baryon density. Comparisons of our results with those from recent Monte Carlo lattice simulations on finite density QCD are given.Comment: 18 pages, 6 figures, revtex4; some discussions are clarified, version to appear in Phys. Rev.

Full-wave invisibility of active devices at all frequencies

There has recently been considerable interest in the possibility, both theoretical and practical, of invisibility (or "cloaking") from observation by electromagnetic (EM) waves. Here, we prove invisibility, with respect to solutions of the Helmholtz and Maxwell's equations, for several constructions of cloaking devices. Previous results have either been on the level of ray tracing [Le,PSS] or at zero frequency [GLU2,GLU3], but recent numerical [CPSSP] and experimental [SMJCPSS] work has provided evidence for invisibility at frequency $k\ne 0$. We give two basic constructions for cloaking a region $D$ contained in a domain $\Omega$ from measurements of Cauchy data of waves at \p \Omega; we pay particular attention to cloaking not just a passive object, but an active device within $D$, interpreted as a collection of sources and sinks or an internal current.Comment: Final revision; to appear in Commun. in Math. Physic