Characterization of Grain Boundaries in Superplastically Deformed Y-TZP Ceramics

The effects of compressive deformation on the grain boundary characteristics of fine-grained Y-TZP have been investigated using surface spectroscopy, impedance analysis, and transmission electron microscopy. After sintering at low temperature (1150°C), the grain boundaries are covered by an ultrathin (1nm) yttrium-rich amorphous film. After deformation at 1200°–1300°C under low stress, some grain boundaries are no longer covered by the amorphous film. Yttrium segregation seems to occur only at wetted grain boundaries. Evidence has been found that the extent of dewetting increases with increasing applied stress

Patches in a side-by-side configuration: a description of the flow and deposition fields

In the last few decades, a lot of research attention has been paid to flow-vegetation interactions. Starting with the description of the flow field around uniform macrophyte stands, research has evolved more recently to the description of flow fields around individual, distinct patches. However, in the field, vegetation patches almost never occur in isolation. As such, patches will influence each other during their development and interacting, complex flow fields can be expected. In this study, two emergent patches of the same diameter (D = 22 cm) and a solid volume fraction of 10% were placed in a side-by-side configuration in a lab flume. The patches were built as an array of wooden cylinders, and the distance between the patches (gap width Delta) was varied between Delta = 0 and 14 cm. Flow measurements were performed by a 3D Vectrino Velocimeter (Nortek AS) at mid-depth of the flow. Deposition experiments of suspended solids were performed for selected gap widths. Directly behind each patch, the wake evolved in a manner identical to that of a single, isolated patch. On the centerline between the patches, the maximum velocity U-max was found to be independent of the gap width Delta. However, the length over which this maximum velocity persists, the potential core L-j, increased linearly as the gap width increased. After the merging of the wakes, the centerline velocity reaches a minimum value U-min. The minimum centerline velocity decreased in magnitude as the gap width decreased. The velocity pattern within the wake is reflected in the deposition patterns. An erosion zone occurs on the centerline between the patches, where the velocity is elevated. Deposition occurs in the low velocity zones directly behind each patch and also downstream of the patches, along the centerline between the patches at the point of local velocity minimum. This downstream deposition zone, a result of the interaction of neighbouring patch wakes, may facilitate the establishment of new vegetation, which may eventually inhibit flow between the upstream patches and facilitate patch merger

Oxygen non-stoichiometry determination of perovskite materials by a carbonation process

A new and easy method is developed to determine the oxygen non-stoichiometry of perovskite materials under equilibrium conditions. The method is based on the complete decomposition of the powder to stoichiometric metal oxides and/or metal carbonates by using CO2 as reacting gas. The oxygen non-stoichiometry is calculated from the mass change caused by this reaction. Its applicability is demonstrated by using SrCoO3 − δ, BaCoO3 − δ, BaFeO3 − δ and BaCeO3 − δ as representative materials. The oxygen non-stoichiometry (δ) values at 950 °C in air were determined as 0.48, 0.36, 0.43 and 0.03 respectively. These values can be used as reference points for oxygen non-stoichiometry analysis at other temperature

Mixture of multiple copies of maximally entangled states is quasi-pure

Employing the general BXOR operation and local state discrimination, the mixed state of the form \rho^{(k)}_{d}=\frac{1}{d^{2}}\sum_{m,n=0}^{d-1}(|\phi_{mn}><\phi_{mn}|)^{\otim es k} is proved to be quasi-pure, where $\{|\phi_{mn}>\}$ is the canonical set of mutually orthogonal maximally entangled states in $d\times d$. Therefore irreversibility does not occur in the process of distillation for this family of states. Also, the distillable entanglement is calculated explicitly.Comment: 6 pages, 1 figure. The paper is subtantially revised and the general proof is give

Isovector and isoscalar superfluid phases in rotating nuclei

The subtle interplay between the two nuclear superfluids, isovector T=1 and isoscalar T=0 phases, are investigated in an exactly soluble model. It is shown that T=1 and T=0 pair-modes decouple in the exact calculations with the T=1 pair-energy being independent of the T=0 pair-strength and vice-versa. In the rotating-field, the isoscalar correlations remain constant in contrast to the well known quenching of isovector pairing. An increase of the isoscalar (J=1, T=0) pair-field results in a delay of the bandcrossing frequency. This behaviour is shown to be present only near the N=Z line and its experimental confirmation would imply a strong signature for isoscalar pairing collectivity. The solutions of the exact model are also discussed in the Hartree-Fock-Bogoliubov approximation.Comment: 5 pages, 4 figures, submitted to PR

Quantum Vibrational Impurity Embedded in a One-dimensional Chain

We perform a fully quantum mechanical numerical calculation for the problem of a single electron (or excitation) propagating in a N-site one-dimensional chain in the presence of a single Holstein impurity. We compute the long-time averaged probability for finding the electron on the impurity site as a function of the nonlinearity parameter, defined in terms of the electron-phonon coupling strength and the oscillator frequency. The results, in the intermediate nonlinearity parameter range, differ substantially from the ones obtained through the use of the discrete nonlinear Schroedinger equation, even in the high-frequency regime.Comment: 8 pages, 4 figure