Modelling of artefacts in estimations of particle size of needle-like particles from laser diffraction measurements

Manufacturing of particulate products across many industries relies on accurate measurements of particle size distributions in dispersions or powders. Laser diffraction (or small angle light scattering) is commonly used, usually off-line, for particle size measurements. The estimation of particle sizes by this method requires the solution of an inverse problem using a suitable scattering model that takes into account size, shape and optical properties of the particles. However, laser diffraction instruments are usually accompanied by software that employs a default scattering model for spherical particles, which is then used to solve the inverse problem even though a significant number of particulate products occur in strongly non-spherical shapes such as needles. In this work, we demonstrate that using the spherical model for the estimation of sizes of needle-like particles can lead to the appearance of artefacts in the form of multimodal populations of particles with size modes much smaller than those actually present in the sample. This effect can result in a significant under-estimation of the mean particle size and in false modes in estimated particles size distributions.Comment: 28 pages 8 figures accepted in the journal of Chemical Engineering Scienc

Dynamic response studies on aggregation and breakage dynamics of colloidal dispersions in stirred tanks

Aggregation and breakage of aggregates of fully destabilized polystyrene latex particles in turbulent flow was studied experimentally in both batch and continuous stirred tanks using small-angle static light scattering. It was found that the steady-state values of the root-mean-square radius of gyration are fully reversible upon changes of stirring speed as well as solid volume fraction. Steady-state values of the root-mean-square radius of gyration were decreasing with decreasing solid volume fraction as well as with increasing stirring speed. Moreover, it was found that the steady-state structure and shape of the aggregates is not influenced by the applied stirring speed

Analysis of strategies for improving uranium utilization in pressurized water reactors

Systematic procedures have been devised and applied to evaluate core design and fuel management strategies for improving uranium utilization in Pressurized Water Reactors operated on a once-through fuel cycle. A principal objective has been the evaluation of suggested improvements on a self-consistent basis, allowing for concurrent changes in dependent variables such as core leakage and batch power histories, which might otherwise obscure the sometimes subtle effects of interest. Two levels of evaluation have been devised: a simple but accurate analytic model based on the observed linear variations in assembly reactivity as a function of burnup; and a numerical approach, embodied in a computer program, which relaxes this assumption and combines it with empirical prescriptions for assembly (or batch) power as a function of reactivity, and core leakage as a function of peripheral assembly power. State-of-the-art physics methods, such as PDQ-7, were used to verify and supplement these techniques.These methods have been applied to evaluate several suggested improvements: (1) axial blankets of low-enriched or depleted uranium, and of beryllium metal, (2) radial natural uranium blankets, (3) lowleakage radial fuel management, (4) high burnup fuels, (5) optimized H/U atom ratio, (6) annular fuel, and (7) mechanical spectral shift (i.e. variable fuel-to-moderator ratio) concepts such as those involving pin pulling and bundle reconstitution.The potential savings in uranium requirements compared to current practice were found to be as follows: (1) O0-3%, (2) negative, (3) 2-3%; possibly 5%, (4) "15%, (5) 0-2.5%, (6) no inherent advantage, (7) 10%. Total savings should not be assumed to be additive; and thermal/hydraulic or mechanical design restrictions may preclude full realization of some of the potential improvements

Effects of secondary metal carbonate addition on the porous character of resorcinol-formaldehyde xerogels

A deeper understanding of the chemistry and physics of growth, aggregation and gelation processes involved in the formation of xerogels is key to providing greater control of the porous characteristics of such materials, increasing the range of applications for which they may be utilised. Time-resolved dynamic light scattering has been used to study the formation of resorcinol-formaldehyde gels in the presence of combinations of Group I (Na and Cs) and Group II (Ca and Ba) metal carbonates. It was found that the combined catalyst composition, including species and times of addition, is crucial in determining the end properties of the xerogels, via its effect on growth of clusters involved in formation of the gel network. Combination materials have textural characteristics within the full gamut offered by each catalyst alone; however, in addition, combination materials which retain the small pores associated with sodium carbonate catalysed xerogels exhibit a narrowing of the pore size distribution, providing an increased pore volume within an application-specific range of pore sizes. We also show evidence of pore size tunability while maintaining ionic strength, which significantly increases the potential of such systems for biological applications

Analysis of strategies for improving uranium utilization in pressurized water reactors

Includes bibliographical references (pages 238-241)Systematic procedures have been devised and applied to evaluate core design and fuel management strategies for improving uranium utilization in Pressurized Water Reactors operated on a once-through fuel cycle. A principal objective has been the evaluation of suggested improvements on a self-consistent basis, allowing for concurrent changes in dependent variables such as core leakage and batch power histories, which might otherwise obscure the sometimes subtle effects of interest. Two levels of evaluation have been devised: a simple but accurate analytic model based on the observed linear variations in assembly reactivity as a function of burnup; and a numerical approach, embodied in a computer program, which relaxes this assumption and combines it with empirical prescriptions for assembly (or batch) power as a function of reactivity, and core leakage as a function of peripheral assembly power. State-of-the-art physics methods, such as PDQ-7, were used ! to verify and supplement these techniques.These methods have been applied to evaluate several suggested improvements: (1) axial blankets of low-enriched or depleted uranium, and of beryllium metal, (2) radial natural uranium blankets, (3) low-leakage radial fuel management, (4) high burnup fuels, (5) optimized H/U atom ratio, (6) annular fuel, and (7) mechanical spectral shift (i.e. variable fuel-to-moderator ratio) concepts such as those involving pin pulling and bundle reconstitution.The potential savings in uranium requirements compared to current practice were found to be as follows: (1) O0-3%, (2) negative, (3) 2-3%; possibly 5%, (4) "15%, (5) 0-2.5%, (6) no inherent advantage, (7) 10%. Total savings should not be assumed to be additive; and thermal/hydraulic or mechanical design restrictions may preclude full realization of some of the potential improvements

Hard x-ray production from high intensity laser solid interactions

Intense laser (> 10{sup 21} W/cm{sup 2}) driven hard x-ray sources offer a new alternative to conventional electron accelerator bremsstrahlung sources. These laser driven sources offer considerable simplicity in design and cost advantage for multiple axis views and have the potential for much higher spatial and temporal resolution than is achievable with accelerator sources We have begun a series of experiments using the Petawatt Laser system at LLNL to determine the potential of these sources for radiography applications Absolutely calibrated spectra extending to 20 MeV and high resolution radiographs through a {rho}r{>=}150 gm/cm{sup 2} have been obtained The physics of these sources and the scaling relationships and laser technology required to provide the dose levels necessary for radiography applications will be discussed Diagnostics of the laser produced electrons and photons will be addresse

An Accelerated Development, Reduced Cost Approach to Lunar/Mars Exploration Using a Modular NTR-Based Space Transportation System

The results of integrated systems and mission studies are presented which quantify the benefits and rationale for developing a common, modular lunar/Mars space transportation system (STS) based on nuclear thermal rocket (NTR) technology. At present NASA's Exploration Program Office (ExPO) is considering chemical propulsion for an 'early return to the Moon' and NTR propulsion for the more demanding Mars missions to follow. The time and cost to develop these multiple systems are expected to be significant. The Nuclear Propulsion Office (NPO) has examined a variety of lunar and Mars missions and heavy lift launch vehicle (HLLV) options in an effort to determine a 'standardized' set of engine and stage components capable of satisfying a wide range of Space Exploration Initiative (SEI) missions. By using these components in a 'building block' fashion, a variety of single and multi-engine lunar and Mars vehicles can be configured. For NASA's 'First Lunar Outpost' (FLO) mission, an expendable NTR stage powered by two 50 klbf engines can deliver approximately 96 metric tons (t) to translunar injection (TLI) conditions for an initial mass in low earth orbit (IMLEO) of approximately 198 t compared to 250 t for a cryogenic chemical TLI stage. The NTR stage liquid hydrogen (LH2) tank has a 10 m diameter, 14.5 m length, and 66 t LH2 capacity. The NTR utilizes a UC-ZrC-graphite 'composite' fuel with a specific impulse (Isp) capability of approximately 900 s and an engine thrust-to-weight ratio of approximately 4.3. By extending the size and LH2 capacity of the lunar NTR stage to approximately 20 m and 96 t, respectively, a single launch Mars cargo vehicle capable of delivering approximately 50 t of surface payload is possible. Three 50 klbf NTR engines and the two standardized LH2 tank sizes developed for lunar and Mars cargo vehicle applications would be used to configure the Mars piloted vehicle for a mission as early as 2010. The paper describes the features of the 'common' NTR-based moon/Mars STS, examines performance sensitivities resulting from different 'mission mode' assumptions, and quantifies potential schedule and cost benefits resulting from this modular moon/Mars NTR vehicle approach

Concentration and pH dependence of colloidal scale solute clustering within aqueous solutions of small organic molecule

Aqueous solutions of well soluble molecules are usually assumed to be essentially homogenous systems with some degree of local structuring due to specific interactions on the sub-nanometre scale, involving the creation of, e.g. molecular clusters, hydration shells, etc., usually not exceeding several solute molecules. These small molecular structures (molecular clusters) are commonly observed (experimentally and theoretically) in aqueous solutions of many organic and inorganic systems. The presence of colloidal scale (mesoscale) structures has been well established in aqueous solutions of various small molecules [1] and these clusters have been proposed to be involved in non-classical crystal nucleation mechanisms [2,3]. Clusters in solutions of amino acids have been reported to be thermodynamically stable and can be present in both undersaturated and supersaturated solutions with respect to the solid-liquid equilibrium [4,5]. We investigated concentration and pH dependence of mesoscale clustering in aqueous solutions of small organic molecules, including amino acids (such as glycine) and amines (such as triethylenetetramine), which are well soluble in water and have a range of charged states that can be adjusted by changing solution pH. We used Dynamic Light Scattering (DLS) and Brownian Microscopy/ Nanoparticles Tracking Analysis (NTA) in order to measure size distributions and number concentrations as well as scattered intensities and optical contrast of mesoscale clusters. Mesoscale clusters were present in undersaturated solutions at solute concentrations well below the solid-liquid equilibrium (saturation) concentration at a given temperature, with mean diameters within 200-400 nm. Scattering intensities and number concentrations increased with increasing solute concentrations, while the mean size of mesoscale clusters remained approximately constant. When pH was varied in amino acid solutions, values away from the isoelectric point resulted in a decrease of the number concentration of mesoscale clusters. While the mean size of mesoscale clusters remained approximately independent of pH, scattering intensities decreased sharply as solution pH moved more than 3 units away from the isoelectric point in either direction. This change was closely correlated with the speciation of charged species, whereby the zwitterions predominate near the isoelectric point and positively and negatively charged species predominate at lower and higher pH, respectively. We note that the mesospecies are not to be seen as a separate phase and the system is better described as a thermodynamically stable mesostructured liquid containing solute-rich domains (mesoscale clusters) dispersed within bulk solute solution [6]. At a given temperature, solute molecules in such a mesostructured liquid phase are subject to equilibrium distribution between solute-rich mesospecies and the surrounding bulk solution